Transition-metal-mediated activation of the heptaarsenide trianion: isolation of a diaryltetraarsenabutadienediide
Reaction of an ethylenediamine solution of K(3)As(7) with the low-valent, low-coordinate cobalt(II) complex [Co(mes)(2)(PEt(2)Ph)(2)] yielded the novel dianionic species [Co(η(3)-As(3)){η(4)-As(4)(mes)(2)}](2-) (1). The [η(4)-As(4)(mes)(2)](2-) moiety present in 1 is a rare example of a group 15 ana...
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| Published in | Chemical communications (Cambridge, England) Vol. 48; no. 100; pp. 12183 - 12185 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
28.12.2012
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| Abstract | Reaction of an ethylenediamine solution of K(3)As(7) with the low-valent, low-coordinate cobalt(II) complex [Co(mes)(2)(PEt(2)Ph)(2)] yielded the novel dianionic species [Co(η(3)-As(3)){η(4)-As(4)(mes)(2)}](2-) (1). The [η(4)-As(4)(mes)(2)](2-) moiety present in 1 is a rare example of a group 15 analogue of a butadienediide. |
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| AbstractList | Reaction of an ethylenediamine solution of K(3)As(7) with the low-valent, low-coordinate cobalt(II) complex [Co(mes)(2)(PEt(2)Ph)(2)] yielded the novel dianionic species [Co(η(3)-As(3)){η(4)-As(4)(mes)(2)}](2-) (1). The [η(4)-As(4)(mes)(2)](2-) moiety present in 1 is a rare example of a group 15 analogue of a butadienediide. Reaction of an ethylenediamine solution of K sub(3)As sub(7) with the low-valent, low-coordinate cobalt(ii) complex [Co(mes) sub(2)(PEt sub(2)Ph) sub(2)] yielded the novel dianionic species [Co( eta super(3)-As sub(3) ){ eta super(4)-As sub(4)(me s) sub(2)}] super(2-) (1). The [ eta super(4)-As sub(4)(me s) sub(2)] super(2-) moiety present in 1 is a rare example of a group 15 analogue of a butadienediide. |
| Author | McGrady, J E Westcott, B H Goicoechea, J M Knapp, Caroline M Raybould, M A C |
| Author_xml | – sequence: 1 givenname: Caroline M surname: Knapp fullname: Knapp, Caroline M organization: Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, UK – sequence: 2 givenname: B H surname: Westcott fullname: Westcott, B H – sequence: 3 givenname: M A C surname: Raybould fullname: Raybould, M A C – sequence: 4 givenname: J E surname: McGrady fullname: McGrady, J E – sequence: 5 givenname: J M surname: Goicoechea fullname: Goicoechea, J M |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23147418$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1021_acs_chemrev_8b00713 crossref_primary_10_1039_C5DT02380G crossref_primary_10_1021_cr500387w crossref_primary_10_1039_c3ic90011h crossref_primary_10_1039_c3ic90001k crossref_primary_10_1002_ange_202217316 crossref_primary_10_1002_cjoc_202100161 crossref_primary_10_1002_anie_201812473 crossref_primary_10_1002_cjoc_202100682 crossref_primary_10_1039_C9CC03079D crossref_primary_10_1002_ange_201812473 crossref_primary_10_1002_anie_201507355 crossref_primary_10_1021_acs_inorgchem_1c03940 crossref_primary_10_1002_anie_202217316 crossref_primary_10_1002_ange_201507355 crossref_primary_10_1002_ejic_202300514 crossref_primary_10_1039_C6DT00028B |
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| Snippet | Reaction of an ethylenediamine solution of K(3)As(7) with the low-valent, low-coordinate cobalt(II) complex [Co(mes)(2)(PEt(2)Ph)(2)] yielded the novel... Reaction of an ethylenediamine solution of K sub(3)As sub(7) with the low-valent, low-coordinate cobalt(ii) complex [Co(mes) sub(2)(PEt sub(2)Ph) sub(2)]... |
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| SubjectTerms | Activation Analogue Ethylenediamine |
| Title | Transition-metal-mediated activation of the heptaarsenide trianion: isolation of a diaryltetraarsenabutadienediide |
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