Synthesis of ZnO nanoparticles and its application in photocatalytic degradation of LABS by the trial-and-error and Taguchi methods
In the work ZnO nanoparticles were prepared by sol-gel method. The catalyst was characterized by X-ray powder diffractometer (XRD), scanning electron microscopy (SEM). The photocatalytic oxidation of anionic surfactant in detergent industries was studied using ZnO nanoparticles with diameter size 20...
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| Published in | Russian journal of applied chemistry Vol. 89; no. 5; pp. 823 - 829 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.05.2016
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| Subjects | |
| Online Access | Get full text |
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| Abstract | In the work ZnO nanoparticles were prepared by sol-gel method. The catalyst was characterized by X-ray powder diffractometer (XRD), scanning electron microscopy (SEM). The photocatalytic oxidation of anionic surfactant in detergent industries was studied using ZnO nanoparticles with diameter size 20 nm as catalyst on irradiation with UV light. Analysis of kinetic showed that the amount of surfactant photocatalytic degradation can be fitted with pseudo-first-order model and studied photochemical elimination of Linear alkyl benzene sulfonates by the trial-and-error and Taguchi methods. Our experimental design consisted of testing five factors, i.e. dosage of K
2
S
2
O
8
, concentration of surfactant, amount of ZnO, irradiation time, and initial pH. The results showed that photocatalytic degradation of linear alkyl benzene sulfonates was strongly influenced by these parameters. |
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| AbstractList | In the work ZnO nanoparticles were prepared by sol-gel method. The catalyst was characterized by X-ray powder diffractometer (XRD), scanning electron microscopy (SEM). The photocatalytic oxidation of anionic surfactant in detergent industries was studied using ZnO nanoparticles with diameter size 20 nm as catalyst on irradiation with UV light. Analysis of kinetic showed that the amount of surfactant photocatalytic degradation can be fitted with pseudo-first-order model and studied photochemical elimination of Linear alkyl benzene sulfonates by the trial-and-error and Taguchi methods. Our experimental design consisted of testing five factors, i.e. dosage of K
2
S
2
O
8
, concentration of surfactant, amount of ZnO, irradiation time, and initial pH. The results showed that photocatalytic degradation of linear alkyl benzene sulfonates was strongly influenced by these parameters. |
| Author | Toutounchi, S. Giahi, M. |
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| Cites_doi | 10.1016/S1010-6030(02)00374-X 10.1021/jp013602t 10.5012/bkcs.2013.34.7.2176 10.1134/S10704272150120228 10.1039/f19858100449 10.1016/j.apcatb.2003.11.010 10.1016/S1010-6030(01)00423-3 10.1134/S0036024412130080 10.1016/S0273-1223(97)00027-9 10.1016/S0048-9697(98)00395-7 10.1016/j.apcatb.2004.02.006 10.1021/cr00017a016 10.1016/S0920-5861(02)00222-5 10.1016/j.apcatb.2005.07.006 10.1016/j.jphotochem.2004.02.018 10.1016/j.jphotochem.2005.02.015 10.1016/S0045-6535(99)00313-6 10.1016/0021-9517(86)90028-X 10.1016/S0927-0248(02)00255-6 10.1016/S1010-6030(97)00318-3 |
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| Title | Synthesis of ZnO nanoparticles and its application in photocatalytic degradation of LABS by the trial-and-error and Taguchi methods |
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