Structural and Magnetic Studies of the Tris(cyclopentadienyl)manganese(II) "Paddle-Wheel" Anions [Cp3−n(MeCp)nMn]− (n=0-3, MeCp=C5H4CH3, Cp=C5H5)
The ion‐contact complexes [{(η5‐Cp)2Mn(η2:η5‐Cp)K}3]⋅0.5 THF (1⋅0.5 THF) and [{(η2‐Cp)2(η2;η5‐MeCp)MnK(thf)}]⋅2 THF (2⋅2 THF) and ion‐separated complexes [Mg(thf)6][(η2‐Cp)3Mn]2 (3), [Mg(thf)6][(η2‐Cp)(η2‐MeCp)2Mn)]2⋅0.5 THF (4⋅0.5 THF), [Mg(thf)6][(η2‐MeCp)3Mn)]2⋅0.5 THF (5⋅0.5 THF) and [Li([12]cro...
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| Published in | Chemistry : a European journal Vol. 12; no. 11; pp. 3053 - 3060 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
03.04.2006
WILEY‐VCH Verlag |
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| Abstract | The ion‐contact complexes [{(η5‐Cp)2Mn(η2:η5‐Cp)K}3]⋅0.5 THF (1⋅0.5 THF) and [{(η2‐Cp)2(η2;η5‐MeCp)MnK(thf)}]⋅2 THF (2⋅2 THF) and ion‐separated complexes [Mg(thf)6][(η2‐Cp)3Mn]2 (3), [Mg(thf)6][(η2‐Cp)(η2‐MeCp)2Mn)]2⋅0.5 THF (4⋅0.5 THF), [Mg(thf)6][(η2‐MeCp)3Mn)]2⋅0.5 THF (5⋅0.5 THF) and [Li([12]crown‐4)]5[(η‐Cp)3Mn]5 (6) (Cp=C5H5, CpMe=C5H4CH3), have been prepared and structurally characterised. The effects of varying the Cp and CpMe ligands in complexes 1–5 have been probed by variable‐temperature magnetic susceptibility measurements and EPR spectroscopic studies.
Making contact! A series of complexes containing ion‐separated and ion‐paired [Cp3−x(CpMe)xMn]− ions have been structurally characterised. The ion‐paired complexes, which form similar graphite‐like lattices with K+ counterions, are composed of six‐membered K3Mn3 ring units linked by cyclopentadienyl ligands (see picture). The electronic and magnetic properties are investigated by using variable‐temperature magnetic measurements and ESR spectroscopy. |
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| AbstractList | The ion‐contact complexes [{(η5‐Cp)2Mn(η2:η5‐Cp)K}3]⋅0.5 THF (1⋅0.5 THF) and [{(η2‐Cp)2(η2;η5‐MeCp)MnK(thf)}]⋅2 THF (2⋅2 THF) and ion‐separated complexes [Mg(thf)6][(η2‐Cp)3Mn]2 (3), [Mg(thf)6][(η2‐Cp)(η2‐MeCp)2Mn)]2⋅0.5 THF (4⋅0.5 THF), [Mg(thf)6][(η2‐MeCp)3Mn)]2⋅0.5 THF (5⋅0.5 THF) and [Li([12]crown‐4)]5[(η‐Cp)3Mn]5 (6) (Cp=C5H5, CpMe=C5H4CH3), have been prepared and structurally characterised. The effects of varying the Cp and CpMe ligands in complexes 1–5 have been probed by variable‐temperature magnetic susceptibility measurements and EPR spectroscopic studies.
Making contact! A series of complexes containing ion‐separated and ion‐paired [Cp3−x(CpMe)xMn]− ions have been structurally characterised. The ion‐paired complexes, which form similar graphite‐like lattices with K+ counterions, are composed of six‐membered K3Mn3 ring units linked by cyclopentadienyl ligands (see picture). The electronic and magnetic properties are investigated by using variable‐temperature magnetic measurements and ESR spectroscopy. Abstract The ion‐contact complexes [{(η 5 ‐Cp) 2 Mn(η 2 :η 5 ‐Cp)K} 3 ]⋅0.5 THF ( 1 ⋅0.5 THF) and [{(η 2 ‐Cp) 2 (η 2 ;η 5 ‐MeCp)MnK(thf)}]⋅2 THF ( 2 ⋅2 THF) and ion‐separated complexes [Mg(thf) 6 ][(η 2 ‐Cp) 3 Mn] 2 ( 3 ), [Mg(thf) 6 ][(η 2 ‐Cp)(η 2 ‐MeCp) 2 Mn)] 2 ⋅0.5 THF ( 4 ⋅0.5 THF), [Mg(thf) 6 ][(η 2 ‐MeCp) 3 Mn)] 2 ⋅0.5 THF ( 5 ⋅0.5 THF) and [Li([12]crown‐4)] 5 [(η‐Cp) 3 Mn] 5 ( 6 ) (Cp=C 5 H 5 , CpMe=C 5 H 4 CH 3 ), have been prepared and structurally characterised. The effects of varying the Cp and CpMe ligands in complexes 1 – 5 have been probed by variable‐temperature magnetic susceptibility measurements and EPR spectroscopic studies. |
| Author | Wright, Dominic S. Alvarez, Carmen Soria Bashall, Alan Mole, Richard A. Wood, Paul T. McInnes, Eric J. L. Layfield, Richard A. McPartlin, Mary Rawson, Jeremy M. |
| Author_xml | – sequence: 1 givenname: Carmen Soria surname: Alvarez fullname: Alvarez, Carmen Soria organization: University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362 – sequence: 2 givenname: Alan surname: Bashall fullname: Bashall, Alan organization: School of Chemistry, London Metropolitan University, Holloway Road, London N7 8DB, UK – sequence: 3 givenname: Eric J. L. surname: McInnes fullname: McInnes, Eric J. L. organization: Department of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK – sequence: 4 givenname: Richard A. surname: Layfield fullname: Layfield, Richard A. email: ral34@cam.ac.uk organization: University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362 – sequence: 5 givenname: Richard A. surname: Mole fullname: Mole, Richard A. organization: University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362 – sequence: 6 givenname: Mary surname: McPartlin fullname: McPartlin, Mary organization: School of Chemistry, London Metropolitan University, Holloway Road, London N7 8DB, UK – sequence: 7 givenname: Jeremy M. surname: Rawson fullname: Rawson, Jeremy M. email: jmr31@cam.ac.uk organization: University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362 – sequence: 8 givenname: Paul T. surname: Wood fullname: Wood, Paul T. organization: University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362 – sequence: 9 givenname: Dominic S. surname: Wright fullname: Wright, Dominic S. email: dsw1000@cus.cam.ac.uk organization: University of Cambridge, Department of Chemistry, Lensfield Road, Cambridge, CB2 1EW, UK, Fax: (+44) 1223-336-362 |
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| CitedBy_id | crossref_primary_10_1021_om300478v crossref_primary_10_1039_c3dt51632f crossref_primary_10_1016_j_ica_2009_06_023 crossref_primary_10_1039_C9DT03551F crossref_primary_10_1039_B700409E crossref_primary_10_1002_ange_200700925 crossref_primary_10_1021_om200381p crossref_primary_10_1039_c2cc32893c crossref_primary_10_1002_anie_200700925 crossref_primary_10_1039_C8DT00537K crossref_primary_10_1002_ange_200603875 crossref_primary_10_1002_anie_200603875 crossref_primary_10_1002_zaac_201400302 crossref_primary_10_1039_c2cc35213c crossref_primary_10_1002_zaac_200700351 crossref_primary_10_1021_om801135d crossref_primary_10_1039_b708850g crossref_primary_10_1021_ic302320w crossref_primary_10_1021_om100162j crossref_primary_10_1039_C4SC00666F crossref_primary_10_1021_cr3002966 crossref_primary_10_1039_c2sc20737k crossref_primary_10_1039_c1cc10194c |
| Cites_doi | 10.1039/c39950001141 10.1039/b106366a 10.1039/c39720000687 10.1039/b111486g 10.1007/978-3-642-70733-9 10.1002/ange.19961080122 10.1002/ange.19941061717 10.1021/ja025709f 10.1021/ja00832a049 10.1002/(SICI)1521-3757(19980504)110:9<1357::AID-ANGE1357>3.0.CO;2-J 10.1002/anie.199417441 10.1016/S0010-8545(98)00113-1 10.1515/zna-1972-0706 10.1021/cr941099t 10.1039/f29747000356 10.1002/anie.199600971 10.1016/0020-1650(79)80143-9 10.1021/om980777p 10.1039/a827225z 10.1016/0301-0104(80)80040-1 10.1016/0022-1902(56)80004-3 10.1016/S0022-328X(00)94124-X 10.1002/(SICI)1521-3773(19980518)37:9<1239::AID-ANIE1239>3.0.CO;2-Y 10.1016/0022-1902(59)80015-4 10.1063/1.1677256 10.1021/ja00832a012 10.1016/S0010-8545(01)00298-3 10.1021/om020928v 10.1002/1521-3765(20020603)8:11<2526::AID-CHEM2526>3.0.CO;2-I |
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| Snippet | The ion‐contact complexes [{(η5‐Cp)2Mn(η2:η5‐Cp)K}3]⋅0.5 THF (1⋅0.5 THF) and [{(η2‐Cp)2(η2;η5‐MeCp)MnK(thf)}]⋅2 THF (2⋅2 THF) and ion‐separated complexes... Abstract The ion‐contact complexes [{(η 5 ‐Cp) 2 Mn(η 2 :η 5 ‐Cp)K} 3 ]⋅0.5 THF ( 1 ⋅0.5 THF) and [{(η 2 ‐Cp) 2 (η 2 ;η 5 ‐MeCp)MnK(thf)}]⋅2 THF ( 2 ⋅2 THF)... |
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| SubjectTerms | cyclopentadienyl ligands magnetic properties manganese structure elucidation |
| Title | Structural and Magnetic Studies of the Tris(cyclopentadienyl)manganese(II) "Paddle-Wheel" Anions [Cp3−n(MeCp)nMn]− (n=0-3, MeCp=C5H4CH3, Cp=C5H5) |
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| Volume | 12 |
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