Biomimetic porous polypropylene foams with special wettability properties

Nowadays, the subject of wettability still has received little attention in the scientific literature, especially in the cellular solids, despite its significant role in the pervasiveness of the water treatment. Herein, inspired by the mussel, a green method was developed to construct nano-/micro-st...

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Published inComposites. Part B, Engineering Vol. 190; p. 107927
Main Authors Huang, Pengke, Wu, Fei, Shen, Bin, Zheng, Hao, Ren, Qian, Luo, Haibin, Zheng, Wenge
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.06.2020
Subjects
Biomimetic
Dopamine
Polypropylene foams
Porous architecture
Super-wetting
Porous architecture
Dopamine
Super-wetting
Biomimetic
Polypropylene foams
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Abstract Nowadays, the subject of wettability still has received little attention in the scientific literature, especially in the cellular solids, despite its significant role in the pervasiveness of the water treatment. Herein, inspired by the mussel, a green method was developed to construct nano-/micro-structures on the multi-structural polypropylene (like the dense solids, big hollow, small hollow and hierarchical open/closed-cell porous structure) by the surface-adherent polydopamine. Moreover, the relationship between both surface chemical and physical (such as pore structure and size) properties of the porous media, and wettability were studied. Besides, water–glycerol mixture solutions with various viscosities were used to study the spreading and imbibition behavior in the porous polypropylene foams, and the surface free energy of the different cellular solids (before and after modification) was estimated by Owens-Wendt equation. More interestingly, different kinds of the super-wetting materials like super-amphiphilic and hierarchical super-hydrophilic/super-hydrophobic, etc., were successful prepared. Both fundamental theoretical and numerical analysis were also conducted to reveal the mechanism of the penetration or surface repellency toward a drop, and to predict the transport of fluids in porous media. We believe that this work may serve as a source of inspiration in designing other advanced functional materials. [Display omitted]
AbstractList Nowadays, the subject of wettability still has received little attention in the scientific literature, especially in the cellular solids, despite its significant role in the pervasiveness of the water treatment. Herein, inspired by the mussel, a green method was developed to construct nano-/micro-structures on the multi-structural polypropylene (like the dense solids, big hollow, small hollow and hierarchical open/closed-cell porous structure) by the surface-adherent polydopamine. Moreover, the relationship between both surface chemical and physical (such as pore structure and size) properties of the porous media, and wettability were studied. Besides, water–glycerol mixture solutions with various viscosities were used to study the spreading and imbibition behavior in the porous polypropylene foams, and the surface free energy of the different cellular solids (before and after modification) was estimated by Owens-Wendt equation. More interestingly, different kinds of the super-wetting materials like super-amphiphilic and hierarchical super-hydrophilic/super-hydrophobic, etc., were successful prepared. Both fundamental theoretical and numerical analysis were also conducted to reveal the mechanism of the penetration or surface repellency toward a drop, and to predict the transport of fluids in porous media. We believe that this work may serve as a source of inspiration in designing other advanced functional materials. [Display omitted]
ArticleNumber 107927
Author Huang, Pengke
Zheng, Hao
Luo, Haibin
Shen, Bin
Zheng, Wenge
Wu, Fei
Ren, Qian
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  givenname: Wenge
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  email: wgzheng@nimte.ac.cn
  organization: Ningbo Key Lab of Polymer Materials, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China
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Keywords Porous architecture
Dopamine
Super-wetting
Biomimetic
Polypropylene foams
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Snippet Nowadays, the subject of wettability still has received little attention in the scientific literature, especially in the cellular solids, despite its...
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StartPage 107927
SubjectTerms Biomimetic
Dopamine
Polypropylene foams
Porous architecture
Super-wetting
Title Biomimetic porous polypropylene foams with special wettability properties
URI https://dx.doi.org/10.1016/j.compositesb.2020.107927
Volume 190
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