Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts
Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-t...
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| Published in | Topics in catalysis Vol. 57; no. 17-20; pp. 1351 - 1358 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.11.2014
Springer Verlag [1994-....] |
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| Abstract | Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-time. Among the known numerous families of olefin metathesis catalysts, the Umicore M7-catalyst family represents a novel class of Hoveyda-type complexes showing excellent chemical stabilities and modular activity profiles. Relevant aspects related to their industrial synthesis as well as their catalytic performance in valuable olefin metathesis transformations are overviewed here. |
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| AbstractList | Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-time. Among the known numerous families of olefin metathesis catalysts, the Umicore M7-catalyst family represents a novel class of Hoveyda-type complexes showing excellent chemical stabilities and modular activity profiles. Relevant aspects related to their industrial synthesis as well as their catalytic performance in valuable olefin metathesis transformations are overviewed here. |
| Author | Tripoteau, Fabien Crévisy, Christophe Caijo, Frederic Bompard, Savinien Mauduit, Marc Doppiu, Angelino |
| Author_xml | – sequence: 1 givenname: Angelino surname: Doppiu fullname: Doppiu, Angelino email: angelino.doppiu@eu.umicore.com organization: Precious Metals Chemistry, Umicore AG & Co. KG – sequence: 2 givenname: Frederic surname: Caijo fullname: Caijo, Frederic organization: OMEGA CAT SYSTEM Sarl, Ecole Nationale Supérieure de Chimie de Rennes – sequence: 3 givenname: Fabien surname: Tripoteau fullname: Tripoteau, Fabien organization: OMEGA CAT SYSTEM Sarl, Ecole Nationale Supérieure de Chimie de Rennes – sequence: 4 givenname: Savinien surname: Bompard fullname: Bompard, Savinien organization: CNRS, UMR 6226, Ecole Nationale Supérieure de Chimie de Rennes – sequence: 5 givenname: Christophe surname: Crévisy fullname: Crévisy, Christophe organization: CNRS, UMR 6226, Ecole Nationale Supérieure de Chimie de Rennes – sequence: 6 givenname: Marc surname: Mauduit fullname: Mauduit, Marc organization: CNRS, UMR 6226, Ecole Nationale Supérieure de Chimie de Rennes |
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| CitedBy_id | crossref_primary_10_1002_cctc_201500261 crossref_primary_10_1016_j_ccr_2015_09_012 crossref_primary_10_1021_acsomega_7b00635 crossref_primary_10_1021_acssuschemeng_6b01648 crossref_primary_10_1002_cctc_201700426 crossref_primary_10_1002_chin_201452280 crossref_primary_10_1002_ejoc_201800324 crossref_primary_10_1021_acscatal_0c05508 crossref_primary_10_1021_acs_organomet_7b00836 |
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| Issue | 17-20 |
| Keywords | Fragrances Ruthenium Olefin metathesis Terpenes Fatty esters Industrial catalyst synthesis |
| Language | English |
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| Snippet | Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective... |
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| SubjectTerms | Catalysis Characterization and Evaluation of Materials Chemical Sciences Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Original Paper Pharmacy Physical Chemistry |
| Title | Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts |
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