Photocure kinetics and control of LC microdroplets for acrylate-based polymer dispersed liquid crystal with different methacrylate contents

• Published in: Macromolecular research Vol. 21; no. 12; pp. 1297 - 1304
• Main Authors: Cho, Jung-Dae, Lee, Sang-Sub, Kim, Yang-Bae, Hong, Jin-Who
• Format: Journal Article
• Language: English
• Published: Dordrecht Springer Netherlands 01.12.2013; 한국고분자학회
• Subjects: Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Complex Fluids and Microfluidics; Nanochemistry; Nanotechnology; Physical Chemistry; Polymer Sciences; Soft and Granular Matter; 고분자공학; polymer dispersed liquid crystal (PDLC); photo-DSC; autocatalytic kinetics model; LC droplets; photocure kinetics
• ISSN: 1598-5032; 2092-7673
• DOI: 10.1007/s13233-013-1176-5

This paper reports on the relationship between the photocure kinetics and the morphological properties of UV-curable acrylate-based polymer dispersed liquid crystal (PDLC) systems with the various 2-ethylhexylacrylate (2-EHA) and 2-ethylhexylmethacrylate (2-EHMA) contents using photo-differential scanning calorimetry (photo-DSC), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscopy (SEM). Photo-DSC analysis using an autocatalytic kinetics model demonstrated that the cure extent and cure rate gradually decreased and then leveled off as the concentration of 2-EHMA increased up to 25 wt%, which was well confirmed by using FTIR spectroscopy. The morphological observations revealed that increasing the 2-EHMA content increased the size of the LC droplets within the acrylate-based polymer matrix. Notably, there was a marked increase in the number of LC droplets larger than 10 μm in PDLC composites containing more than 20 wt% 2-EHMA, suggesting that the addition of more than 20 wt% 2-EHMA to the acrylate-based PDLC compounds is not desirable. The presence of 2-EHMA clearly affected the photocure behaviors of acrylate-based PDLC compounds, which interestingly means that the slow reactivity of methacrylate monomer could be simply used to control the phase separation rate and the microstructures of LC droplets of acrylate-based PDLC systems.