A study on the physicochemical properties of a graphite/polybenzoxazine composite for bipolar plate of polymer electrolyte membrane fuel cells

The effects of graphite content, compression molding conditions, and types of catalysts on the mechanical and electrical properties and corrosion resistance of a graphite composite based on benzoxazine resin for the bipolar plate of polymer electrolyte membrane fuel cells (PEMFC) are provided in thi...

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Published inMacromolecular research Vol. 21; no. 11; pp. 1226 - 1232
Main Authors Kim, Seon Gi, Kim, Jeong-Heon, Yim, Jin-Heong
Format Journal Article
LanguageEnglish
Published Dordrecht Springer Netherlands 01.11.2013
한국고분자학회
Subjects
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Nanochemistry
Nanotechnology
Physical Chemistry
Polymer Sciences
Soft and Granular Matter
고분자공학
polymer electrolyte membrane fuel cell (PEMFC)
imidazole
graphite
bipolar plate
benzoxazine resin
Online AccessGet full text
ISSN1598-5032
2092-7673
DOI10.1007/s13233-013-1166-7

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Abstract The effects of graphite content, compression molding conditions, and types of catalysts on the mechanical and electrical properties and corrosion resistance of a graphite composite based on benzoxazine resin for the bipolar plate of polymer electrolyte membrane fuel cells (PEMFC) are provided in this study. Four kinds of catalysts based on imidazole (Im) acting as catalysts are investigated in order to enhance the physicochemical properties of the graphite/polybenzoxazine composites. The characteristics of the graphite composites based on benzoxazine resin with 85 wt% graphite content prepared via compression molding satisfy the US DOE targets for the bipolar plate of a PEMFC. A graphite composite based on polybenzoxazine with an Im-based catalyst having a relatively long alkyl chain shows the best performance in terms of flexural strength and corrosion resistance without sacrificing electrical conductivity. This graphite/polybenzoxazine composite can be successfully molded as a bipolar plate with excellent physicochemical properties through a compression molding process.
AbstractList The effects of graphite content, compression molding conditions, and types of catalysts on the mechanical and electrical properties and corrosion resistance of a graphite composite based on benzoxazine resin for the bipolar plate of polymer electrolyte membrane fuel cells (PEMFC) are provided in this study. Four kinds of catalysts based on imidazole (Im) acting as catalysts are investigated in order to enhance the physicochemical properties of the graphite/polybenzoxazine composites. The characteristics of the graphite composites based on benzoxazine resin with 85 wt% graphite content prepared via compression molding satisfy the US DOE targets for the bipolar plate of a PEMFC. A graphite composite based on polybenzoxazine with an Im-based catalyst having a relatively long alkyl chain shows the best performance in terms of flexural strength and corrosion resistance without sacrificing electrical conductivity. This graphite/polybenzoxazine composite can be successfully molded as a bipolar plate with excellent physicochemical properties through a compression molding process. KCI Citation Count: 6
The effects of graphite content, compression molding conditions, and types of catalysts on the mechanical and electrical properties and corrosion resistance of a graphite composite based on benzoxazine resin for the bipolar plate of polymer electrolyte membrane fuel cells (PEMFC) are provided in this study. Four kinds of catalysts based on imidazole (Im) acting as catalysts are investigated in order to enhance the physicochemical properties of the graphite/polybenzoxazine composites. The characteristics of the graphite composites based on benzoxazine resin with 85 wt% graphite content prepared via compression molding satisfy the US DOE targets for the bipolar plate of a PEMFC. A graphite composite based on polybenzoxazine with an Im-based catalyst having a relatively long alkyl chain shows the best performance in terms of flexural strength and corrosion resistance without sacrificing electrical conductivity. This graphite/polybenzoxazine composite can be successfully molded as a bipolar plate with excellent physicochemical properties through a compression molding process.
Author Kim, Seon Gi
Kim, Jeong-Heon
Yim, Jin-Heong
Author_xml – sequence: 1
  givenname: Seon Gi
  surname: Kim
  fullname: Kim, Seon Gi
  organization: Division of Advanced Materials Engineering, Kongju National University
– sequence: 2
  givenname: Jeong-Heon
  surname: Kim
  fullname: Kim, Jeong-Heon
  organization: Fuel Cell Development Team, Hankook Tire Co., Ltd
– sequence: 3
  givenname: Jin-Heong
  surname: Yim
  fullname: Yim, Jin-Heong
  email: jhyim@kongju.ac.kr
  organization: Division of Advanced Materials Engineering, Kongju National University
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Issue 11
Keywords polymer electrolyte membrane fuel cell (PEMFC)
imidazole
graphite
bipolar plate
benzoxazine resin
Language English
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한국고분자학회
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Snippet The effects of graphite content, compression molding conditions, and types of catalysts on the mechanical and electrical properties and corrosion resistance of...
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SubjectTerms Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complex Fluids and Microfluidics
Nanochemistry
Nanotechnology
Physical Chemistry
Polymer Sciences
Soft and Granular Matter
고분자공학
Title A study on the physicochemical properties of a graphite/polybenzoxazine composite for bipolar plate of polymer electrolyte membrane fuel cells
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