LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution
An excellent second harmonic generation (SHG) material, LiMg(IO 3 ) 3 (LMIO), has been elaborately designed from Li 2 M IV (IO 3 ) 6 (M IV = Ti, Sn, and Ge) by aliovalent substitution of the central M IV cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of...
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| Published in | Chemical science (Cambridge) Vol. 10; no. 47; pp. 10870 - 10875 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
21.12.2019
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| Subjects | |
| Online Access | Get full text |
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| Abstract | An excellent second harmonic generation (SHG) material, LiMg(IO
3
)
3
(LMIO), has been elaborately designed from Li
2
M
IV
(IO
3
)
6
(M
IV
= Ti, Sn, and Ge) by aliovalent substitution of the central M
IV
cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO
3
)
−
groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH
2
PO
4
(KDP) under 1064 nm laser radiation or 1.5 × AgGaS
2
(AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO
3
(18 × KDP). The replacement of M
IV
with Mg
2+
without d–d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials. |
|---|---|
| AbstractList | An excellent SHG iodate, LiMg(IO
3
)
3
, has been obtained
via
the aliovalent substitution of defect-containing M
IV
sites with ordered Mg
2+
.
An excellent second harmonic generation (SHG) material, LiMg(IO
3
)
3
(LMIO), has been elaborately designed from Li
2
M
IV
(IO
3
)
6
(M
IV
= Ti, Sn, and Ge) by aliovalent substitution of the central M
IV
cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO
3
)
–
groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH
2
PO
4
(KDP) under 1064 nm laser radiation or 1.5 × AgGaS
2
(AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO
3
(18 × KDP). The replacement of M
IV
with Mg
2+
without d–d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials. An excellent second harmonic generation (SHG) material, LiMg(IO3)3 (LMIO), has been elaborately designed from Li2MIV(IO3)6 (MIV = Ti, Sn, and Ge) by aliovalent substitution of the central MIV cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO3)- groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH2PO4 (KDP) under 1064 nm laser radiation or 1.5 × AgGaS2 (AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO3 (18 × KDP). The replacement of MIV with Mg2+ without d-d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials.An excellent second harmonic generation (SHG) material, LiMg(IO3)3 (LMIO), has been elaborately designed from Li2MIV(IO3)6 (MIV = Ti, Sn, and Ge) by aliovalent substitution of the central MIV cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO3)- groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH2PO4 (KDP) under 1064 nm laser radiation or 1.5 × AgGaS2 (AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO3 (18 × KDP). The replacement of MIV with Mg2+ without d-d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials. An excellent second harmonic generation (SHG) material, LiMg(IO ) (LMIO), has been elaborately designed from Li M (IO ) (M = Ti, Sn, and Ge) by aliovalent substitution of the central M cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO ) groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH PO (KDP) under 1064 nm laser radiation or 1.5 × AgGaS (AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO (18 × KDP). The replacement of M with Mg without d-d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials. An excellent second harmonic generation (SHG) material, LiMg(IO3)3 (LMIO), has been elaborately designed from Li2MIV(IO3)6 (MIV = Ti, Sn, and Ge) by aliovalent substitution of the central MIV cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO3)− groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH2PO4 (KDP) under 1064 nm laser radiation or 1.5 × AgGaS2 (AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO3 (18 × KDP). The replacement of MIV with Mg2+ without d–d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials. An excellent second harmonic generation (SHG) material, LiMg(IO 3 ) 3 (LMIO), has been elaborately designed from Li 2 M IV (IO 3 ) 6 (M IV = Ti, Sn, and Ge) by aliovalent substitution of the central M IV cation followed by Wyckoff position exchange. The new structure sustains the ideal-alignment of (IO 3 ) − groups. Importantly, LMIO exhibits an extremely strong SHG effect of roughly 24 × KH 2 PO 4 (KDP) under 1064 nm laser radiation or 1.5 × AgGaS 2 (AGS) under 2.05 μm laser radiation, which is larger than that of α-LiIO 3 (18 × KDP). The replacement of M IV with Mg 2+ without d–d electronic transitions induces an obviously larger band gap (4.34 eV) with a short absorption edge (285 nm). This study shows that single-site aliovalent substitution provides a new synthetic route for designing SHG materials. |
| Author | Mao, Jiang-Gao Zhang, Xiao-Han Mao, Fei-Fei Hu, Chun-Li Chen, Jin Yang, Bing-Ping |
| AuthorAffiliation | c Nanjing Agricultural University , Nanjing 210095 , P. R. China a State Key Laboratory of Structural Chemistry , Fujian Institute of Research on the Structure of Matter , Chinese Academy of Sciences , Fuzhou 350002 , P. R. China . Email: mjg@fjirsm.ac.cn ; Email: clhu@fjirsm.ac.cn b University of Chinese Academy of Sciences , Beijing 100039 , P. R. China |
| AuthorAffiliation_xml | – name: a State Key Laboratory of Structural Chemistry , Fujian Institute of Research on the Structure of Matter , Chinese Academy of Sciences , Fuzhou 350002 , P. R. China . Email: mjg@fjirsm.ac.cn ; Email: clhu@fjirsm.ac.cn – name: b University of Chinese Academy of Sciences , Beijing 100039 , P. R. China – name: c Nanjing Agricultural University , Nanjing 210095 , P. R. China |
| Author_xml | – sequence: 1 givenname: Jin orcidid: 0000-0003-2439-7535 surname: Chen fullname: Chen, Jin organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China – sequence: 2 givenname: Chun-Li surname: Hu fullname: Hu, Chun-Li organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China – sequence: 3 givenname: Fei-Fei orcidid: 0000-0002-8174-0646 surname: Mao fullname: Mao, Fei-Fei organization: Nanjing Agricultural University, Nanjing 210095, P. R. China – sequence: 4 givenname: Xiao-Han surname: Zhang fullname: Zhang, Xiao-Han organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China – sequence: 5 givenname: Bing-Ping surname: Yang fullname: Yang, Bing-Ping organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China – sequence: 6 givenname: Jiang-Gao orcidid: 0000-0002-5101-8898 surname: Mao fullname: Mao, Jiang-Gao organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32190241$$D View this record in MEDLINE/PubMed |
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| Snippet | An excellent second harmonic generation (SHG) material, LiMg(IO
3
)
3
(LMIO), has been elaborately designed from Li
2
M
IV
(IO
3
)
6
(M
IV
= Ti, Sn, and Ge) by... An excellent second harmonic generation (SHG) material, LiMg(IO ) (LMIO), has been elaborately designed from Li M (IO ) (M = Ti, Sn, and Ge) by aliovalent... An excellent second harmonic generation (SHG) material, LiMg(IO3)3 (LMIO), has been elaborately designed from Li2MIV(IO3)6 (MIV = Ti, Sn, and Ge) by aliovalent... An excellent SHG iodate, LiMg(IO 3 ) 3 , has been obtained via the aliovalent substitution of defect-containing M IV sites with ordered Mg 2+ . An excellent... |
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| SubjectTerms | Chemistry Crystallography Germanium Potassium phosphates Rapid prototyping Second harmonic generation Silver gallium sulfide Substitutes Tin |
| Title | LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/32190241 https://www.proquest.com/docview/2320936610 https://www.proquest.com/docview/2379020893 https://pubmed.ncbi.nlm.nih.gov/PMC7066663 |
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