Spin crossover in iron(II) complexes with new ligand 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine

• Published in: Inorganica Chimica Acta Vol. 532; p. 120746
• Main Authors: Ivanova, Alina D., Korotaev, Evgeniy V., Komarov, Vladislav Yu, Sukhikh, Taisiya S., Trubina, Svetlana V., Sheludyakova, Liliya A., Petrov, Sergey A., Tikhonov, Alexsei Ya, Lavrenova, Lyudmila G.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.03.2022; Elsevier Science Ltd
• Subjects: 2,6-bis(4,5-dimethyl-1H-imidazol-2-yl)pyridine; Composition; Coordination compounds; Crossovers; Crystal structure; Dehydration; EXAFS spectroscopy; Fine structure; High temperature; Imidazole; Iron; Iron(II) complexes; Ligands; Magnetic permeability; Mössbauer spectroscopy; Pyridines; Spin crossover; Temperature dependence; X ray absorption; EXAFS spectroscopy; Iron(II) complexes; 2,6-bis(4,5-dimethyl-1H-imidazol-2-yl)pyridine; Mössbauer spectroscopy; Spin crossover; Crystal structure

Iron(II) complexes with new ligand 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine possessing a high-temperature 1A1 ↔ 5T2 spin crossover were obtained. [Display omitted] •Fe(II) complexes with 2,6-bis(4,5-dimethyl-1H-imidazole-2-yl)pyridine are studied.•Fe(II) complexes exhibit high-temperature 1A1...