Macrocyclic Inorganic Tin‐Containing Oxo Clusters: Heterometallic Strategy for Configuration and Catalytic Activity Modulation

• Published in: Chemistry : a European journal Vol. 27; no. 65; pp. 16117 - 16120
• Main Authors: Wang, Di, Chen, Guang‐Hui, Yuan, Lv‐Bing, Feng, Cheng‐Cheng, Zhang, Jian, Zhang, Lei
• Format: Journal Article
• Language: English
• Published: 22.11.2021
• Subjects: cluster compounds; heterometallic complexes; macrocycles; structure-activity relationships; tin

In this work, the first examples of inorganic macrocyclic tin‐oxo clusters which are stabilized by sulfate ligands are reported. As determined by X‐ray diffraction and photoelectron spectroscopy analyses, the prepared inorganic Sn10‐oxo cluster displays interesting mixed valence behaviors, with 8 Sn...