Hydrothermal Ageing of Metallocene Polyethylene Films in Presence of Grafted Amine Stabilizers

The hydrothermal degradation at 90°C in distilled water of metallocene linear low density polyethylene films (mLLDPE) has been studied using low density polyethylene (LDPE) for comparison. FTIR spectroscopy, DSC and chemiluminescence techniques were used for investigation of the hydrothermal ageing-...

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Published inArabian Journal for Science and Engineering Vol. 40; no. 1; pp. 69 - 80
Main Authors Setnescu, Radu, Kaci, Mustapha, Dehouche, Nadjet, Setnescu, Tanţa, Nasri, Lounis, Zaharescu, Traian
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer Berlin Heidelberg 01.01.2015
Subjects
Degradation
Density
Distilled water
Engineering
Grafting
Humanities and Social Sciences
Metallocenes
multidisciplinary
Polyethylenes
Research Article - Chemistry
Science
Spectra
Stability
Stabilization
Hydrothermal ageing
FT-IR
Metallocene LLDPE
Chemiluminescence
DSC
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Abstract The hydrothermal degradation at 90°C in distilled water of metallocene linear low density polyethylene films (mLLDPE) has been studied using low density polyethylene (LDPE) for comparison. FTIR spectroscopy, DSC and chemiluminescence techniques were used for investigation of the hydrothermal ageing-induced changes. The stabilization effect of a commercially available HALS, namely Sanduvor PR 31, able to graft on polyolefin structures has been also studied, as well. It was found that intense oxidation process occurs in the case of LDPE: hydroxyl, carbonyl and unsaturated groups were identified in FTIR spectra. mLLDPE reference films presented considerably higher stability as compared to LDPE ones, this behaviour being assigned to the structural peculiarities. Sanduvor PR 31 induced higher stability in LDPE, possibly by grafting mechanism, but it did not present a significant effect in the case of mLLDPE. Besides a possible antagonist interaction with the process stabilizer or a graft-hindering effect of the alkyl side groups, the intrinsic higher stability of the mLLDPE which offers less active sites for grafting could be supposed to explain this lower effectiveness.
AbstractList The hydrothermal degradation at 90 degree C in distilled water of metallocene linear low density polyethylene films (mLLDPE) has been studied using low density polyethylene (LDPE) for comparison. FTIR spectroscopy, DSC and chemiluminescence techniques were used for investigation of the hydrothermal ageing-induced changes. The stabilization effect of a commercially available HALS, namely Sanduvor PR 31, able to graft on polyolefin structures has been also studied, as well. It was found that intense oxidation process occurs in the case of LDPE: hydroxyl, carbonyl and unsaturated groups were identified in FTIR spectra. mLLDPE reference films presented considerably higher stability as compared to LDPE ones, this behaviour being assigned to the structural peculiarities. Sanduvor PR 31 induced higher stability in LDPE, possibly by grafting mechanism, but it did not present a significant effect in the case of mLLDPE. Besides a possible antagonist interaction with the process stabilizer or a graft-hindering effect of the alkyl side groups, the intrinsic higher stability of the mLLDPE which offers less active sites for grafting could be supposed to explain this lower effectiveness.
The hydrothermal degradation at 90°C in distilled water of metallocene linear low density polyethylene films (mLLDPE) has been studied using low density polyethylene (LDPE) for comparison. FTIR spectroscopy, DSC and chemiluminescence techniques were used for investigation of the hydrothermal ageing-induced changes. The stabilization effect of a commercially available HALS, namely Sanduvor PR 31, able to graft on polyolefin structures has been also studied, as well. It was found that intense oxidation process occurs in the case of LDPE: hydroxyl, carbonyl and unsaturated groups were identified in FTIR spectra. mLLDPE reference films presented considerably higher stability as compared to LDPE ones, this behaviour being assigned to the structural peculiarities. Sanduvor PR 31 induced higher stability in LDPE, possibly by grafting mechanism, but it did not present a significant effect in the case of mLLDPE. Besides a possible antagonist interaction with the process stabilizer or a graft-hindering effect of the alkyl side groups, the intrinsic higher stability of the mLLDPE which offers less active sites for grafting could be supposed to explain this lower effectiveness.
Author Setnescu, Tanţa
Setnescu, Radu
Zaharescu, Traian
Dehouche, Nadjet
Nasri, Lounis
Kaci, Mustapha
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CitedBy_id crossref_primary_10_1016_j_polymertesting_2018_01_007
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crossref_primary_10_1016_j_matdes_2016_08_065
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crossref_primary_10_1002_anie_202307573
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Snippet The hydrothermal degradation at 90°C in distilled water of metallocene linear low density polyethylene films (mLLDPE) has been studied using low density...
The hydrothermal degradation at 90 degree C in distilled water of metallocene linear low density polyethylene films (mLLDPE) has been studied using low density...
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StartPage 69
SubjectTerms Degradation
Density
Distilled water
Engineering
Grafting
Humanities and Social Sciences
Metallocenes
multidisciplinary
Polyethylenes
Research Article - Chemistry
Science
Spectra
Stability
Stabilization
Title Hydrothermal Ageing of Metallocene Polyethylene Films in Presence of Grafted Amine Stabilizers
URI https://link.springer.com/article/10.1007/s13369-014-1478-8
https://search.proquest.com/docview/1660083356
Volume 40
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