Cramér–Rao, Fisher–Shannon and LMC–Rényi Complexity-like Measures of Multidimensional Hydrogenic Systems with Application to Rydberg States

Statistical measures of complexity hold significant potential for applications in D-dimensional finite fermion systems, spanning from the quantification of the internal disorder of atoms and molecules to the information–theoretical analysis of chemical reactions. This potential will be shown in hydr...

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Published inQuantum reports Vol. 5; no. 1; pp. 116 - 137
Main Author Dehesa, Jesús S.
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.02.2023
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Abstract Statistical measures of complexity hold significant potential for applications in D-dimensional finite fermion systems, spanning from the quantification of the internal disorder of atoms and molecules to the information–theoretical analysis of chemical reactions. This potential will be shown in hydrogenic systems by means of the monotone complexity measures of Cramér–Rao, Fisher–Shannon and LMC(Lopez-Ruiz, Mancini, Calbet)–Rényi types. These quantities are shown to be analytically determined from first principles, i.e., explicitly in terms of the space dimensionality D, the nuclear charge and the hyperquantum numbers, which characterize the system’ states. Then, they are applied to several relevant classes of particular states with emphasis on the quasi-spherical and the highly excited Rydberg states, obtaining compact and physically transparent expressions. This is possible because of the use of powerful techniques of approximation theory and orthogonal polynomials, asymptotics and generalized hypergeometric functions.
AbstractList Statistical measures of complexity hold significant potential for applications in D-dimensional finite fermion systems, spanning from the quantification of the internal disorder of atoms and molecules to the information–theoretical analysis of chemical reactions. This potential will be shown in hydrogenic systems by means of the monotone complexity measures of Cramér–Rao, Fisher–Shannon and LMC(Lopez-Ruiz, Mancini, Calbet)–Rényi types. These quantities are shown to be analytically determined from first principles, i.e., explicitly in terms of the space dimensionality D, the nuclear charge and the hyperquantum numbers, which characterize the system’ states. Then, they are applied to several relevant classes of particular states with emphasis on the quasi-spherical and the highly excited Rydberg states, obtaining compact and physically transparent expressions. This is possible because of the use of powerful techniques of approximation theory and orthogonal polynomials, asymptotics and generalized hypergeometric functions.
Author Dehesa, Jesús S.
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CitedBy_id crossref_primary_10_1063_5_0153747
crossref_primary_10_1088_1751_8121_ad33da
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SSID ssj0002802968
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Snippet Statistical measures of complexity hold significant potential for applications in D-dimensional finite fermion systems, spanning from the quantification of the...
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StartPage 116
SubjectTerms Charged particles
Chemical reactions
Complexity
Cramér–Rao complexity-like measures
Entropy
Fermions
First principles
Fisher–Shannon complexity-like measures
Fourier transforms
highly excited Rydberg states
Hypergeometric functions
LMC–Rényi complexity-like measures
Mathematical analysis
multidimensional hydrogenic systems
Polynomials
Rydberg states
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Title Cramér–Rao, Fisher–Shannon and LMC–Rényi Complexity-like Measures of Multidimensional Hydrogenic Systems with Application to Rydberg States
URI https://www.proquest.com/docview/2791699223
https://doaj.org/article/1d5cc9127ded4b55a597b1071975008d
Volume 5
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