Formation, reactivity, photorelease, and scavenging of NO in ruthenium nitrosyl complexes

• Published in: Inorganica Chimica Acta Vol. 502; p. 119360
• Main Authors: Giri, Bishnubasu, Kumbhakar, Sadananda, Kalai Selvan, K., Muley, Arabinda, Maji, Somnath
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.03.2020; Elsevier Science Ltd
• Subjects: Acetonitrile; Crystal structure; Deoxygenation; Electrochemistry; Ligand design; Myoglobins; Nitrogen dioxide; Photocleavage; Room temperature; Ruthenium; Scavenging; Single crystals; Spectra; Structure; Electrochemistry; Ligand design; Spectra; Ruthenium; Structure; Photocleavage

The co-ligands dmdptz: (N,N-dimethyl-4,6-di(pyridin-2-yl)-1,3,5-triazin-2-amine) and phen: (1,10-phenanthroline) in the selective framework [RuII(dmdptz)(phen)(NO)]n+ stabilized both in {RuNO}6 and {RuNO}7 configurations. A sizeable shift in ν(NO) frequency (Δν = 361cm−1) has been observed on moving...