From benzodithiophene to diethoxy-benzodithiophene covalent organic frameworks - structural investigations

• Published in: CrystEngComm Vol. 18; no. 23; pp. 4295 - 432
• Main Authors: Lohse, Maria S, Rotter, Julian M, Margraf, Johannes T, Werner, Veronika, Becker, Matthias, Herbert, Simon, Knochel, Paul, Clark, Timothy, Bein, Thomas, Medina, Dana D
• Format: Journal Article
• Language: English
• Published: 01.01.2016
• Subjects: Accessibility; Assembly; Backbone; Buildings; Covalence; Crystal structure; Crystallinity; Porosity

The incorporation of side groups into a covalent organic framework (COF) backbone can be of significant importance for developing new frameworks with enhanced properties. Here we present a novel π-stacked thiophene-based COF containing a benzodithiophene building unit modified with ethoxy side chain...