Catalytic pyrolysis of corn straw for deoxygenation of bio-oil with different types of catalysts

Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst...

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Published inThe Korean journal of chemical engineering Vol. 39; no. 5; pp. 1240 - 1247
Main Authors Zhang, Wenkai, Wang, Ze, Ge, Tengze, Yang, Cuiguang, Song, Wenli, Li, Songgeng, Ma, Rui
Format Journal Article
LanguageEnglish
Published New York Springer US 01.05.2022
한국화학공학회
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Abstract Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxy-genated products and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis process was investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. The results showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 °C and then became stable and finally increased rapidly after 550 °C, indicating that the range of 400–550 °C was the proper temperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO, δ -Al 2 O 3 , γ -Al 2 O 3 , acidified- α -Al 2 O 3 and acidified- γ -Al 2 O 3 ) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation of bio-oil with more produced CO 2 , while a higher acidity was promoted the decrease of alcohols and carbonyls with more generation of H 2 O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The quality of bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C.
AbstractList Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxy-genated products and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis process was investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. The results showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 °C and then became stable and finally increased rapidly after 550 °C, indicating that the range of 400–550 °C was the proper temperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO, δ -Al 2 O 3 , γ -Al 2 O 3 , acidified- α -Al 2 O 3 and acidified- γ -Al 2 O 3 ) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation of bio-oil with more produced CO 2 , while a higher acidity was promoted the decrease of alcohols and carbonyls with more generation of H 2 O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The quality of bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C.
Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severelyrestricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and thedeoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxygenatedproducts and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis processwas investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. Theresults showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 oC andthen became stable and finally increased rapidly after 550 oC, indicating that the range of 400-550 oC was the propertemperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO, -Al2O3, -Al2O3, acidified--Al2O3 andacidified--Al2O3) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation ofbio-oil with more produced CO2, while a higher acidity was promoted the decrease of alcohols and carbonyls withmore generation of H2O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The qualityof bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C. KCI Citation Count: 2
Author Li, Songgeng
Song, Wenli
Ge, Tengze
Wang, Ze
Yang, Cuiguang
Zhang, Wenkai
Ma, Rui
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  organization: State Key Laboratory of Multi-Phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences
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Keywords Pyrolysis
Catalysis
Corn Straw
Deoxygenation
Bio-oil
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한국화학공학회
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SSID ssj0055620
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Snippet Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen....
Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severelyrestricted due to the high content of oxygen....
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SubjectTerms Biotechnology
Catalysis
Chemistry
Chemistry and Materials Science
Environmental Engineering
Industrial Chemistry/Chemical Engineering
Materials Science
화학공학
Title Catalytic pyrolysis of corn straw for deoxygenation of bio-oil with different types of catalysts
URI https://link.springer.com/article/10.1007/s11814-021-1018-7
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Volume 39
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