A Novel Electrochemical Sensor for Detection of Molinate Using ZnO Nanoparticles Loaded Carbon Electrode
In this work, electrochemical detection of molinate herbicide was studied by developing a novel sensor based on carbon paste incorporated with zinc oxide (ZnO) nanoparticles using cyclic (CV) and square wave voltammetric (SWV) techniques. Molinate exhibited one well resolved peak at pH of 3.0 phosph...
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| Published in | Electroanalysis (New York, N.Y.) Vol. 31; no. 6; pp. 1040 - 1049 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.06.2019
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| Subjects | |
| Online Access | Get full text |
| ISSN | 1040-0397 1521-4109 |
| DOI | 10.1002/elan.201800775 |
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| Abstract | In this work, electrochemical detection of molinate herbicide was studied by developing a novel sensor based on carbon paste incorporated with zinc oxide (ZnO) nanoparticles using cyclic (CV) and square wave voltammetric (SWV) techniques. Molinate exhibited one well resolved peak at pH of 3.0 phosphate buffer solution (PBS), which was irreversible. The lowest possible detection limit of 1.0×10−8 M was achieved in the concentration range of 0.002 μM to 0.25 μM. The modifying ability of ZnO nanoparticles was responsible for such a low level sensing in water and soil samples. |
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| AbstractList | In this work, electrochemical detection of molinate herbicide was studied by developing a novel sensor based on carbon paste incorporated with zinc oxide (ZnO) nanoparticles using cyclic (CV) and square wave voltammetric (SWV) techniques. Molinate exhibited one well resolved peak at pH of 3.0 phosphate buffer solution (PBS), which was irreversible. The lowest possible detection limit of 1.0×10
−8
M was achieved in the concentration range of 0.002 μM to 0.25 μM. The modifying ability of ZnO nanoparticles was responsible for such a low level sensing in water and soil samples. In this work, electrochemical detection of molinate herbicide was studied by developing a novel sensor based on carbon paste incorporated with zinc oxide (ZnO) nanoparticles using cyclic (CV) and square wave voltammetric (SWV) techniques. Molinate exhibited one well resolved peak at pH of 3.0 phosphate buffer solution (PBS), which was irreversible. The lowest possible detection limit of 1.0×10−8 M was achieved in the concentration range of 0.002 μM to 0.25 μM. The modifying ability of ZnO nanoparticles was responsible for such a low level sensing in water and soil samples. |
| Author | Shetti, Nagaraj P. Malode, Shweta J. Ilager, Davalasab Raghava Reddy, Kakarla Aminabhavi, Tejraj M. Shukla, Shyam S. |
| Author_xml | – sequence: 1 givenname: Nagaraj P. surname: Shetti fullname: Shetti, Nagaraj P. email: dr.npshetti@gmail.com organization: Lamar University – sequence: 2 givenname: Shweta J. surname: Malode fullname: Malode, Shweta J. organization: Visvesvaraya Technological University Karnataka – sequence: 3 givenname: Davalasab surname: Ilager fullname: Ilager, Davalasab organization: Visvesvaraya Technological University Karnataka – sequence: 4 givenname: Kakarla surname: Raghava Reddy fullname: Raghava Reddy, Kakarla organization: The University of Sydney – sequence: 5 givenname: Shyam S. surname: Shukla fullname: Shukla, Shyam S. organization: Lamar University – sequence: 6 givenname: Tejraj M. surname: Aminabhavi fullname: Aminabhavi, Tejraj M. organization: Lamar University |
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| SubjectTerms | Analysis Carbon paste Electrochemical degradation Molinate ZnO modifier |
| Title | A Novel Electrochemical Sensor for Detection of Molinate Using ZnO Nanoparticles Loaded Carbon Electrode |
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