Materials potentially harder than diamond : quenchable high-pressure phases of transition metal dioxides
Findings are presented from pressure-volume relationships obtained by angle-dispersive x-ray powder diffraction on the high-pressure phases of RuO sub 2 and HfO sub 2 . The results indicate that both are significantly stiffer than cubic boron nitride and are as stiff or stiffer than diamond. It is t...
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Published in | Journal of materials science letters Vol. 13; no. 23; pp. 1688 - 1690 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Dordrecht
Kluwer Academic Publishers
01.01.1994
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Abstract | Findings are presented from pressure-volume relationships obtained by angle-dispersive x-ray powder diffraction on the high-pressure phases of RuO sub 2 and HfO sub 2 . The results indicate that both are significantly stiffer than cubic boron nitride and are as stiff or stiffer than diamond. It is the first time that a high-pressure phase that can be kept in a metastable state under normal pressure is reported to display a higher bulk modulus than diamond. This raises the possibility of finding new stiff materials. From the correlation between bulk modulus and hardness, it is evident that the high-pressure phases of these oxides, and possibly of several other transition metal dioxides, could present a new family of ultra-hard materials. Partial reverse transformation occurred in both compounds, and stabilization of these and other high-pressure oxide phases is discussed. |
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AbstractList | The results of pressure - volume relationships obtained by angle-dispersive X-ray powder diffraction on the high pressure places of ruthenium and hafnium dioxides are presented. These phases were found to have bulk moduli, at ambient pressure, similar to or greater than that of diamond. In both compounds partial reverse transformation occurred. Phase stabilisation could be achieved by heating under high pressure followed by quenching. 16 refs. Findings are presented from pressure-volume relationships obtained by angle-dispersive x-ray powder diffraction on the high-pressure phases of RuO sub 2 and HfO sub 2 . The results indicate that both are significantly stiffer than cubic boron nitride and are as stiff or stiffer than diamond. It is the first time that a high-pressure phase that can be kept in a metastable state under normal pressure is reported to display a higher bulk modulus than diamond. This raises the possibility of finding new stiff materials. From the correlation between bulk modulus and hardness, it is evident that the high-pressure phases of these oxides, and possibly of several other transition metal dioxides, could present a new family of ultra-hard materials. Partial reverse transformation occurred in both compounds, and stabilization of these and other high-pressure oxide phases is discussed. |
Author | LEGER, J. M HAINES, J BLANZAT, B |
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Cites_doi | 10.1038/337349a0 10.1063/1.325497 10.1002/adma.19920041114 10.1103/PhysRev.71.809 10.1063/1.325277 10.1103/PhysRevB.48.13344 10.1016/0012-821X(77)90015-2 10.1007/BF00309573 10.1103/PhysRevB.48.93 10.1063/1.1141918 10.1016/0022-3697(81)90074-3 10.1103/PhysRevB.45.10123 |
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Keywords | Cubic lattices Pressure volume ratio Inorganic compounds Pressure effects Equations of state Tetragonal lattices Phase transformations Transition element compounds Ruthenium oxides Experimental study Lattice parameters Knoop hardness |
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References | R. J. Goble (CR3) 1985; 23 I. V. Aleksandrov (CR2) 1987; 66 R. Riedel (CR1) 1992; 4 T. Mashimo (CR6) 1983; 9 M. Ueno (CR7) 1992; 45 J. Haines (CR14) 1993; 48 F. Birch (CR15) 1947; 71 K. Syassen (CR11) 1978; 49 H. K. Mao (CR12) 1978; 49 J. M. Leger (CR10) 1993; 48 J. M. Gonzalez-calbet (CR16) 1983; 3 C. Meade (CR13) 1990; 61 O. L. Anderson (CR5) 1972 R. M. Hazen (CR8) 1981; 42 E. Knittle (CR4) 1989; 337 Y. Sato (CR9) 1977; 34 |
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Snippet | Findings are presented from pressure-volume relationships obtained by angle-dispersive x-ray powder diffraction on the high-pressure phases of RuO sub 2 and... The results of pressure - volume relationships obtained by angle-dispersive X-ray powder diffraction on the high pressure places of ruthenium and hafnium... |
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SubjectTerms | Condensed matter: structure, mechanical and thermal properties Equations of state, phase equilibria, and phase transitions Exact sciences and technology Physics Solid-solid transitions Specific phase transitions |
Title | Materials potentially harder than diamond : quenchable high-pressure phases of transition metal dioxides |
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