Overcoming the Incompatibility Between Electrical Conductivity and Electromagnetic Transmissivity: A Graphene Glass Fiber Fabric Design Strategy
Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electro...
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| Published in | Advanced materials (Weinheim) Vol. 36; no. 24; pp. e2313752 - n/a |
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| Main Authors | , , , , , , , , , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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Germany
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01.06.2024
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| Abstract | Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction‐integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high‐quality and layer‐limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250–3000 Ω·sq−1), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42–0.51) and higher transmissivity (by 0.27–0.62) than those of its metal‐based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems.
Graphene glass fiber fabric is innovatively fabricated through the first‐developed decoupling chemical vapor deposition growth strategy to controllably prepare high‐quality, layer‐limited graphene on the non‐catalytic nonmetallic GFF, through which the desired compatibility of electrical conductivity and EM transmissivity can be realized; thus, helping get rid of the electrical conductivity–electromagnetic transmissivity‐incompatible dilemma suffered by conventional conductive materials effectively. |
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| AbstractList | Abstract
Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction‐integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high‐quality and layer‐limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250–3000 Ω·sq
−1
), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42–0.51) and higher transmissivity (by 0.27–0.62) than those of its metal‐based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems. Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction‐integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high‐quality and layer‐limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250–3000 Ω·sq−1), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42–0.51) and higher transmissivity (by 0.27–0.62) than those of its metal‐based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems. Graphene glass fiber fabric is innovatively fabricated through the first‐developed decoupling chemical vapor deposition growth strategy to controllably prepare high‐quality, layer‐limited graphene on the non‐catalytic nonmetallic GFF, through which the desired compatibility of electrical conductivity and EM transmissivity can be realized; thus, helping get rid of the electrical conductivity–electromagnetic transmissivity‐incompatible dilemma suffered by conventional conductive materials effectively. Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction-integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high-quality and layer-limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250-3000 Ω·sq-1), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42-0.51) and higher transmissivity (by 0.27-0.62) than those of its metal-based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems.Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction-integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high-quality and layer-limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250-3000 Ω·sq-1), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42-0.51) and higher transmissivity (by 0.27-0.62) than those of its metal-based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems. Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction‐integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high‐quality and layer‐limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250–3000 Ω·sq−1), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42–0.51) and higher transmissivity (by 0.27–0.62) than those of its metal‐based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems. Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their severe intrinsic impedance mismatch with air dielectric causes strong reflection of incident electromagnetic waves, and the resulting low electromagnetic transmissivity typically interferes with surrounding electromagnetic signal communications in modern multifunction-integrated instruments. Herein, graphene glass fiber fabric (GGFF) that merges intrinsic electrical and electromagnetic properties of graphene with dielectric attributes and highly porous macrostructure of glass fiber fabric (GFF) is innovatively developed. Using a novel decoupling chemical vapor deposition growth strategy, high-quality and layer-limited graphene is prepared on noncatalytic nonmetallic GFF in a controlled manner; this is pivotal to realizing GGFF with the desired compatibility among high conductivity, low electromagnetic reflectivity, and high electromagnetic transmissivity. At the same sheet resistance over a wide range of values (250-3000 Ω·sq ), the GGFF exhibits significantly lower electromagnetic reflectivity (by 0.42-0.51) and higher transmissivity (by 0.27-0.62) than those of its metal-based conductive counterpart (CuGFF). The material design strategy reported herein provides a constructive solution to eliminate the incompatibility between electrical conductivity and electromagnetic transmissivity faced by conventional conductive materials, spotlighting the applicability of GGFF in electric heating scenarios in radar, antenna, and stealth systems. |
| Author | Li, Wenjuan Xie, Qin Zhang, Qinchi Huang, Kewen Tu, Ce Sun, Jianbo Wang, Kun Liu, Ruojuan Ge, Yunsong Cheng, Yi Li, Zhihao Yin, Wanjian Liu, Zhongfan Yang, Fan Yang, Yuyao Liang, Fushun Yuan, Hao Wang, Xiaobai Cheng, Shuting Ma, Mingyang Qi, Yue Jiang, Jun |
| Author_xml | – sequence: 1 givenname: Kewen surname: Huang fullname: Huang, Kewen organization: Beijing Graphene Institute – sequence: 2 givenname: Fushun surname: Liang fullname: Liang, Fushun organization: Beijing Graphene Institute – sequence: 3 givenname: Jianbo surname: Sun fullname: Sun, Jianbo organization: Beijing Graphene Institute – sequence: 4 givenname: Qinchi surname: Zhang fullname: Zhang, Qinchi organization: Beijing Graphene Institute – sequence: 5 givenname: Zhihao surname: Li fullname: Li, Zhihao organization: Soochow University – sequence: 6 givenname: Shuting surname: Cheng fullname: Cheng, Shuting organization: China University of Petroleum – sequence: 7 givenname: Wenjuan surname: Li fullname: Li, Wenjuan organization: Beijing Graphene Institute – sequence: 8 givenname: Hao surname: Yuan fullname: Yuan, Hao organization: Beijing Graphene Institute – sequence: 9 givenname: Ruojuan surname: Liu fullname: Liu, Ruojuan organization: Beijing Graphene Institute – sequence: 10 givenname: Yunsong surname: Ge fullname: Ge, Yunsong organization: Beijing Graphene Institute – sequence: 11 givenname: Yi surname: Cheng fullname: Cheng, Yi organization: Beijing Graphene Institute – sequence: 12 givenname: Kun surname: Wang fullname: Wang, Kun organization: Beijing Graphene Institute – sequence: 13 givenname: Jun surname: Jiang fullname: Jiang, Jun organization: China University of Petroleum – sequence: 14 givenname: Yuyao surname: Yang fullname: Yang, Yuyao organization: Beijing Graphene Institute – sequence: 15 givenname: Mingyang surname: Ma fullname: Ma, Mingyang organization: Beijing Graphene Institute – sequence: 16 givenname: Fan surname: Yang fullname: Yang, Fan organization: Beijing Graphene Institute – sequence: 17 givenname: Ce surname: Tu fullname: Tu, Ce organization: Beijing Graphene Institute – sequence: 18 givenname: Qin surname: Xie fullname: Xie, Qin organization: Beijing Graphene Institute – sequence: 19 givenname: Wanjian surname: Yin fullname: Yin, Wanjian organization: Soochow University – sequence: 20 givenname: Xiaobai surname: Wang fullname: Wang, Xiaobai email: xiaobai_wang@yeah.net organization: Beijing Technology and Business University – sequence: 21 givenname: Yue surname: Qi fullname: Qi, Yue email: qiyue@bgi-graphene.com organization: Beijing Graphene Institute – sequence: 22 givenname: Zhongfan orcidid: 0000-0001-5554-1902 surname: Liu fullname: Liu, Zhongfan email: zfliu@pku.edu.cn organization: Beijing Graphene Institute |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38576272$$D View this record in MEDLINE/PubMed |
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| Keywords | graphene glass fiber fabric high electrical conductivity high electromagnetic transmissivity chemical vapor deposition |
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| Snippet | Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However, their... Abstract Conventional conductive materials such as metals are crucial functional components of conductive systems in diverse electronic instruments. However,... |
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| SubjectTerms | Chemical vapor deposition Decoupling Dielectric strength Electric heating Electrical resistivity Electromagnetic properties Electromagnetic radiation Glass fibers Graphene graphene glass fiber fabric high electrical conductivity high electromagnetic transmissivity Incompatibility Macrostructure Reflectance Transmissivity Wave reflection |
| Title | Overcoming the Incompatibility Between Electrical Conductivity and Electromagnetic Transmissivity: A Graphene Glass Fiber Fabric Design Strategy |
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