Extraction of microamounts of europium and americium by using hydrogen dicarbollylcobaltate in the presence of dibutyl diethylcarbamoylmethylene phosphonate
Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H + B − ) in the presence of dibutyl diethylcarbamoylmethylene phosphonate (DBDECMP, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL + ,...
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| Published in | Journal of radioanalytical and nuclear chemistry Vol. 275; no. 2; pp. 309 - 312 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Dordrecht
Springer Netherlands
01.02.2008
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of dibutyl diethylcarbamoylmethylene phosphonate (DBDECMP, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL
+
, HL
2
2+
ML
3
3+
and ML
4
3+
(M
3+
= Eu
3+
, Am
3+
) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. |
|---|---|
| AbstractList | Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of dibutyl diethylcarbamoylmethylene phosphonate (DBDECMP, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL
+
, HL
2
2+
ML
3
3+
and ML
4
3+
(M
3+
= Eu
3+
, Am
3+
) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (HB) in the presence of dibutyl diethylcarbamoylmethylene phosphonate (DBDECMP, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL, HL2 ML3 and ML4 (M = Eu, Am) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. |
| Author | Vaňura, P. Selucký, P. Makrlík, E. |
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| Cites_doi | 10.1016/S0956-053X(98)00015-4 10.1080/07366299208918094 10.1135/cccc19931324 10.1007/s10967-006-0071-3 10.1016/0039-9140(85)80110-7 10.1021/ja01006a008 10.1135/cccc19920289 10.1080/01496398808075625 10.1080/01496399108050526 10.1524/ract.91.3.127.19983 10.1135/cccc19860498 10.1080/07366299208918124 10.1135/cccc19821444 10.1080/01496399408006945 10.1007/s10967-006-0037-5 |
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| Keywords | Americium Nitrobenzene Phosphine Oxide Nitrobenzene Phase Nitrobenzene Solution |
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| Snippet | Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H
+
B
−
) in the presence of dibutyl... Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (HB) in the presence of dibutyl... |
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| SubjectTerms | Chemistry Chemistry and Materials Science Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Nuclear Chemistry Nuclear Physics Physical Chemistry |
| Title | Extraction of microamounts of europium and americium by using hydrogen dicarbollylcobaltate in the presence of dibutyl diethylcarbamoylmethylene phosphonate |
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