The impact of B2O3/Al2O3 substitution on physical properties and γ-ray shielding competence of aluminum-borate glasses: comparative study

This work investigates the impact of B 2 O 3 /Al 2 O 3 substitution on the physical properties and γ-ray shielding parameters in the γ-energy range of 0.015: 15 MeV of the aluminum-borate glasses with the composition: (75-X)B 2 O 3  + 10ZnO + 10CdO + 5Na 2 O + XAl 2 O 3 where X = 5 (BNCZAl-5)–20 (BN...

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Published inJournal of materials science. Materials in electronics Vol. 35; no. 12; p. 845
Main Authors Abouhaswa, A. S., Abdelghany, A. M., Alfryyan, Nada, Alsaif, Norah A. M., Rammah, Y. S., Nabil, Islam M.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.04.2024
Springer Nature B.V
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Abstract This work investigates the impact of B 2 O 3 /Al 2 O 3 substitution on the physical properties and γ-ray shielding parameters in the γ-energy range of 0.015: 15 MeV of the aluminum-borate glasses with the composition: (75-X)B 2 O 3  + 10ZnO + 10CdO + 5Na 2 O + XAl 2 O 3 where X = 5 (BNCZAl-5)–20 (BNCZAl-20)% mol (with step of 5%). Samples were fabricated using the well-known melt quenching technique. The density (ρ) increased gradually from 3.492 to 3.901 g/cm 3 and molar volume (V m ) decreased from 22.311 to 21.216 cm 3 /mol as the Al 2 O 3 content increased from 5 to 20 mol%. The oxygen molar volume (OMV) increased from 9.107 to 9.868 cm 3 /mol, while the oxygen packing density (OPD) values decreased from 109.810 to 101.341 g.atom/l. Linear-attenuation coefficient (μ) followed the order: BNCZAl-5 < BNCZAl-10 < BNCZAl-15 < BNCZAl-20. The sample that coded as BNCZAL-20 (highest content of Al 2 O 3 ) possessed the lowest half-value (HVL) and tenth-value (TVL) layers among all studied samples. Within the investigated energy range of Zef Z ef within the range: from 27.324 to 10.783, 26.820 to 10.957, 26.351 to 11.128, and 25.915 to 11.296 for the prepared samples BNCZAl-5, BNCZAl-10, BNCZAl-15, and BNCZAl-20 glasses, respectively. The obtained results confirmed that the suggested glasses can be used as alternative materials for radiation shielding applications.
AbstractList This work investigates the impact of B2O3/Al2O3 substitution on the physical properties and γ-ray shielding parameters in the γ-energy range of 0.015: 15 MeV of the aluminum-borate glasses with the composition: (75-X)B2O3 + 10ZnO + 10CdO + 5Na2O + XAl2O3 where X = 5 (BNCZAl-5)–20 (BNCZAl-20)% mol (with step of 5%). Samples were fabricated using the well-known melt quenching technique. The density (ρ) increased gradually from 3.492 to 3.901 g/cm3 and molar volume (Vm) decreased from 22.311 to 21.216 cm3/mol as the Al2O3 content increased from 5 to 20 mol%. The oxygen molar volume (OMV) increased from 9.107 to 9.868 cm3/mol, while the oxygen packing density (OPD) values decreased from 109.810 to 101.341 g.atom/l. Linear-attenuation coefficient (μ) followed the order: BNCZAl-5 < BNCZAl-10 < BNCZAl-15 < BNCZAl-20. The sample that coded as BNCZAL-20 (highest content of Al2O3) possessed the lowest half-value (HVL) and tenth-value (TVL) layers among all studied samples. Within the investigated energy range of ZefZef within the range: from 27.324 to 10.783, 26.820 to 10.957, 26.351 to 11.128, and 25.915 to 11.296 for the prepared samples BNCZAl-5, BNCZAl-10, BNCZAl-15, and BNCZAl-20 glasses, respectively. The obtained results confirmed that the suggested glasses can be used as alternative materials for radiation shielding applications.
This work investigates the impact of B 2 O 3 /Al 2 O 3 substitution on the physical properties and γ-ray shielding parameters in the γ-energy range of 0.015: 15 MeV of the aluminum-borate glasses with the composition: (75-X)B 2 O 3  + 10ZnO + 10CdO + 5Na 2 O + XAl 2 O 3 where X = 5 (BNCZAl-5)–20 (BNCZAl-20)% mol (with step of 5%). Samples were fabricated using the well-known melt quenching technique. The density (ρ) increased gradually from 3.492 to 3.901 g/cm 3 and molar volume (V m ) decreased from 22.311 to 21.216 cm 3 /mol as the Al 2 O 3 content increased from 5 to 20 mol%. The oxygen molar volume (OMV) increased from 9.107 to 9.868 cm 3 /mol, while the oxygen packing density (OPD) values decreased from 109.810 to 101.341 g.atom/l. Linear-attenuation coefficient (μ) followed the order: BNCZAl-5 < BNCZAl-10 < BNCZAl-15 < BNCZAl-20. The sample that coded as BNCZAL-20 (highest content of Al 2 O 3 ) possessed the lowest half-value (HVL) and tenth-value (TVL) layers among all studied samples. Within the investigated energy range of Zef Z ef within the range: from 27.324 to 10.783, 26.820 to 10.957, 26.351 to 11.128, and 25.915 to 11.296 for the prepared samples BNCZAl-5, BNCZAl-10, BNCZAl-15, and BNCZAl-20 glasses, respectively. The obtained results confirmed that the suggested glasses can be used as alternative materials for radiation shielding applications.
ArticleNumber 845
Author Abouhaswa, A. S.
Abdelghany, A. M.
Nabil, Islam M.
Alfryyan, Nada
Rammah, Y. S.
Alsaif, Norah A. M.
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  fullname: Abdelghany, A. M.
  organization: Physics Division, Spectroscopy Department, National Research Center, Basic Science Department, Horus University
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  givenname: Nada
  surname: Alfryyan
  fullname: Alfryyan, Nada
  organization: Physics Department, College of Science, Princess Nourah Bint Abdulrahman University
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  givenname: Norah A. M.
  surname: Alsaif
  fullname: Alsaif, Norah A. M.
  organization: Physics Department, College of Science, Princess Nourah Bint Abdulrahman University
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  givenname: Islam M.
  surname: Nabil
  fullname: Nabil, Islam M.
  organization: Physics Department, Faculty of Science, Fayoum University
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Snippet This work investigates the impact of B 2 O 3 /Al 2 O 3 substitution on the physical properties and γ-ray shielding parameters in the γ-energy range of 0.015:...
This work investigates the impact of B2O3/Al2O3 substitution on the physical properties and γ-ray shielding parameters in the γ-energy range of 0.015: 15 MeV...
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SubjectTerms Aluminum
Aluminum oxide
Attenuation coefficients
Boron oxides
Characterization and Evaluation of Materials
Chemistry and Materials Science
Comparative studies
Gamma rays
Materials Science
Molar volume
Optical and Electronic Materials
Oxygen
Packing density
Physical properties
Radiation shielding
Substitutes
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Title The impact of B2O3/Al2O3 substitution on physical properties and γ-ray shielding competence of aluminum-borate glasses: comparative study
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