Nanocrystalline Copper Oxide(II)-Catalyzed Alkyne-Azide Cycloadditions

Although the use of Cu(II) salts as catalysts without reductants is limited in the cycloaddition of acetylenes with azides, the catalytic system employing average 10 nm CuO(II) nanoparticles in the absence of reductants shows good catalytic activity to form 1,4-disubstituted 1,2,3-triazoles even in...

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Published inBulletin of the Korean Chemical Society Vol. 29; no. 8; pp. 1561 - 1564
Main Authors 송영진, 유충열, 홍종태, 김승주, 손승욱, 장혜영
Format Journal Article
LanguageEnglish
Published 대한화학회 20.08.2008
Subjects
화학
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Abstract Although the use of Cu(II) salts as catalysts without reductants is limited in the cycloaddition of acetylenes with azides, the catalytic system employing average 10 nm CuO(II) nanoparticles in the absence of reductants shows good catalytic activity to form 1,4-disubstituted 1,2,3-triazoles even in wet THF as well as water. It is also noticeable that CuO(II) nanoparticle catalysts can be recycled with consistent activity. A range of alkynes and azides were subject to the optimized CuO(II) nanoparticle-catalyzed cycloaddition reaction conditions to afford the desired products in good yields. KCI Citation Count: 37
AbstractList Although the use of Cu(II) salts as catalysts without reductants is limited in the cycloaddition of acetylenes with azides, the catalytic system employing average 10 nm CuO(II) nanoparticles in the absence of reductants shows good catalytic activity to form 1,4-disubstituted 1,2,3-triazoles even in wet THF as well as water. It is also noticeable that CuO(II) nanoparticle catalysts can be recycled with consistent activity. A range of alkynes and azides were subject to the optimized CuO(II) nanoparticle-catalyzed cycloaddition reaction conditions to afford the desired products in good yields. KCI Citation Count: 37
Author 홍종태
장혜영
송영진
김승주
손승욱
유충열
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  fullname: 홍종태
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  fullname: 김승주
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  fullname: 손승욱
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  fullname: 장혜영
  organization: (아주대학교)
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Title Nanocrystalline Copper Oxide(II)-Catalyzed Alkyne-Azide Cycloadditions
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