Achieving a Thermodynamic Self‐Regulation Dynamic Adsorption Mechanism for Ammonia Synthesis through Selective Orbital Coupling

• Published in: Angewandte Chemie International Edition Vol. 64; no. 6; pp. e202418035 - n/a
• Main Authors: Dai, Tian‐Yi, Shi, Hang, Wang, Tong‐Hui, Lang, Xing‐You, Jiang, Qing
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 03.02.2025
• Edition: International ed. in English
• Subjects: Adsorption; Ammonia; Catalysts; Catalytic activity; Chemical reduction; Chemical synthesis; Coupling; Electrocatalysis; Electrodes; Intermediates; Intermetallic Compound; Nitrogen Reduction Reaction; Orbital Coupling; Reaction intermediates; Scaling; Scaling Relation; Electrocatalysis; Intermetallic Compound; Nitrogen Reduction Reaction; Scaling Relation; Orbital Coupling

With the continuous pursuing on the improvement of catalytic activity, a catalyst performed exceeding catalytic volcano plots is desired, while it is impeded by the adsorption‐energy scaling relations of reaction intermediates. Numerous efforts have been focused on optimizing the initial and final i...