Catalytic pyrolysis of corn straw for deoxygenation of bio-oil with different types of catalysts

• Published in: The Korean journal of chemical engineering Vol. 39; no. 5; pp. 1240 - 1247
• Main Authors: Zhang, Wenkai, Wang, Ze, Ge, Tengze, Yang, Cuiguang, Song, Wenli, Li, Songgeng, Ma, Rui
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.05.2022; 한국화학공학회
• Subjects: Biotechnology; Catalysis; Chemistry; Chemistry and Materials Science; Environmental Engineering; Industrial Chemistry/Chemical Engineering; Materials Science; 화학공학; Pyrolysis; Catalysis; Corn Straw; Deoxygenation; Bio-oil
• ISSN: 0256-1115; 1975-7220
• DOI: 10.1007/s11814-021-1018-7

Corn straw can be converted to bio-oil through pyrolysis. However, the application of bio-oil is severely restricted due to the high content of oxygen. Catalytic pyrolysis is an available way for deoxygenation of bio-oil, and the deoxygenation reactions are strongly dependent on the type of catalyst. Whereas, the correlation between the deoxy-genated products and the catalyst types is still far from clear. In this work, the migration of O in the pyrolysis process was investigated, and eight catalysts were screened for deoxygenation of bio-oil, with a lab-scale fixed-bed reactor. The results showed that with the increase of pyrolysis temperature, the content of O in bio-oil decreased below 400 °C and then became stable and finally increased rapidly after 550 °C, indicating that the range of 400–550 °C was the proper temperature for deoxygenation. Eight catalysts (ZSM-5, SAPO-34, ZnO, MgO, δ -Al 2 O 3 , γ -Al 2 O 3 , acidified- α -Al 2 O 3 and acidified- γ -Al 2 O 3 ) were tested, and it was found that a higher alkalinity of catalyst was favorable for decarboxylation of bio-oil with more produced CO 2 , while a higher acidity was promoted the decrease of alcohols and carbonyls with more generation of H 2 O and/or CO. MgO was judged as the optimal catalyst for deoxygenation of bio-oil. The quality of bio-oil under the catalysis of MgO was best, with higher H/C and lower O/C.