Chiral Evaluation of Aroma-active Compounds in Real Complex Samples
ABSTRACT The enantiomeric distribution of aroma‐active compounds resulting from stereospecific biosyn‐thetic pathways was established using a multidimensional chromatographic system, which involves the on‐line coupling of reversed‐phase liquid chromatography and gas chromatography (RPLC‐GC). The pro...
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| Published in | Journal of food science Vol. 68; no. 3; pp. 770 - 774 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Oxford, UK
Blackwell Publishing Ltd
01.04.2003
Wiley Subscription Services, Inc |
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| Online Access | Get full text |
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| Abstract | ABSTRACT The enantiomeric distribution of aroma‐active compounds resulting from stereospecific biosyn‐thetic pathways was established using a multidimensional chromatographic system, which involves the on‐line coupling of reversed‐phase liquid chromatography and gas chromatography (RPLC‐GC). The proposed approach allowed the rapid determination of the enantiomeric composition of chiral terpenes such as α‐pinene, limonene, linalool and α‐terpineol in different products (that is, orange aroma, orange essential oils, and fruit beverage) without requiring the previous concentration of the sample. Relative standard deviation values lower than 7.5% were obtained for the investigated compounds. Applications to the authentication of fruit products based on both the R‐ and S‐form contents of chiral terpenes were considered. |
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| AbstractList | The enantiomeric distribution of aroma-active compounds resulting from stereospecific biosynthetic pathways was established using a multidimensional chromatographic system, which involves the on-line coupling of reversed-phase liquid chromatography and gas chromatography (RPLC-GC). The proposed approach allowed the rapid determination of the enantiomeric composition of chiral terpenes such as a-pinene, limonene, linalool and a-terpineol in different products (that is, orange aroma, orange essential oils, and fruit beverage) without requiring the previous concentration of the sample. Relative standard deviation values lower than 7.5% were obtained for the investigated compounds. Applications to the authentication of fruit products based on both the R- and S-form contents of chiral terpenes were considered. [PUBLICATION ABSTRACT] The enantiomeric distribution of aroma-active compounds resulting from stereospecific biosynthetic pathways was established using a multidimensional chromatographic system, which involves the on-line coupling of reversed-phase liquid chromatography and gas chromatography (RPLC-GC). The proposed approach allowed the rapid determination of the enantiomeric composition of chiral terpenes such as a-pinene, limonene, linalool and a-terpineol in different products (that is, orange aroma, orange essential oils, and fruit beverage) without requiring the previous concentration of the sample. Relative standard deviation values lower than 7.5% were obtained for the investigated compounds. Applications to the authentication of fruit products based on both the R- and S-form contents of chiral terpenes were considered. ABSTRACT The enantiomeric distribution of aroma‐active compounds resulting from stereospecific biosyn‐thetic pathways was established using a multidimensional chromatographic system, which involves the on‐line coupling of reversed‐phase liquid chromatography and gas chromatography (RPLC‐GC). The proposed approach allowed the rapid determination of the enantiomeric composition of chiral terpenes such as α‐pinene, limonene, linalool and α‐terpineol in different products (that is, orange aroma, orange essential oils, and fruit beverage) without requiring the previous concentration of the sample. Relative standard deviation values lower than 7.5% were obtained for the investigated compounds. Applications to the authentication of fruit products based on both the R‐ and S‐form contents of chiral terpenes were considered. ABSTRACT The enantiomeric distribution of aroma‐active compounds resulting from stereospecific biosyn‐thetic pathways was established using a multidimensional chromatographic system, which involves the on‐line coupling of reversed‐phase liquid chromatography and gas chromatography (RPLC‐GC). The proposed approach allowed the rapid determination of the enantiomeric composition of chiral terpenes such as α‐pinene, limonene, linalool and α‐terpineol in different products (that is, orange aroma, orange essential oils, and fruit beverage) without requiring the previous concentration of the sample. Relative standard deviation values lower than 7.5% were obtained for the investigated compounds. Applications to the authentication of fruit products based on both the R‐ and S‐form contents of chiral terpenes were considered. |
| Author | Caja, M.M. Herraiz, M. Ruiz del Castillo, M.L. Blanch, G.P. |
| Author_xml | – sequence: 1 givenname: M.L. surname: Ruiz del Castillo fullname: Ruiz del Castillo, M.L. organization: Authors are with Instituto de Fermentaciones Industriales, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain. Direct inquiries to author Herraiz (ifihc23@ifi.csic.es) – sequence: 2 givenname: M.M. surname: Caja fullname: Caja, M.M. organization: Authors are with Instituto de Fermentaciones Industriales, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain. Direct inquiries to author Herraiz (ifihc23@ifi.csic.es) – sequence: 3 givenname: G.P. surname: Blanch fullname: Blanch, G.P. organization: Authors are with Instituto de Fermentaciones Industriales, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain. Direct inquiries to author Herraiz (ifihc23@ifi.csic.es) – sequence: 4 givenname: M. surname: Herraiz fullname: Herraiz, M. organization: Authors are with Instituto de Fermentaciones Industriales, CSIC, Juan de la Cierva 3, 28006 Madrid, Spain. Direct inquiries to author Herraiz (ifihc23@ifi.csic.es) |
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| Cites_doi | 10.1021/jf9807014 10.1007/BF01197930 10.1002/(SICI)1520-636X(1998)10:5<499::AID-CHIR13>3.0.CO;2-V 10.1016/0021-9673(92)85684-L 10.1016/S0021-9673(99)00488-4 10.1080/10412905.1996.9700674 10.1002/(SICI)1520-667X(1996)8:4<275::AID-MCS5>3.0.CO;2-Z 10.1007/BF00321500 10.1002/(SICI)1521-4168(19980301)21:3<145::AID-JHRC145>3.0.CO;2-Z 10.1021/jf00098a010 10.1002/(SICI)1099-1026(199911/12)14:6<367::AID-FFJ856>3.0.CO;2-4 10.1093/chromsci/36.12.589 10.1002/mcs.1220060307 10.1016/S0021-9673(00)00048-0 10.1002/ffj.2730100409 10.1016/0021-9673(95)00094-4 10.1016/S0021-9673(99)00202-2 10.1002/jhrc.1240200202 10.1093/chromsci/38.3.95 10.1021/jf950183m 10.1002/(SICI)1520-667X(1998)10:2<203::AID-MCS5>3.0.CO;2-K 10.1021/jf990655n 10.1080/10412905.1993.9698165 10.1016/0021-9673(94)80374-9 |
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| References_xml | – volume: 85 start-page: 327 year: 1992 end-page: 46 article-title: Use of chiral phase gas chromatography in the control of natural aromas publication-title: Ann Falsif Expert Chim Toxicol – volume: 77 start-page: 306 year: 1994 end-page: 27 article-title: Liquid chromatography coupled on‐line with gas chromatography: state of the art publication-title: J Assoc Off Anal Chem Int – volume: 38 start-page: 1674 year: 1990 end-page: 7 article-title: Relevance of enantiomeric separations in food and beverage analyses publication-title: J Agric Food Chem – start-page: 168 year: 1992 – volume: 8 start-page: 487 year: 1996 end-page: 97 article-title: Chiral compounds of essential oils. XX. Chirality evaluation and authenticity profiles of neroli and petitgrain oils publication-title: J Essent Oil Res – volume: 6 start-page: 237 year: 1994 end-page: 44 article-title: Automated LC‐GC: A powerful method for essential oils analysis. Part IV. 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| Snippet | ABSTRACT The enantiomeric distribution of aroma‐active compounds resulting from stereospecific biosyn‐thetic pathways was established using a multidimensional... ABSTRACT The enantiomeric distribution of aroma‐active compounds resulting from stereospecific biosyn‐thetic pathways was established using a multidimensional... The enantiomeric distribution of aroma-active compounds resulting from stereospecific biosynthetic pathways was established using a multidimensional... |
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| SubjectTerms | chiral terpenes Chromatography enantiomeric distribution Food science Fruits Odors on-line coupled RPLC-GC |
| Title | Chiral Evaluation of Aroma-active Compounds in Real Complex Samples |
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