Synthesis, spectral, magnetic properties, electrochemical evaluation and SOD mimetic activity of four mixed-ligand Cu(II) complexes

• Published in: Inorganica Chimica Acta Vol. 455; pp. 298 - 306
• Main Authors: Puchoňová, Miroslava, Švorec, Jozef, Švorc, Ľubomír, Pavlik, Ján, Mazúr, Milan, Dlháň, Ľubor, Růžičková, Zdeňka, Moncoľ, Ján, Valigura, Dušan
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 30.01.2017; Elsevier Science Ltd
• Subjects: Coordination compounds; Coordination polymers; Copper; Copper compounds; Cyclic voltammetry; Electrochemical analysis; Imidazole; Iridium; Ligands; Magnetic measurement; Magnetic properties; Methylsalicylato copper(II) complexes; Molecular structure; SOD mimetic activity; Structure; Superoxide dismutase; Ultraviolet radiation; Cyclic voltammetry; SOD mimetic activity; Methylsalicylato copper(II) complexes; Structure; Magnetic properties

Four new methylsalicylato copper(II) complexes are reported. Despite common coordination environment {CuO2N2O′2} various supramolecular structures were found. The exceptionally low SOD-like activity of one of complexes was found, which appears to be related to the distortion of its coordination envi...