Organoammonium Salt-Catalyzed Enantioselective Cycloaddition Reactions with α-(Acyloxy)- or α-Diacylaminoacroleins

• Published in: Bulletin of the Chemical Society of Japan Vol. 83; no. 4; pp. 313 - 322
• Main Authors: Sakakura, Akira, Ishihara, Kazuaki
• Format: Journal Article
• Language: English
• Published: The Chemical Society of Japan 15.04.2010

The rational design of small-molecule chiral catalysts is an important subject in the development of practical organic syntheses. We have designed primary ammonium salt catalysts for enantioselective cycloaddition reactions with α-substituted acroleins such as α-(acyloxy)acroleins and α-diacylaminoa...