Non-invasive PGAA, PIXE and ToF-ND analyses on Hungarian Bronze Age defensive armour
Non-invasive, archaeometric analyses on selected Hungarian Bronze Age defensive armour is presented here: three greaves, three helmets two shields as well as one vessel fragment were analysed with PIXE, PGAA and TOF-ND. The detected alloy elemental and phase composition as well as its intergranular...
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| Published in | Journal of radioanalytical and nuclear chemistry Vol. 300; no. 2; pp. 787 - 799 |
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| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Dordrecht
Springer Netherlands
01.05.2014
Springer |
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| Abstract | Non-invasive, archaeometric analyses on selected Hungarian Bronze Age defensive armour is presented here: three greaves, three helmets two shields as well as one vessel fragment were analysed with PIXE, PGAA and TOF-ND. The detected alloy elemental and phase composition as well as its intergranular or spatial concentration distribution reveals important insights into the alloys used and the manufacturing techniques applied c. 1200–950 BC, and allows to reconstruct the production techniques used during the Late Bronze Age. |
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| AbstractList | Non-invasive, archaeometric analyses on selected Hungarian Bronze Age defensive armour is presented here: three greaves, three helmets two shields as well as one vessel fragment were analysed with PIXE, PGAA and TOF-ND. The detected alloy elemental and phase composition as well as its intergranular or spatial concentration distribution reveals important insights into the alloys used and the manufacturing techniques applied c. 1200-950 BC, and allows to reconstruct the production techniques used during the Late Bronze Age. Keywords Metals * Annealing * Cold working * Neutron scattering and diffraction * X-ray diffraction * Neutron topography * PGAA * PIXE Non-invasive, archaeometric analyses on selected Hungarian Bronze Age defensive armour is presented here: three greaves, three helmets two shields as well as one vessel fragment were analysed with PIXE, PGAA and TOF-ND. The detected alloy elemental and phase composition as well as its intergranular or spatial concentration distribution reveals important insights into the alloys used and the manufacturing techniques applied c. 1200–950 BC, and allows to reconstruct the production techniques used during the Late Bronze Age. |
| Audience | Academic |
| Author | Káli, György Mödlinger, Marianne Kasztovszky, Zsolt Maróti, Boglárka Kovács, Imre El Morr, Ziad Horváth, Eszter Sánta, Zsombor Szőkefalvi-Nagy, Zoltán Kis, Zoltán |
| Author_xml | – sequence: 1 givenname: Marianne surname: Mödlinger fullname: Mödlinger, Marianne email: marianne.moedlinger@univie.ac.at organization: Dipartimento di Chimica e Chimica Industriale, University of Genoa – sequence: 2 givenname: Zsolt surname: Kasztovszky fullname: Kasztovszky, Zsolt organization: Centre for Energy Research, Hungarian Academy of Sciences – sequence: 3 givenname: Zoltán surname: Kis fullname: Kis, Zoltán organization: Centre for Energy Research, Hungarian Academy of Sciences – sequence: 4 givenname: Boglárka surname: Maróti fullname: Maróti, Boglárka organization: Centre for Energy Research, Hungarian Academy of Sciences – sequence: 5 givenname: Imre surname: Kovács fullname: Kovács, Imre organization: Institute for Particle and Nuclear Physics, Wigner Research Centre for Physics, Hungarian Academy of Sciences – sequence: 6 givenname: Zoltán surname: Szőkefalvi-Nagy fullname: Szőkefalvi-Nagy, Zoltán organization: Institute for Particle and Nuclear Physics, Wigner Research Centre for Physics, Hungarian Academy of Sciences – sequence: 7 givenname: György surname: Káli fullname: Káli, György organization: Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences – sequence: 8 givenname: Eszter surname: Horváth fullname: Horváth, Eszter organization: Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences – sequence: 9 givenname: Zsombor surname: Sánta fullname: Sánta, Zsombor organization: Institute for Solid State Physics and Optics, Wigner Research Centre for Physics, Hungarian Academy of Sciences, Mirrotron Ltd – sequence: 10 givenname: Ziad surname: El Morr fullname: El Morr, Ziad organization: IRAMAT-CRPAA, UMR5060, CNRS, Université de Bordeaux 3 |
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| Cites_doi | 10.1016/j.matchar.2013.02.007 10.1007/s10967-010-0765-4 10.1016/S0168-583X(00)00156-7 10.1080/10448632.2012.645689 10.1021/ac9011705 10.1007/s00339-006-3538-8 10.1016/S0168-583X(98)00948-3 10.1007/s10967-005-0818-2 10.1007/s00339-007-4225-0 10.1515/pz-2013-0005 |
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| Keywords | Annealing PGAA PIXE Neutron topography Metals X-ray diffraction Cold working Neutron scattering and diffraction |
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| References | Mozsolics (CR13) 1985 Kasztovszky, Rosta (CR9) 2012; 23 Mödlinger, El Morr (CR10) 2013 Cartechini, Rinaldi, Kockelmann, Bonamore, Manconi, Borgia, Rocchi, Brunetti, Sgamellotti (CR4) 2006; 83 Born, Hansen (CR2) 1992; 24 Szentmiklósi, Révay, Kis (CR17) 2010; 286 CR6 Mödlinger, Piccardo, Kasztovszky, Kovács, Szőkefalvi-Nagy, Káli, Szilágyi (CR12) 2013; 79 Gyódi, Demeter, Hollós-Nagy, Kovács, Szőkefalvi-Nagy (CR8) 1999; 150 Révay (CR16) 2009; 81 CR18 Arletti, Cartechini, Rinaldi, Giovannini, Kockelmann, Cardarelli (CR1) 2008; 90 CR14 Dillmann, Beranger, Piccardo, Matthiesen (CR7) 2007 CR11 Révay, Belgya, Molnár (CR15) 2005; 265 Uckelmann (CR20) 2012 Choi, Firestone, Lindstrom, Molnár, Mughabghab, Paviotti-Corcuera, Révay, Trkov, Zerkin, Chunmei (CR5) 2007 Campbell, Hopman, Maxwell, Nejedly (CR3) 2000; 170 Szentmiklósi, Kis, Belgya, Berlizov (CR19) 2013 R Arletti (3064_CR1) 2008; 90 (3064_CR7) 2007 Z Kasztovszky (3064_CR9) 2012; 23 M Mödlinger (3064_CR10) 2013 HD Choi (3064_CR5) 2007 Z Révay (3064_CR15) 2005; 265 H Born (3064_CR2) 1992; 24 M Mödlinger (3064_CR12) 2013; 79 M Uckelmann (3064_CR20) 2012 I Gyódi (3064_CR8) 1999; 150 B Szentmiklósi (3064_CR17) 2010; 286 3064_CR11 L Szentmiklósi (3064_CR19) 2013 JL Campbell (3064_CR3) 2000; 170 3064_CR6 A Mozsolics (3064_CR13) 1985 3064_CR14 Z Révay (3064_CR16) 2009; 81 3064_CR18 L Cartechini (3064_CR4) 2006; 83 |
| References_xml | – ident: CR18 – year: 2007 ident: CR5 publication-title: Database of prompt gamma rays from slow neutron capture for elemental analysis contributor: fullname: Chunmei – volume: 79 start-page: 22 year: 2013 end-page: 36 ident: CR12 article-title: Archaeometallurgical characterization of the earliest European metal helmets publication-title: Mater Charact doi: 10.1016/j.matchar.2013.02.007 contributor: fullname: Szilágyi – volume: 286 start-page: 501 year: 2010 end-page: 505 ident: CR17 article-title: Upgrade of the prompt gamma activation analysis and the neutron-induced prompt gamma spectroscopy facilities at the Budapest Research Reactor publication-title: J Radioanal Nucl Chem doi: 10.1007/s10967-010-0765-4 contributor: fullname: Kis – year: 2012 ident: CR20 publication-title: Die Schilde der Bronzezeit in Nord-, West- und Zentraleuropa. Prähistorische Bronzefunde III, vol 4 contributor: fullname: Uckelmann – volume: 170 start-page: 193 year: 2000 end-page: 204 ident: CR3 article-title: The Guelph PIXE software package III: alternative proton database’ publication-title: Nucl Instrum Methods Phys Res Sect B doi: 10.1016/S0168-583X(00)00156-7 contributor: fullname: Nejedly – volume: 23 start-page: 25 issue: 1 year: 2012 end-page: 28 ident: CR9 article-title: How can neutrons contribute to cultural heritage research? publication-title: Neutron News doi: 10.1080/10448632.2012.645689 contributor: fullname: Rosta – ident: CR14 – year: 2013 ident: CR10 article-title: European Bronze Age sheet metal objects: 3000 years of high level bronze manufacture publication-title: JOM contributor: fullname: El Morr – volume: 81 start-page: 6851 year: 2009 end-page: 6859 ident: CR16 article-title: Determining elemental composition using prompt gamma activation analysis publication-title: Anal Chem doi: 10.1021/ac9011705 contributor: fullname: Révay – volume: 24 start-page: 339 year: 1992 end-page: 356 ident: CR2 article-title: Ein urnenfelderzeitlicher Glockenhelm aus der Sammlung Zschille publication-title: Acta Praehist Archaeol contributor: fullname: Hansen – ident: CR11 – volume: 83 start-page: 631 issue: 4 year: 2006 end-page: 636 ident: CR4 article-title: Non-destructive characterization of compositional and textural properties of Etruscan bronzes: a multi-method approach publication-title: Appl Phys A doi: 10.1007/s00339-006-3538-8 contributor: fullname: Sgamellotti – ident: CR6 – volume: 150 start-page: 605 year: 1999 end-page: 610 ident: CR8 article-title: External-beam PIXE analysis of small sculptures publication-title: Nucl Instrum Methods Phys Res B doi: 10.1016/S0168-583X(98)00948-3 contributor: fullname: Szőkefalvi-Nagy – volume: 265 start-page: 261 year: 2005 end-page: 265 ident: CR15 article-title: Application of Hypermet-PC in PGAA publication-title: J Radioanal Nucl Chem doi: 10.1007/s10967-005-0818-2 contributor: fullname: Molnár – year: 1985 ident: CR13 publication-title: Bronzefunde aus Ungarn. 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| SubjectTerms | Alloys Annealing Chemistry Chemistry and Materials Science Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Nuclear Chemistry Nuclear Physics Physical Chemistry |
| Title | Non-invasive PGAA, PIXE and ToF-ND analyses on Hungarian Bronze Age defensive armour |
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