Controlled Self‐assembly of Nanographdiynes Mediated by Molecular Dipoles Induced by Rotatory Asymmetric Substituents

• Published in: Chemistry : a European journal Vol. 31; no. 12; pp. e202404275 - n/a
• Main Authors: Chen, Jing, He, Jingyi, Wu, Xingzhong, Li, Yongjun
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 25.02.2025; Wiley Subscription Services, Inc
• Subjects: Aggregates; Asymmetry; Chemistry; Chemistry, Multidisciplinary; Dipole interactions; Graphdiyne; Molecular dipole; Nano graphdiyne; Optical properties; Optoelectronics; Physical Sciences; Science & Technology; Self-assemble; Self-assembly; Substitutes; π–π stacking; DEHYDROBENZOANNULENES; Graphdiyne; Nano graphdiyne; Molecular dipole; pi-pi stacking; Self-assemble; π–π stacking

The discrete π‐ stacks of specific lengths and orientation is crucial for understanding the impact of intermolecular interactions on optical or electronic properties of nanographdiynes. We designed and synthesized nanographdiynes modified with bulky rotatable asymmetric substituents. The peripheral...