An unusual diverse coordination of silver(I) with N-allylthiohydantoin ligand in the presence of benzene- and p-toluenesulfonate anions

• Published in: Inorganica Chimica Acta Vol. 484; pp. 79 - 86
• Main Authors: Fedorchuk, A.A., Slyvka, Yu.I., Kinzhybalo, V., Lis, T., Mys'kiv, M.G.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.01.2019; Elsevier Science Ltd
• Subjects: Anions; Atoms & subatomic particles; Benzene; Benzenesulfonate anion; Coordination compounds; Crystal structure; Ligands; Metals; Organic chemicals; Polymers; Serpentine; Silver; Silver(I); Thiohydantoin; Toluenesulfonate anion; Silver(I); Benzenesulfonate anion; Toluenesulfonate anion; Thiohydantoin; Crystal structure

[Display omitted] •Two novel complexes with unusual diverse coordination of Ag(I) with N-allylthiohydantoin were studied.•Different Ag(I) arrangements are determined by variable thiohydantoin coordination modes.•Simulations presence of molecular ligand and its ionic form were observed. Crystalline s...