Liquid–liquid equilibria of water+lactic acid+methyl isobutyl ketone

Experimental liquid–liquid equilibria of the ternary system of water+lactic acid+methyl isobutyl ketone (MIBK) were studied at T=(298.15, 303.15 and 308.15) K under atmospheric conditions. Complete phase diagrams were obtained by determining solubility and tie-line data. The ternary system exhibits...

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Published inFluid phase equilibria Vol. 379; pp. 19 - 25
Main Authors Afolabi, Tinuade Jolaade, Alao, Adeyinka Idowu
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.10.2014
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Abstract Experimental liquid–liquid equilibria of the ternary system of water+lactic acid+methyl isobutyl ketone (MIBK) were studied at T=(298.15, 303.15 and 308.15) K under atmospheric conditions. Complete phase diagrams were obtained by determining solubility and tie-line data. The ternary system exhibits type-1 behavior of LLE. The reliability of the experimental tie-line data was ascertained by using both Hand and Othmer–Tobias correlations. The UNIFAC group contribution method was used to predict the observed ternary liquid–liquid equilibrium data. Distribution coefficients and separation factors were evaluated to evaluate the extracting capability of the solvent. Separation factors were more than unity and the UNIFAC prediction was satisfactory.
AbstractList Experimental liquid–liquid equilibria of the ternary system of water+lactic acid+methyl isobutyl ketone (MIBK) were studied at T=(298.15, 303.15 and 308.15) K under atmospheric conditions. Complete phase diagrams were obtained by determining solubility and tie-line data. The ternary system exhibits type-1 behavior of LLE. The reliability of the experimental tie-line data was ascertained by using both Hand and Othmer–Tobias correlations. The UNIFAC group contribution method was used to predict the observed ternary liquid–liquid equilibrium data. Distribution coefficients and separation factors were evaluated to evaluate the extracting capability of the solvent. Separation factors were more than unity and the UNIFAC prediction was satisfactory.
Author Alao, Adeyinka Idowu
Afolabi, Tinuade Jolaade
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Keywords Separation factor
UNIFAC
Lactic acid
Liquid–liquid equilibria
Methyl isobutyl ketone
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Snippet Experimental liquid–liquid equilibria of the ternary system of water+lactic acid+methyl isobutyl ketone (MIBK) were studied at T=(298.15, 303.15 and 308.15) K...
Experimental liquid-liquid equilibria of the ternary system of water+lactic acid+methyl isobutyl ketone (MIBK) were studied at T =(298.15, 303.15 and 308.15) K...
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SubjectTerms Fluid dynamics
Ketones
Lactic acid
Liquid-liquid equilibria
Methyl isobutyl ketone
Phase diagrams
Separation
Separation factor
Solubility
Ternary systems
UNIFAC
Unity
Title Liquid–liquid equilibria of water+lactic acid+methyl isobutyl ketone
URI https://dx.doi.org/10.1016/j.fluid.2014.06.010
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