Phase‐Tunable Molybdenum Boride Ceramics as an Emerging Sensitive and Reliable SERS Platform in Harsh Environments

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 20; no. 31; pp. e2308690 - n/a
• Main Authors: Hu, Mengen, Li, Ke, Dang, Xian, Yang, Chengwan, Li, Xinyang, Wang, Zhen, Li, Kewei, Cao, Liang, Hu, Xiaoye, Li, Yue, Wu, Nianqiang, Huang, Zhulin, Meng, Guowen
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.08.2024
• Subjects: Ceramic powders; Ceramics; charge interaction; Chemical sensors; Extreme environments; High temperature; Molybdenum; molybdenum boride; Noble metals; phase tunable; Phases; Raman spectra; Rhodamine 6G; Substrates; surface‐enhanced Raman scattering; charge interaction; molybdenum boride; surface‐enhanced Raman scattering; phase tunable
• DOI: 10.1002/smll.202308690
• ISSN: 1613-6810; 1613-6829

Traditional surface‐enhanced Raman scattering (SERS) sensors rely heavily on the use of plasmonic noble metals, which have limitations due to their high cost and lack of physical and chemical stability. Hence, it is imperative to explore new materials as SERS platforms that can withstand high temperatures and harsh conditions. In this study, the SERS effect of molybdenum boride ceramic powders is presented with an enhancement factor of 5 orders, which is comparable to conventional noble metal substrates. The molybdenum boride powders synthesized through liquid‐phase precursor and carbothermal reduction have β‐MoB, MoB2, and Mo2B5 phases. Among these phases, β‐MoB demonstrates the most significant SERS activity, with a detection limit for rhodamine 6G (R6G) molecules of 10−9 m. The impressive SERS enhancement can be attributed to strong molecule interactions and prominent charge interactions between R6G and the various phases of molybdenum boride, as supported by theoretical calculations. Additionally, Raman measurements show that the SERS activity remains intact after exposure to high temperature, strong acids, and alkalis. This research introduces a novel molybdenum boride all‐ceramic SERS platform capable of functioning in harsh conditions, thereby showing the promising of boride ultrahigh‐temperature ceramics for detection applications in extreme environments. The all‐ceramic SERS substrates prepared by three different crystalline phases of molybdenum boride powders have good SERS activity, which is closely related to their crystal structure. Among them, β‐MoB has the best SERS enhancement activity, and the enhancement factor of 5 orders is comparable to that of noble metals. This all‐ceramic SERS platform shows promising applications in corrosive and high temperature environments.