Catalytic pyrolysis of corn straw for deoxygenation of bio-oil with different types of catalysts
Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst...
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Published in | The Korean journal of chemical engineering Vol. 39; no. 5; pp. 1240 - 1247 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
01.05.2022
한국화학공학회 |
Subjects | |
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Abstract | Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxy-genated products and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis process was investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. The results showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 °C and then became stable and finally increased rapidly after 550 °C, indicating that the range of 400–550 °C was the proper temperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO,
δ
-Al
2
O
3
,
γ
-Al
2
O
3
, acidified-
α
-Al
2
O
3
and acidified-
γ
-Al
2
O
3
) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation of bio-oil with more produced CO
2
, while a higher acidity was promoted the decrease of alcohols and carbonyls with more generation of H
2
O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The quality of bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C. |
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AbstractList | Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxy-genated products and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis process was investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. The results showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 °C and then became stable and finally increased rapidly after 550 °C, indicating that the range of 400–550 °C was the proper temperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO,
δ
-Al
2
O
3
,
γ
-Al
2
O
3
, acidified-
α
-Al
2
O
3
and acidified-
γ
-Al
2
O
3
) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation of bio-oil with more produced CO
2
, while a higher acidity was promoted the decrease of alcohols and carbonyls with more generation of H
2
O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The quality of bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C. Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severelyrestricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and thedeoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxygenatedproducts and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis processwas investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. Theresults showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 oC andthen became stable and finally increased rapidly after 550 oC, indicating that the range of 400-550 oC was the propertemperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO, -Al2O3, -Al2O3, acidified--Al2O3 andacidified--Al2O3) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation ofbio-oil with more produced CO2, while a higher acidity was promoted the decrease of alcohols and carbonyls withmore generation of H2O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The qualityof bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C. KCI Citation Count: 2 |
Author | Li, Songgeng Song, Wenli Ge, Tengze Wang, Ze Yang, Cuiguang Zhang, Wenkai Ma, Rui |
Author_xml | – sequence: 1 givenname: Wenkai surname: Zhang fullname: Zhang, Wenkai organization: State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Sino-Danish College, University of Chinese Academy of Sciences/Sino-Danish Center for Education and Research – sequence: 2 givenname: Ze surname: Wang fullname: Wang, Ze email: wangze@ipe.ac.cn organization: State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Sino-Danish College, University of Chinese Academy of Sciences/Sino-Danish Center for Education and Research – sequence: 3 givenname: Tengze surname: Ge fullname: Ge, Tengze organization: Petrochina CoalBed Methane Company Limited – sequence: 4 givenname: Cuiguang surname: Yang fullname: Yang, Cuiguang organization: Yunnan Water Investment Company Limited – sequence: 5 givenname: Wenli surname: Song fullname: Song, Wenli organization: State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Sino-Danish College, University of Chinese Academy of Sciences/Sino-Danish Center for Education and Research – sequence: 6 givenname: Songgeng surname: Li fullname: Li, Songgeng organization: State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Sino-Danish College, University of Chinese Academy of Sciences/Sino-Danish Center for Education and Research – sequence: 7 givenname: Rui surname: Ma fullname: Ma, Rui organization: State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences |
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Cites_doi | 10.1016/j.biortech.2018.11.008 10.1016/j.apcata.2017.05.002 10.1016/j.jaap.2021.105079 10.1007/s11814-019-0467-8 10.1016/j.joei.2018.07.017 10.1016/j.fuel.2020.118807 10.1016/j.biortech.2020.124415 10.1016/j.apcatb.2015.11.017 10.1016/j.renene.2020.12.098 10.1016/j.fuproc.2019.106223 10.1007/s11814-016-0214-3 10.1021/ef1009605 10.1021/acs.energyfuels.9b00906 10.1016/j.biortech.2019.02.118 10.1021/acssuschemeng.5b01606 10.1016/j.biortech.2014.10.012 10.1016/j.cej.2020.124878 10.1016/j.jaap.2019.02.001 |
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Keywords | Pyrolysis Catalysis Corn Straw Deoxygenation Bio-oil |
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Snippet | Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen.... Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severelyrestricted due to the high content of oxygen.... |
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Title | Catalytic pyrolysis of corn straw for deoxygenation of bio-oil with different types of catalysts |
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ispartofPNX | Korean Journal of Chemical Engineering, 2022, 39(5), 266, pp.1240-1247 |
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