Graphene oxide/chitosan nanocomposite coated quartz crystal microbalance sensor for detection of amine vapors

•Graphene oxide/chitosan (GO/CS) nanocomposite prepared with a facile approach was used as the sensing material for a QCM sensor.•The QCM sensor based on the GO/CS nanocomposite provided a highly selective method for sensitive amine vapor detection.•The combination of CS and GO improved the sensor p...

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Published inSensors and actuators. B, Chemical Vol. 243; pp. 721 - 730
Main Authors Zhang, Kaihuan, Hu, Ruifen, Fan, Guokang, Li, Guang
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 01.05.2017
Elsevier Science Ltd
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Abstract •Graphene oxide/chitosan (GO/CS) nanocomposite prepared with a facile approach was used as the sensing material for a QCM sensor.•The QCM sensor based on the GO/CS nanocomposite provided a highly selective method for sensitive amine vapor detection.•The combination of CS and GO improved the sensor performances significantly in comparison with individual GO and CS. Graphene oxide/chitosan (GO/CS) nanocomposite was synthesized using a facile method and employed as the sensing material of a quartz crystal microbalance (QCM) sensor to detect amine vapors. Scanning election microscopy (SEM), Fourier transform infrared spectrometer (FT-IR) and UV–visible spectra analysis were performed to characterize the morphology and physicochemical properties of the nanocomposite. The GO/CS obtained was in a porous mesh structure composed of interconnected nanofibers with diameters of approximately 50nm. A GO/CS functionalized QCM sensor was fabricated and its sensing properties were investigated. Being tested at room temperature, the sensor exhibited high sensitivity to aliphatic amines including methylamine (MA), dimethylamine (DMA) and trimethylamine (TMA), with the sensitivity values of 2.7, 2.3 and 4.8Hz/ppm, respectively. Their detection limits were all below 3ppm. The sensor maintained reasonable reversibility, repeatability as well as long-term stability. Combining the specific adsorption properties of chitosan (CS) with some inherent properties of graphene oxide (GO), the GO/CS coated sensor also performed favorable selectivity, especially for MA, DMA and TMA. The sensing mechanism might involve an adsorption–desorption process mainly caused by hydrogen bonding of the protonated amine and hydroxyl sites of the GO/CS film with the amine vapors. The underlying analyte sorption properties were further investigated based on the linear solvation energy relationship (LSER) model. This work might contribute to the future development of sensors for detection of amine vapors and broaden the application of GO and CS composite materials.
AbstractList •Graphene oxide/chitosan (GO/CS) nanocomposite prepared with a facile approach was used as the sensing material for a QCM sensor.•The QCM sensor based on the GO/CS nanocomposite provided a highly selective method for sensitive amine vapor detection.•The combination of CS and GO improved the sensor performances significantly in comparison with individual GO and CS. Graphene oxide/chitosan (GO/CS) nanocomposite was synthesized using a facile method and employed as the sensing material of a quartz crystal microbalance (QCM) sensor to detect amine vapors. Scanning election microscopy (SEM), Fourier transform infrared spectrometer (FT-IR) and UV–visible spectra analysis were performed to characterize the morphology and physicochemical properties of the nanocomposite. The GO/CS obtained was in a porous mesh structure composed of interconnected nanofibers with diameters of approximately 50nm. A GO/CS functionalized QCM sensor was fabricated and its sensing properties were investigated. Being tested at room temperature, the sensor exhibited high sensitivity to aliphatic amines including methylamine (MA), dimethylamine (DMA) and trimethylamine (TMA), with the sensitivity values of 2.7, 2.3 and 4.8Hz/ppm, respectively. Their detection limits were all below 3ppm. The sensor maintained reasonable reversibility, repeatability as well as long-term stability. Combining the specific adsorption properties of chitosan (CS) with some inherent properties of graphene oxide (GO), the GO/CS coated sensor also performed favorable selectivity, especially for MA, DMA and TMA. The sensing mechanism might involve an adsorption–desorption process mainly caused by hydrogen bonding of the protonated amine and hydroxyl sites of the GO/CS film with the amine vapors. The underlying analyte sorption properties were further investigated based on the linear solvation energy relationship (LSER) model. This work might contribute to the future development of sensors for detection of amine vapors and broaden the application of GO and CS composite materials.
Graphene oxide/chitosan (GO/CS) nanocomposite was synthesized using a facile method and employed as the sensing material of a quartz crystal microbalance (QCM) sensor to detect amine vapors. Scanning election microscopy (SEM), Fourier transform infrared spectrometer (FT-IR) and UV–visible spectra analysis were performed to characterize the morphology and physicochemical properties of the nanocomposite. The GO/CS obtained was in a porous mesh structure composed of interconnected nanofibers with diameters of approximately 50 nm. A GO/CS functionalized QCM sensor was fabricated and its sensing properties were investigated. Being tested at room temperature, the sensor exhibited high sensitivity to aliphatic amines including methylamine (MA), dimethylamine (DMA) and trimethylamine (TMA), with the sensitivity values of 2.7, 2.3 and 4.8 Hz/ppm, respectively. Their detection limits were all below 3 ppm. The sensor maintained reasonable reversibility, repeatability as well as long-term stability. Combining the specific adsorption properties of chitosan (CS) with some inherent properties of graphene oxide (GO), the GO/CS coated sensor also performed favorable selectivity, especially for MA, DMA and TMA. The sensing mechanism might involve an adsorption–desorption process mainly caused by hydrogen bonding of the protonated amine and hydroxyl sites of the GO/CS film with the amine vapors. The underlying analyte sorption properties were further investigated based on the linear solvation energy relationship (LSER) model. This work might contribute to the future development of sensors for detection of amine vapors and broaden the application of GO and CS composite materials.
Author Fan, Guokang
Zhang, Kaihuan
Hu, Ruifen
Li, Guang
Author_xml – sequence: 1
  givenname: Kaihuan
  surname: Zhang
  fullname: Zhang, Kaihuan
  organization: State Key Laboratory of Industrial Control Technology, Institute of Cyber Systems and Control, Zhejiang University, Hangzhou 310027, Zhejiang, China
– sequence: 2
  givenname: Ruifen
  surname: Hu
  fullname: Hu, Ruifen
  organization: State Key Laboratory of Industrial Control Technology, Institute of Cyber Systems and Control, Zhejiang University, Hangzhou 310027, Zhejiang, China
– sequence: 3
  givenname: Guokang
  surname: Fan
  fullname: Fan, Guokang
  organization: School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu, China
– sequence: 4
  givenname: Guang
  surname: Li
  fullname: Li, Guang
  email: guangli@zju.edu.cn
  organization: State Key Laboratory of Industrial Control Technology, Institute of Cyber Systems and Control, Zhejiang University, Hangzhou 310027, Zhejiang, China
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Keywords Graphene oxide/chitosan nanocomposite
Gas sensor
Amine vapor
Quartz crystal microbalance
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Snippet •Graphene oxide/chitosan (GO/CS) nanocomposite prepared with a facile approach was used as the sensing material for a QCM sensor.•The QCM sensor based on the...
Graphene oxide/chitosan (GO/CS) nanocomposite was synthesized using a facile method and employed as the sensing material of a quartz crystal microbalance (QCM)...
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SubjectTerms Adsorption
Aliphatic amines
Amine vapor
Amines
Ammonia
Carbohydrates
Chitosan
Crystals
Detection
Finite element method
Fourier transforms
FTIR spectrometers
Gas sensor
Graphene
Graphene oxide/chitosan nanocomposite
Hydrogen bonding
Infrared analysis
Metals
Microbalances
Morphology
Nanocomposites
Nanofibers
Properties (attributes)
Quartz
Quartz crystal microbalance
Quartz crystals
Sensitivity
Sensors
Solvation
Trimethylamine
Title Graphene oxide/chitosan nanocomposite coated quartz crystal microbalance sensor for detection of amine vapors
URI https://dx.doi.org/10.1016/j.snb.2016.12.063
https://www.proquest.com/docview/2098784495
Volume 243
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