Impedance and Dielectric Spectroscopy of Functional Materials: A Critical Evaluation of the Two Techniques
Impedance and dielectric spectroscopies are closely related techniques for measuring the electrical properties of materials. The techniques differ in two ways. First, impedance measurements are usually made over several decades of frequency (i.e. broadband) whereas most dielectric measurements are m...
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Published in | Journal of the Electrochemical Society Vol. 170; no. 11; pp. 116504 - 116517 |
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Format | Journal Article |
Language | English |
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Abstract | Impedance and dielectric spectroscopies are closely related techniques for measuring the electrical properties of materials. The techniques differ in two ways. First, impedance measurements are usually made over several decades of frequency (i.e. broadband) whereas most dielectric measurements are made at fixed frequency. Second, time constants that control semicircles in impedance complex plane plots and peaks in permittivity or tan
δ
spectroscopic plots are not the same. Differences between the techniques are confined to data analysis procedures and interpretation since they use similar instrumentation for measurements and data collection. In impedance data, time constants represent conducting components and parallel resistance-capacitance (RC) combinations; in permittivity data, they represent dielectric processes and series RC combinations. Using broadband data, it is possible to (i) determine the best equivalent circuit to fit experimental data, (ii) unambiguously evaluate and assign resistance, capacitance, and time constant parameters to regions of the material being measured and (iii) quantify departures from ideality using constant phase elements, CPEs. Using fixed frequency, variable temperature data in either impedance or dielectric methodologies, it is possible to detect the presence of different electrical components that contribute to a data set. However, it is not possible to separate the effects of frequency and temperature in terms of equivalent circuits, nor to deconvolute, parametrise, quantify, and assign the results to different regions of the sample. The advantages of using broadband measurements are highlighted with two examples: calcium copper titanate, CCTO which is often, erroneously, described as a giant or colossal dielectric; lead magnesium niobate, PMN, the classic relaxor ferroelectric whose characteristic properties are controlled entirely by the presence of non-ideality, represented by a CPE, in its equivalent circuit. |
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AbstractList | Impedance and dielectric spectroscopies are closely related techniques for measuring the electrical properties of materials. The techniques differ in two ways. First, impedance measurements are usually made over several decades of frequency (i.e. broadband) whereas most dielectric measurements are made at fixed frequency. Second, time constants that control semicircles in impedance complex plane plots and peaks in permittivity or tan
δ
spectroscopic plots are not the same. Differences between the techniques are confined to data analysis procedures and interpretation since they use similar instrumentation for measurements and data collection. In impedance data, time constants represent conducting components and parallel resistance-capacitance (RC) combinations; in permittivity data, they represent dielectric processes and series RC combinations. Using broadband data, it is possible to (i) determine the best equivalent circuit to fit experimental data, (ii) unambiguously evaluate and assign resistance, capacitance, and time constant parameters to regions of the material being measured and (iii) quantify departures from ideality using constant phase elements, CPEs. Using fixed frequency, variable temperature data in either impedance or dielectric methodologies, it is possible to detect the presence of different electrical components that contribute to a data set. However, it is not possible to separate the effects of frequency and temperature in terms of equivalent circuits, nor to deconvolute, parametrise, quantify, and assign the results to different regions of the sample. The advantages of using broadband measurements are highlighted with two examples: calcium copper titanate, CCTO which is often, erroneously, described as a giant or colossal dielectric; lead magnesium niobate, PMN, the classic relaxor ferroelectric whose characteristic properties are controlled entirely by the presence of non-ideality, represented by a CPE, in its equivalent circuit. |
Author | Ramírez-González, Julia West, Anthony R. Sinclair, Derek C. |
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Cites_doi | 10.1038/s43586-021-00039-w 10.1063/1.5016561 10.1002/adma.19900020304 10.1111/j.1551-2916.2006.01184.x 10.1039/b910871h 10.1016/S0167-2738(99)00216-7 10.1103/PhysRevB.19.3593 10.1016/j.jssc.2004.05.009 10.1149/1.2119778 10.1023/B:JECR.0000011215.56084.87 10.1016/j.matchemphys.2020.123034 10.1016/S0038-1098(00)00182-4 10.1021/acsami.5b07467 10.1002/pssa.2210750240 10.1038/267673a0 10.1016/0022-3697(69)90039-0 10.1038/nmat3691 10.1016/j.physb.2017.07.048 10.1016/j.ceramint.2017.09.149 10.1088/0953-8984/11/46/310 10.1039/D2TC03914A 10.1063/1.1463211 10.1016/S0038-1098(99)00153-2 10.1016/S0022-0728(76)80229-X 10.1063/1.3106639 10.1063/1.3253743 10.1016/0167-2738(83)90063-2 10.1063/1.1750906 10.1080/00150199908014812 10.1179/174328406X101328 10.1016/0032-3861(67)90021-3 10.1016/j.jallcom.2020.158060 10.1140/epjst/e2010-01212-5 10.1016/S0022-0728(97)00490-7 10.1039/D0TC03539D 10.1038/s41563-018-0112-7 10.1063/1.1747496 10.1016/S0022-0728(98)00115-6 10.1002/1521-4095(20020916)14:18<1321::AID-ADMA1321>3.0.CO;2-P 10.1039/C7CP05236G 10.1103/PhysRevLett.92.157601 10.1038/s42005-021-00775-1 10.1088/0022-3727/39/7/S03 10.1002/9781118202470.ch3 10.1080/00150198708016945 10.1038/s41467-019-10665-4 10.1038/266042a0 10.1016/0038-1101(80)90028-3 10.1109/57.63055 10.1016/j.jpowsour.2021.230577 10.1063/1.344049 10.1016/0022-3093(94)90668-8 10.1126/science.1061655 10.1016/0955-2219(93)90127-D 10.1021/acs.jpcc.0c10853 10.1109/57.55287 10.1080/00018732.2011.555385 10.1103/PhysRevB.73.094124 10.1006/jssc.2000.8703 10.1016/j.matpr.2020.11.790 |
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References | Almond (jesad09fabib46) 2006; 39 Zhang (jesad09fabib14) 2018; 44 Weiss (jesad09fabib28) 2017; 19 Daniel (jesad09fabib2) 1967 Homes (jesad09fabib51) 2001; 293 Bisquert (jesad09fabib44) 1998; 452 Zoltowski (jesad09fabib43) 1998; 443 Sinclair (jesad09fabib33) 1989; 66 Li (jesad09fabib56) 2009; 106 Krogstad (jesad09fabib67) 2018; 17 Jonscher (jesad09fabib7) 1977; 267 Pautrat (jesad09fabib27) 1980; 23 Li (jesad09fabib30) 2021; 125 Runt (jesad09fabib12) 1997 Sinclair (jesad09fabib34) 1995; 65 Ramirez (jesad09fabib50) 2000; 115 Subramanian (jesad09fabib19) 2000; 151 Irvine (jesad09fabib10) 1990; 2 Jonscher (jesad09fabib3) 1983 Lunkenheimer (jesad09fabib13) 2012 Dong (jesad09fabib23) 2015; 7 Lunkenheimer (jesad09fabib21) 2010; 180 Hodge (jesad09fabib31) 1976; 74 Vainas (jesad09fabib49) 1999; 126 Davidson (jesad09fabib36) 1950; 18 Moynihan (jesad09fabib35) 1994; 172–174 Havriliak (jesad09fabib37) 1967; 8 Eremenko (jesad09fabib66) 2019; 10 Almond (jesad09fabib32) 1983; 11 Deng (jesad09fabib52) 2009; 105 Lemanov (jesad09fabib58) 1999; 110 Siragam (jesad09fabib16) 2021; 45 Sinclair (jesad09fabib54) 2002; 80 Adams (jesad09fabib60) 2006; 73 Franklin (jesad09fabib6) 1983; 75 Perry (jesad09fabib42) 2021; 514 Cabral (jesad09fabib65) 2018; 112 Bauerle (jesad09fabib9) 1969; 30 Jonscher (jesad09fabib40) 1990; 6 Egami (jesad09fabib64) 1999; 222 Kremer (jesad09fabib11) 2003 Jha (jesad09fabib20) 2004; 177 Bollmann (jesad09fabib29) 2018; 535 Mohanty (jesad09fabib17) 2021; 863 Wang (jesad09fabib4) 2021; 1 Bruce (jesad09fabib26) 1983; 130 Adams (jesad09fabib53) 2002; 14 Cole (jesad09fabib5) 1941; 9 Barsoukov (jesad09fabib1) 2018 Almond (jesad09fabib48) 1999; 11 Orliukas (jesad09fabib18) 1993; 12 Taniguchi (jesad09fabib24) 2020; 8 Ferrarelli (jesad09fabib55) 2009; 19 Abram (jesad09fabib8) 2003; 10 Grant (jesad09fabib41) 1977; 266 Jonscher (jesad09fabib38) 1990; 6 Cowley (jesad09fabib62) 2011; 60 Hu (jesad09fabib22) 2013; 12 Kakimoto (jesad09fabib25) 2023; 11 Bowen (jesad09fabib47) 2006; 22 Li (jesad09fabib59) 2007; 91 Jonscher (jesad09fabib39) 1990; 6 Almond (jesad09fabib45) 2004; 92 Müller (jesad09fabib57) 1979; 19 Vendrell (jesad09fabib68) 2022; 5 Adams (jesad09fabib61) 2006; 89 Cross (jesad09fabib63) 1987; 76 Fan (jesad09fabib15) 2020; 250 |
References_xml | – volume: 1 start-page: 41 year: 2021 ident: jesad09fabib4 article-title: Electrochemical impedance spectroscopy publication-title: Nature Reviews Methods Primers doi: 10.1038/s43586-021-00039-w contributor: fullname: Wang – volume: 112 year: 2018 ident: jesad09fabib65 article-title: Gradient chemical order in the relaxor PMN publication-title: Appl. Phys. Lett. doi: 10.1063/1.5016561 contributor: fullname: Cabral – volume: 2 start-page: 132 year: 1990 ident: jesad09fabib10 article-title: Electroceramics: characterization by impedance spectroscopy publication-title: Adv Materials doi: 10.1002/adma.19900020304 contributor: fullname: Irvine – volume: 89 start-page: 3129 year: 2006 ident: jesad09fabib61 article-title: The influence of processing on the electrical properties of CaCu3Ti4O12 ceramics publication-title: J Amer. Ceram. Soc. doi: 10.1111/j.1551-2916.2006.01184.x contributor: fullname: Adams – volume: 19 start-page: 5916 year: 2009 ident: jesad09fabib55 article-title: Comment on the origin(s) of the giant permittivity effect in CaCu3Ti4O12 single crystals and ceramics publication-title: J Mat Chem doi: 10.1039/b910871h contributor: fullname: Ferrarelli – volume: 126 start-page: 65 year: 1999 ident: jesad09fabib49 article-title: An evaluation of random R-C networks for modelling the bulk ac electrical response of ionic conductors publication-title: Solid State Ionics doi: 10.1016/S0167-2738(99)00216-7 contributor: fullname: Vainas – volume: 19 start-page: 3593 year: 1979 ident: jesad09fabib57 article-title: SrTiO3: an intrinsic quantum paraelectric below 4 K publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.19.3593 contributor: fullname: Müller – volume: 177 start-page: 2881 year: 2004 ident: jesad09fabib20 article-title: La0.4Ba0.4Ca0.2)(Mn0.4Ti0.6)O3: a new titano-manganate with a high dielectric constant and antiferromagnetic interactions publication-title: J. Solid State Chem. doi: 10.1016/j.jssc.2004.05.009 contributor: fullname: Jha – volume: 130 start-page: 662 year: 1983 ident: jesad09fabib26 article-title: The ac conductivity of polycrystalline LISICON, Li2 + 2x Zn1−x GeO4, and a model for intergranular constriction resistances publication-title: J. Electrochem. Soc. doi: 10.1149/1.2119778 contributor: fullname: Bruce – volume: 10 start-page: 165 year: 2003 ident: jesad09fabib8 article-title: A strategy for analysis and modelling of impedance spectroscopy data of electroceramics: doped lanthanum gallate publication-title: J Electroceram doi: 10.1023/B:JECR.0000011215.56084.87 contributor: fullname: Abram – volume: 250 year: 2020 ident: jesad09fabib15 article-title: Enhanced the dielectric relaxation characteristics of BaTiO3 ceramic doped by BiFeO3 and synthesized by the microwave sintering method publication-title: Mater. Chem. Phys. doi: 10.1016/j.matchemphys.2020.123034 contributor: fullname: Fan – volume: 115 start-page: 217 year: 2000 ident: jesad09fabib50 article-title: Giant dielectric constant response in a copper-titanate publication-title: Solid State Commun. doi: 10.1016/S0038-1098(00)00182-4 contributor: fullname: Ramirez – year: 1967 ident: jesad09fabib2 contributor: fullname: Daniel – volume: 91 year: 2007 ident: jesad09fabib59 article-title: Dielectric and microwave dielectric resonance properties of CaCu2.85 Mn0.15Ti4O12 ceramics publication-title: Appl. Phys. Lett. contributor: fullname: Li – volume: 7 start-page: 25321 year: 2015 ident: jesad09fabib23 article-title: Colossal dielectric behavior of Ga+Nb co-doped rutile TiO2 publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.5b07467 contributor: fullname: Dong – volume: 75 start-page: 647 year: 1983 ident: jesad09fabib6 article-title: The fourier analysis of impedance spectra for electrode electrolytes publication-title: Phys. Stat. Solidi doi: 10.1002/pssa.2210750240 contributor: fullname: Franklin – volume: 267 start-page: 673 year: 1977 ident: jesad09fabib7 article-title: The “universal” dielectric response publication-title: Nature doi: 10.1038/267673a0 contributor: fullname: Jonscher – volume: 30 start-page: 2657 year: 1969 ident: jesad09fabib9 article-title: Study of solid electrolyte polarization by a complex admittance method publication-title: J. Phys. Chem. Solids doi: 10.1016/0022-3697(69)90039-0 contributor: fullname: Bauerle – volume: 12 start-page: 821 year: 2013 ident: jesad09fabib22 article-title: Electron-pinned defect-dipoles for high performance colossal permittivity materials publication-title: Nat. Mater. doi: 10.1038/nmat3691 contributor: fullname: Hu – volume: 535 start-page: 237 year: 2018 ident: jesad09fabib29 article-title: Admittance spectroscopy or deep level transient spectroscopy: a contrasting juxtaposition publication-title: Phys. B Condens. Matter doi: 10.1016/j.physb.2017.07.048 contributor: fullname: Bollmann – volume: 44 start-page: 141 year: 2018 ident: jesad09fabib14 article-title: Temperature stability, low loss and defect relaxation of MgO-TiO2 microwave dielectric ceramics modified by Ca0.8Sr0.2TiO3 publication-title: Ceram. Int. doi: 10.1016/j.ceramint.2017.09.149 contributor: fullname: Zhang – volume: 11 start-page: 9081 year: 1999 ident: jesad09fabib48 article-title: The dielectric properties of random R-C networks as an explanation of the “universal” power law dielectric response of solids publication-title: J Phys Cond Matter doi: 10.1088/0953-8984/11/46/310 contributor: fullname: Almond – volume: 11 start-page: 1304 year: 2023 ident: jesad09fabib25 article-title: Controlling dielectric properties of Nb + X (X = Al, Ga, In) co-doped and Nb-doped rutile-type TiO2 single crystals publication-title: J Mat. Chem. C doi: 10.1039/D2TC03914A contributor: fullname: Kakimoto – volume: 80 start-page: 2153 year: 2002 ident: jesad09fabib54 article-title: CaCu3Ti4O12: a one-step internal barrier layer capacitor publication-title: Appl. Phys. Lett. doi: 10.1063/1.1463211 contributor: fullname: Sinclair – volume: 110 start-page: 611 year: 1999 ident: jesad09fabib58 article-title: Perovskite CaTiO3 as an incipient ferroelectric publication-title: Solid State Commun. doi: 10.1016/S0038-1098(99)00153-2 contributor: fullname: Lemanov – volume: 65 start-page: 55 year: 1995 ident: jesad09fabib34 article-title: Characterization of electro-materials using ac impedance spectroscopy contributor: fullname: Sinclair – year: 2018 ident: jesad09fabib1 contributor: fullname: Barsoukov – volume: 74 start-page: 125 year: 1976 ident: jesad09fabib31 article-title: Impedance and modulus spectroscopy of polycrystalline solid electrolytes publication-title: J. Electroanal. Chem. Interfacial Electrochem. doi: 10.1016/S0022-0728(76)80229-X contributor: fullname: Hodge – volume: 105 year: 2009 ident: jesad09fabib52 article-title: Physical aspects of colossal dielectric constant material CaCu3Ti4O12 thin films publication-title: J. Appl. Phys. doi: 10.1063/1.3106639 contributor: fullname: Deng – volume: 106 year: 2009 ident: jesad09fabib56 article-title: Origin(s) of the apparent high permittivity in CaCu3Ti4O12 ceramics: clarification on the contributions from internal barrier layer capacitor and sample: electrode contact effects publication-title: J. Appl. Phys. doi: 10.1063/1.3253743 contributor: fullname: Li – volume: 11 start-page: 57 year: 1983 ident: jesad09fabib32 article-title: Impedance and modulus spectroscopy of “real” dispersive conductors publication-title: Solid State Ionics doi: 10.1016/0167-2738(83)90063-2 contributor: fullname: Almond – volume: 9 start-page: 341 year: 1941 ident: jesad09fabib5 article-title: Dispersion and absorption in dielectrics: I. Alternating current characteristics publication-title: J. Chem. Phys. doi: 10.1063/1.1750906 contributor: fullname: Cole – volume: 222 start-page: 163 year: 1999 ident: jesad09fabib64 article-title: Microscopic model of relaxor phenomena in Pb-containing mixed oxides publication-title: Ferroelectrics doi: 10.1080/00150199908014812 contributor: fullname: Egami – volume: 22 start-page: 719 year: 2006 ident: jesad09fabib47 article-title: Modelling the “universal” dielectric response in heterogeneous materials using microstructural electrical networks publication-title: Mat Sci Tech doi: 10.1179/174328406X101328 contributor: fullname: Bowen – volume: 8 start-page: 161 year: 1967 ident: jesad09fabib37 article-title: A complex plane representation of dielectric and mechanical relaxation processes in some polymers publication-title: Polymer (Guildf) doi: 10.1016/0032-3861(67)90021-3 contributor: fullname: Havriliak – volume: 863 year: 2021 ident: jesad09fabib17 article-title: Dielectric, electrical and magnetic characteristics of BST modified BLFO lead free ceramic publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2020.158060 contributor: fullname: Mohanty – volume: 180 start-page: 61 year: 2010 ident: jesad09fabib21 article-title: Colossal dielectric constants in transition-metal oxides publication-title: Eur. Phys. J. Special Topics doi: 10.1140/epjst/e2010-01212-5 contributor: fullname: Lunkenheimer – volume: 443 start-page: 149 year: 1998 ident: jesad09fabib43 article-title: On the electrical capacitance of interfaces exhibiting constant phase element behaviour publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(97)00490-7 contributor: fullname: Zoltowski – volume: 8 start-page: 13627 year: 2020 ident: jesad09fabib24 article-title: Permittivity boosting in “yellow” (Nb + In) co-doped TiO2 publication-title: J Mat Chem C doi: 10.1039/D0TC03539D contributor: fullname: Taniguchi – volume: 17 start-page: 718 year: 2018 ident: jesad09fabib67 article-title: The relation of local order to material properties in relaxor ferroelectrics publication-title: Nat. Mater. doi: 10.1038/s41563-018-0112-7 contributor: fullname: Krogstad – year: 1997 ident: jesad09fabib12 contributor: fullname: Runt – volume: 18 start-page: 1417 year: 1950 ident: jesad09fabib36 article-title: Dielectric relaxation in glycerine publication-title: J. Chem. Phys. doi: 10.1063/1.1747496 contributor: fullname: Davidson – volume: 452 start-page: 229 year: 1998 ident: jesad09fabib44 article-title: Impedance of constant phase element (CPE)-blocked diffusion in film electrodes publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(98)00115-6 contributor: fullname: Bisquert – volume: 14 start-page: 1321 year: 2002 ident: jesad09fabib53 article-title: Giant barrier layer capacitance effects in CaCu3Ti4O12 ceramics publication-title: Adv. Mater. doi: 10.1002/1521-4095(20020916)14:18<1321::AID-ADMA1321>3.0.CO;2-P contributor: fullname: Adams – volume: 19 start-page: 30410 year: 2017 ident: jesad09fabib28 article-title: Voltage dependent admittance spectroscopy for the detection of near interface defect states for thin film solar cells publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C7CP05236G contributor: fullname: Weiss – volume: 92 start-page: 1 year: 2004 ident: jesad09fabib45 article-title: Anomalous power law dispersions in ac conductivity and permittivity shown to be characteristics of microstructural electrical networks publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.92.157601 contributor: fullname: Almond – volume: 5 start-page: 1 year: 2022 ident: jesad09fabib68 article-title: Revealing the role of the constant phase element in relaxor ferroelectrics publication-title: Commun. Phys. doi: 10.1038/s42005-021-00775-1 contributor: fullname: Vendrell – volume: 39 start-page: 1295 year: 2006 ident: jesad09fabib46 article-title: Composite dielectrics and conductors: simulation, characterization and design publication-title: J. Phys. D: Appl. Phys. doi: 10.1088/0022-3727/39/7/S03 contributor: fullname: Almond – year: 2012 ident: jesad09fabib13 article-title: Dielectric spectroscopy of glassy dynamics doi: 10.1002/9781118202470.ch3 contributor: fullname: Lunkenheimer – volume: 76 start-page: 241 year: 1987 ident: jesad09fabib63 article-title: Relaxor ferroelectrics publication-title: Ferroelectrics doi: 10.1080/00150198708016945 contributor: fullname: Cross – volume: 10 start-page: 2728 year: 2019 ident: jesad09fabib66 article-title: Local atomic order and hierarchical polar nanoregions in a classical relaxor ferroelectric publication-title: Nat. Commun. doi: 10.1038/s41467-019-10665-4 contributor: fullname: Eremenko – volume: 266 start-page: 42 year: 1977 ident: jesad09fabib41 article-title: Conductivity dispersion in single crystal β-alumina electrolyte publication-title: Nature doi: 10.1038/266042a0 contributor: fullname: Grant – volume: 23 start-page: 1159 year: 1980 ident: jesad09fabib27 article-title: Admittance spectroscopy: a powerful characterization technique for semiconductor crystals—application to ZnTe publication-title: Solid. State. Electron. doi: 10.1016/0038-1101(80)90028-3 contributor: fullname: Pautrat – volume: 6 start-page: 19 year: 1990 ident: jesad09fabib38 article-title: The “universal” dielectric response: Part I publication-title: IEEE Electr. Insul. Mag. doi: 10.1109/57.63055 contributor: fullname: Jonscher – volume: 514 year: 2021 ident: jesad09fabib42 article-title: Probing mass transport processes in Li-ion batteries using electrochemical impedance spectroscopy publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2021.230577 contributor: fullname: Perry – year: 1983 ident: jesad09fabib3 contributor: fullname: Jonscher – volume: 66 start-page: 3850 year: 1989 ident: jesad09fabib33 article-title: Impedance and modulus spectroscopy of semiconducting BaTiO3 showing positive temperature coefficient of resistance publication-title: J. Appl. Phys. doi: 10.1063/1.344049 contributor: fullname: Sinclair – volume: 172–174 start-page: 1395 year: 1994 ident: jesad09fabib35 article-title: Analysis of electrical relaxation in glasses and melts with large concentrations of mobile ions publication-title: J Non Cryst Solids PART 2 doi: 10.1016/0022-3093(94)90668-8 contributor: fullname: Moynihan – volume: 293 start-page: 673 year: 2001 ident: jesad09fabib51 article-title: Optical response of high-dielectric-constant perovskite-related oxide publication-title: Science doi: 10.1126/science.1061655 contributor: fullname: Homes – volume: 12 start-page: 87 year: 1993 ident: jesad09fabib18 article-title: Relaxation dispersion of ionic conductivity in a Zr0.85Ca0.15O1.85 single crystal publication-title: J. Eur. Ceram. Soc. doi: 10.1016/0955-2219(93)90127-D contributor: fullname: Orliukas – volume: 6 start-page: 19 year: 1990 ident: jesad09fabib40 article-title: The “universal” dielectric reponse: Part III publication-title: IEEE Electr. Insul. Mag. doi: 10.1109/57.63055 contributor: fullname: Jonscher – volume: 125 start-page: 2860 year: 2021 ident: jesad09fabib30 article-title: Defect characterization using raw admittance spectroscopy publication-title: J. Phys. Chem. C doi: 10.1021/acs.jpcc.0c10853 contributor: fullname: Li – volume: 6 start-page: 24 year: 1990 ident: jesad09fabib39 article-title: The “universal” dielectric response: Part II publication-title: IEEE Electr. Insul. Mag. doi: 10.1109/57.55287 contributor: fullname: Jonscher – volume: 60 start-page: 229 year: 2011 ident: jesad09fabib62 article-title: Relaxing with relaxors: a review of relaxor ferroelectrics publication-title: Adv. Phys. doi: 10.1080/00018732.2011.555385 contributor: fullname: Cowley – volume: 73 year: 2006 ident: jesad09fabib60 article-title: Characterisation of grain boundary Impedances in fine and coarse grained CaCu3Ti4O12 ceramics publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.73.094124 contributor: fullname: Adams – year: 2003 ident: jesad09fabib11 contributor: fullname: Kremer – volume: 151 start-page: 323 year: 2000 ident: jesad09fabib19 article-title: High dielectric constant in ACu3Ti4O12 and ACu3Ti3FeO12 phases publication-title: J. Solid State Chem. doi: 10.1006/jssc.2000.8703 contributor: fullname: Subramanian – volume: 45 start-page: 2801 year: 2021 ident: jesad09fabib16 article-title: Analysis of dielectric properties of zinc aluminum silicate based ceramic nanoparticles publication-title: Mater. Today Proc. doi: 10.1016/j.matpr.2020.11.790 contributor: fullname: Siragam |
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Title | Impedance and Dielectric Spectroscopy of Functional Materials: A Critical Evaluation of the Two Techniques |
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