Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts

Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-t...

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Published inTopics in catalysis Vol. 57; no. 17-20; pp. 1351 - 1358
Main Authors Doppiu, Angelino, Caijo, Frederic, Tripoteau, Fabien, Bompard, Savinien, Crévisy, Christophe, Mauduit, Marc
Format Journal Article
LanguageEnglish
Published New York Springer US 01.11.2014
Springer Verlag [1994-....]
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Abstract Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-time. Among the known numerous families of olefin metathesis catalysts, the Umicore M7-catalyst family represents a novel class of Hoveyda-type complexes showing excellent chemical stabilities and modular activity profiles. Relevant aspects related to their industrial synthesis as well as their catalytic performance in valuable olefin metathesis transformations are overviewed here.
AbstractList Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective industrial applications require large-scale availability of catalyst precursors which combine high activity, high selectivity and long life-time. Among the known numerous families of olefin metathesis catalysts, the Umicore M7-catalyst family represents a novel class of Hoveyda-type complexes showing excellent chemical stabilities and modular activity profiles. Relevant aspects related to their industrial synthesis as well as their catalytic performance in valuable olefin metathesis transformations are overviewed here.
Author Tripoteau, Fabien
Crévisy, Christophe
Caijo, Frederic
Bompard, Savinien
Mauduit, Marc
Doppiu, Angelino
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  givenname: Angelino
  surname: Doppiu
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  organization: Precious Metals Chemistry, Umicore AG & Co. KG
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  givenname: Frederic
  surname: Caijo
  fullname: Caijo, Frederic
  organization: OMEGA CAT SYSTEM Sarl, Ecole Nationale Supérieure de Chimie de Rennes
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  givenname: Fabien
  surname: Tripoteau
  fullname: Tripoteau, Fabien
  organization: OMEGA CAT SYSTEM Sarl, Ecole Nationale Supérieure de Chimie de Rennes
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  givenname: Savinien
  surname: Bompard
  fullname: Bompard, Savinien
  organization: CNRS, UMR 6226, Ecole Nationale Supérieure de Chimie de Rennes
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  givenname: Christophe
  surname: Crévisy
  fullname: Crévisy, Christophe
  organization: CNRS, UMR 6226, Ecole Nationale Supérieure de Chimie de Rennes
– sequence: 6
  givenname: Marc
  surname: Mauduit
  fullname: Mauduit, Marc
  organization: CNRS, UMR 6226, Ecole Nationale Supérieure de Chimie de Rennes
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IsPeerReviewed true
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Issue 17-20
Keywords Fragrances
Ruthenium
Olefin metathesis
Terpenes
Fatty esters
Industrial catalyst synthesis
Language English
License Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0
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Snippet Olefin metathesis is a powerful catalytic reaction that has a huge potential in the pharmaceutical, polymer and specialty chemicals industries. Cost-effective...
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SubjectTerms Catalysis
Characterization and Evaluation of Materials
Chemical Sciences
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Original Paper
Pharmacy
Physical Chemistry
Title Synthesis Optimization and Catalytic Activity Screening of Industrially Relevant Ruthenium-Based Metathesis Catalysts
URI https://link.springer.com/article/10.1007/s11244-014-0302-8
https://hal.science/hal-01123898
Volume 57
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