Modulated Synthesis of Self‐Standing Covalent Organic Framework Films
The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self‐standing COF films difficult. Herein, a modulated strategy for the facile synthesis of self‐standing COF films with good crystallinity and tunable thickness is reported. As compared with the non‐modu...
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| Published in | Chemistry : a European journal Vol. 28; no. 46; pp. e202200961 - n/a |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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16.08.2022
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| Abstract | The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self‐standing COF films difficult. Herein, a modulated strategy for the facile synthesis of self‐standing COF films with good crystallinity and tunable thickness is reported. As compared with the non‐modulated approach, the modulated strategy changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self‐standing COF films with improved mechanical properties. The Young's modulus of the self‐standing COF film obtained via the modulated strategy could increase by 26 times. Moreover, self‐standing LZU‐8 film can be used as a membrane for efficient removal of 99 % mercury ions from aqueous solution. Our results open up a new approach to prepare self‐standing COF thin films for practical applications.
A modulated strategy was developed for the synthesis of self‐standing COF films with good crystallinity and tunable thickness. As compared with the non‐modulated method, the modulated approach changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self‐standing COF films with improved mechanical properties. The Young's modulus of the self‐standing COF film obtained via the modulated strategy could increase by 26 times. |
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| AbstractList | The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self-standing COF films difficult. Herein, we report a modulated strategy for the facile synthesis of self-standing COF films with good crystallinity and tunable thickness. As compared with the non-modulated approach, the modulated strategy changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self-standing COF films with improved mechanical properties. The Young's modulus of the self-standing COF film obtained via the modulated strategy could increase by 26 times. Moreover, self-standing LZU-8 film can be used as a membrane for efficient removal of 99% mercury ions from aqueous solution. Our results open up a new approach to prepare self-standing COF thin films for practical applications. The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self‐standing COF films difficult. Herein, a modulated strategy for the facile synthesis of self‐standing COF films with good crystallinity and tunable thickness is reported. As compared with the non‐modulated approach, the modulated strategy changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self‐standing COF films with improved mechanical properties. The Young's modulus of the self‐standing COF film obtained via the modulated strategy could increase by 26 times. Moreover, self‐standing LZU‐8 film can be used as a membrane for efficient removal of 99 % mercury ions from aqueous solution. Our results open up a new approach to prepare self‐standing COF thin films for practical applications. A modulated strategy was developed for the synthesis of self‐standing COF films with good crystallinity and tunable thickness. As compared with the non‐modulated method, the modulated approach changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self‐standing COF films with improved mechanical properties. The Young's modulus of the self‐standing COF film obtained via the modulated strategy could increase by 26 times. The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self‐standing COF films difficult. Herein, a modulated strategy for the facile synthesis of self‐standing COF films with good crystallinity and tunable thickness is reported. As compared with the non‐modulated approach, the modulated strategy changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self‐standing COF films with improved mechanical properties. The Young's modulus of the self‐standing COF film obtained via the modulated strategy could increase by 26 times. Moreover, self‐standing LZU‐8 film can be used as a membrane for efficient removal of 99 % mercury ions from aqueous solution. Our results open up a new approach to prepare self‐standing COF thin films for practical applications. The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self-standing COF films difficult. Herein, a modulated strategy for the facile synthesis of self-standing COF films with good crystallinity and tunable thickness is reported. As compared with the non-modulated approach, the modulated strategy changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self-standing COF films with improved mechanical properties. The Young's modulus of the self-standing COF film obtained via the modulated strategy could increase by 26 times. Moreover, self-standing LZU-8 film can be used as a membrane for efficient removal of 99 % mercury ions from aqueous solution. Our results open up a new approach to prepare self-standing COF thin films for practical applications.The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self-standing COF films difficult. Herein, a modulated strategy for the facile synthesis of self-standing COF films with good crystallinity and tunable thickness is reported. As compared with the non-modulated approach, the modulated strategy changes the COF morphology from nanoparticles to nanofibers, enabling the facile preparation of self-standing COF films with improved mechanical properties. The Young's modulus of the self-standing COF film obtained via the modulated strategy could increase by 26 times. Moreover, self-standing LZU-8 film can be used as a membrane for efficient removal of 99 % mercury ions from aqueous solution. Our results open up a new approach to prepare self-standing COF thin films for practical applications. |
| Author | Wang, Yang Yang, Tong Guo, Bei Zhang, Zhi‐Cong Wang, Wei Ding, San‐Yuan Liang, Lin |
| Author_xml | – sequence: 1 givenname: Yang surname: Wang fullname: Wang, Yang organization: Lanzhou University – sequence: 2 givenname: Bei surname: Guo fullname: Guo, Bei organization: Lanzhou University – sequence: 3 givenname: Tong surname: Yang fullname: Yang, Tong organization: Lanzhou University – sequence: 4 givenname: Zhi‐Cong surname: Zhang fullname: Zhang, Zhi‐Cong organization: Lanzhou University – sequence: 5 givenname: Lin surname: Liang fullname: Liang, Lin organization: Lanzhou University – sequence: 6 givenname: San‐Yuan orcidid: 0000-0003-2160-4092 surname: Ding fullname: Ding, San‐Yuan email: dingsy@lzu.edu.cn organization: Lanzhou University – sequence: 7 givenname: Wei surname: Wang fullname: Wang, Wei organization: Lanzhou University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35510482$$D View this record in MEDLINE/PubMed |
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| Snippet | The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self‐standing COF films difficult. Herein, a modulated strategy... The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self-standing COF films difficult. Herein, we report a modulated... The weak interaction of covalent organic framework (COF) nanoparticles makes the preparation of self-standing COF films difficult. Herein, a modulated strategy... |
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| SubjectTerms | Aqueous solutions Chemistry covalent organic framework Mechanical properties Mercury modulated strategy Modulus of elasticity morphology control Nanofibers Nanoparticles self-standing films Synthesis Thin films |
| Title | Modulated Synthesis of Self‐Standing Covalent Organic Framework Films |
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