Polyoxometalate-based organic-inorganic hybrid compounds containing transition metal mixed-organic-ligand complexes of N-containing and pyridinecarboxylate ligands

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 44; no. 19; pp. 8971 - 8983
• Main Authors: Zhao, De-Chuan, Hu, Yang-Yang, Ding, Hong, Guo, Hai-Yang, Cui, Xiao-Bing, Zhang, Xiao, Huo, Qi-Sheng, Xu, Ji-Qing
• Format: Journal Article
• Language: English
• Published: England 21.05.2015
• Subjects: Carboxylic Acids - chemistry; Chains; Crystallography, X-Ray; Degradation; Diffraction; Isomers; Ligands; Models, Molecular; Molecular Structure; Nicotinic acid; Organometallic Compounds - chemical synthesis; Organometallic Compounds - chemistry; Pyridines - chemistry; Rhodamine; Transition Elements - chemistry; Transition metals; Tungsten Compounds - chemistry; X-ray photoelectron spectroscopy

Five new organic–inorganic hybrid compounds based on the Keggin-type polyoxoanion [SiW12O40]4−, namely [Cu3(2,2′-bpy)3(inic)(μ2-OH)(H2O)][SiW12O40]·2H2O (1), [Cu6(phen)6(μ3-Cl)2(μ2-Cl)2Cl2(inic)2][SiW12O40]·6H2O (2), [Cu2(hnic)(2,2′-bpy)2Cl]2[H2SiW12O40] (3), [Cu2(nic)(phen)2Cl2]2[SiW12O40] (4) and...