Ligand-based poly(phenylenediamine) adsorbents for enhanced removal of phosphate from water

Phosphorus removal from effluents is vital to avoid eutrophication. The subject study presents the development and performance of poly(phenylenediamine) isometric adsorbents produced through oxidation using (NH 4 ) 2 S 2 O 8 and K 2 Cr 2 O 7 oxidants. K 2 Cr 2 O 7 synthesized polymers showed better...

Full description

Saved in:

Bibliographic Details
Published in	Polymer bulletin (Berlin, Germany) Vol. 79; no. 10; pp. 8743 - 8763
Main Authors	Mdlalose, Lindani, Balogun, Mohammed, Setshedi, Katlego, Klavins, Maris, Chimuka, Luke, Chetty, Avashnee
Format	Journal Article
Language	English
Published	Berlin/Heidelberg Springer Berlin Heidelberg 01.10.2022 Springer Nature B.V
Subjects	Adsorbents Adsorption Caustic soda Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Eutrophication Fourier transforms Lewis acid Ligands Mass transfer Organic Chemistry Original Paper Oxidation Oxidizing agents Phenylenediamine Phosphates Phosphorus Phosphorus removal Physical Chemistry Polymer Sciences Polymerization Polymers Potassium Potassium dichromate Sodium Soft and Granular Matter Sorbents Spectrum analysis Synthesis Phosphates Regeneration Poly(phenylenediamine) isomers Adsorption Inner-sphere complexing
Online Access	Get full text

Cover

Loading…

Abstract	Phosphorus removal from effluents is vital to avoid eutrophication. The subject study presents the development and performance of poly(phenylenediamine) isometric adsorbents produced through oxidation using (NH 4 ) 2 S 2 O 8 and K 2 Cr 2 O 7 oxidants. K 2 Cr 2 O 7 synthesized polymers showed better adsorption capacities. The presence of Cr Lewis acid on the surface endorsed phosphate interaction through inner-sphere complex mechanism. The maximum adsorption capacities for K 2 Cr 2 O 7 synthesized polymers were 143, 217 and 69.0 mg/L for poly( o -phenylenediamine), poly( m -phenylenediamine) and poly( p -phenylenediamine) adsorbents, respectively. The superior performance of poly( m -phenylenediamine) was associated with minimal symmetrical arrangement, hence it was more amorphous as indicated by XRD patterns. Kinetic model fitted pseudo-second-order and isotherm favoured Langmuir. Adsorption process was also controlled by pore diffusion and external mass transfer in the sorbent. Poly( m -phenylenediamine) displayed high affinity in the presence of competing anions and was amenable to recycling.
AbstractList	Phosphorus removal from effluents is vital to avoid eutrophication. The subject study presents the development and performance of poly(phenylenediamine) isometric adsorbents produced through oxidation using (NH4)2S2O8 and K2Cr2O7 oxidants. K2Cr2O7 synthesized polymers showed better adsorption capacities. The presence of Cr Lewis acid on the surface endorsed phosphate interaction through inner-sphere complex mechanism. The maximum adsorption capacities for K2Cr2O7 synthesized polymers were 143, 217 and 69.0 mg/L for poly(o-phenylenediamine), poly(m-phenylenediamine) and poly(p-phenylenediamine) adsorbents, respectively. The superior performance of poly(m-phenylenediamine) was associated with minimal symmetrical arrangement, hence it was more amorphous as indicated by XRD patterns. Kinetic model fitted pseudo-second-order and isotherm favoured Langmuir. Adsorption process was also controlled by pore diffusion and external mass transfer in the sorbent. Poly(m-phenylenediamine) displayed high affinity in the presence of competing anions and was amenable to recycling. Phosphorus removal from effluents is vital to avoid eutrophication. The subject study presents the development and performance of poly(phenylenediamine) isometric adsorbents produced through oxidation using (NH 4 ) 2 S 2 O 8 and K 2 Cr 2 O 7 oxidants. K 2 Cr 2 O 7 synthesized polymers showed better adsorption capacities. The presence of Cr Lewis acid on the surface endorsed phosphate interaction through inner-sphere complex mechanism. The maximum adsorption capacities for K 2 Cr 2 O 7 synthesized polymers were 143, 217 and 69.0 mg/L for poly( o -phenylenediamine), poly( m -phenylenediamine) and poly( p -phenylenediamine) adsorbents, respectively. The superior performance of poly( m -phenylenediamine) was associated with minimal symmetrical arrangement, hence it was more amorphous as indicated by XRD patterns. Kinetic model fitted pseudo-second-order and isotherm favoured Langmuir. Adsorption process was also controlled by pore diffusion and external mass transfer in the sorbent. Poly( m -phenylenediamine) displayed high affinity in the presence of competing anions and was amenable to recycling.
Author	Mdlalose, Lindani Chetty, Avashnee Setshedi, Katlego Balogun, Mohammed Chimuka, Luke Klavins, Maris
Author_xml	– sequence: 1 givenname: Lindani surname: Mdlalose fullname: Mdlalose, Lindani email: lmdlalose1@csir.co.za organization: Centre for Nanostructures and Advanced Materials (CeNAM), Council for Scientific and Industrial Research – sequence: 2 givenname: Mohammed surname: Balogun fullname: Balogun, Mohammed organization: Centre for Nanostructures and Advanced Materials (CeNAM), Council for Scientific and Industrial Research – sequence: 3 givenname: Katlego surname: Setshedi fullname: Setshedi, Katlego organization: Centre for Nanostructures and Advanced Materials (CeNAM), Council for Scientific and Industrial Research – sequence: 4 givenname: Maris surname: Klavins fullname: Klavins, Maris organization: Department of Environmental Science, University of Latvia – sequence: 5 givenname: Luke surname: Chimuka fullname: Chimuka, Luke organization: Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand WITS – sequence: 6 givenname: Avashnee surname: Chetty fullname: Chetty, Avashnee organization: Centre for Nanostructures and Advanced Materials (CeNAM), Council for Scientific and Industrial Research
BookMark	eNp9kD9PwzAQxS1UJNrCF2CKxAKD4ey4STyiin9SJRaYGCwnvjSpEjvYKajfHkORkBi63L2T3u_u9GZkYp1FQs4ZXDOA_CYA8EJS4IxCKjmn4ohMmUgzyoWQEzIFlgOFIpUnZBbCBuKcZWxK3lbtWltDSx3QJIPrdpdDg3bXoUXT6r61eJVoE5wv0Y4hqZ1P0DbaVtHusXcfuktcnQyNC0OjR0xq7_rkMyp_So5r3QU8--1z8np_97J8pKvnh6fl7YpWKZMjlYsSBRRFZhaLUhjJ81jzMgeUaSmYKJgEU9cVVMiZFqwsTM1NJqKsKs1lOicX-72Dd-9bDKPauK238aTikhWwyHnGo6vYuyrvQvBYq6od9dg6O3rddoqB-o5S7aNUMUr1E6USEeX_0MG3vfa7w1C6h0I02zX6v68OUF89TYk0
CitedBy_id	crossref_primary_10_61186_MCH_2025_1070
Cites_doi	10.1155/2014/961617 10.1016/j.jiec.2013.11.016 10.1016/j.cej.2017.01.066 10.1016/j.progpolymsci.2014.10.007 10.1016/j.jhazmat.2006.10.046 10.1002/pat.2018 10.1016/j.dib.2017.11.098 10.1016/j.apcatb.2015.04.047 10.1016/j.clay.2017.01.015 10.1016/j.chemosphere.2014.02.024 10.1016/j.chemosphere.2007.04.022 10.1016/j.chemosphere.2017.09.088 10.1016/j.jece.2013.07.031 10.1016/j.jhazmat.2013.06.045 10.1016/j.cej.2012.01.089 10.1002/chem.200501070 10.1080/10643389.2012.741311 10.1016/j.cej.2013.10.013 10.1016/j.cej.2013.02.061 10.1016/j.cej.2015.01.070 10.1016/j.powtec.2015.02.055 10.1016/j.jconhyd.2011.12.001 10.1016/j.pbi.2009.04.003 10.1016/j.bios.2012.07.012 10.1016/S0043-1354(97)00371-0 10.1021/la802410p 10.1039/C4RA14630A 10.1021/sc5003209 10.1016/j.eurpolymj.2009.12.007
ContentType	Journal Article
Copyright	The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.
Copyright_xml	– notice: The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021 – notice: The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2021.
DBID	AAYXX CITATION 8FE 8FG ABJCF AFKRA BENPR BGLVJ CCPQU D1I DWQXO HCIFZ KB. PDBOC PHGZM PHGZT PKEHL PQEST PQGLB PQQKQ PQUKI
DOI	10.1007/s00289-021-03922-4
DatabaseName	CrossRef ProQuest SciTech Collection ProQuest Technology Collection Materials Science & Engineering Collection ProQuest Central UK/Ireland ProQuest Central Technology Collection ProQuest One ProQuest Materials Science Collection ProQuest Central Korea SciTech Collection (ProQuest) Materials Science Database Materials Science Collection ProQuest Central Premium ProQuest One Academic (New) ProQuest One Academic Middle East (New) ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Applied & Life Sciences ProQuest One Academic ProQuest One Academic UKI Edition
DatabaseTitle	CrossRef ProQuest Materials Science Collection Technology Collection ProQuest One Academic Middle East (New) ProQuest One Academic Eastern Edition Materials Science Collection SciTech Premium Collection ProQuest One Community College ProQuest Technology Collection ProQuest SciTech Collection ProQuest Central ProQuest One Applied & Life Sciences ProQuest One Academic UKI Edition ProQuest Central Korea Materials Science & Engineering Collection Materials Science Database ProQuest One Academic ProQuest Central (New) ProQuest One Academic (New)
DatabaseTitleList	ProQuest Materials Science Collection
Database_xml	– sequence: 1 dbid: 8FG name: ProQuest Technology Collection url: https://search.proquest.com/technologycollection1 sourceTypes: Aggregation Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1436-2449
EndPage	8763
ExternalDocumentID	10_1007_s00289_021_03922_4
GrantInformation_xml	– fundername: National Research Foundation grantid: 88568 funderid: http://dx.doi.org/10.13039/501100001321 – fundername: Erasmus Mundus grantid: ES15DM0040
GroupedDBID	-4Y -58 -5G -BR -EM -Y2 -~C -~X .86 .VR 06C 06D 0R~ 0VY 123 199 1N0 1SB 2.D 203 28- 29O 2J2 2JN 2JY 2KG 2KM 2LR 2P1 2VQ 2~H 30V 4.4 406 408 409 40D 40E 53G 5QI 5VS 67Z 6NX 78A 8TC 8UJ 95- 95. 95~ 96X AAAVM AABHQ AACDK AAHNG AAIAL AAIKT AAJBT AAJKR AANZL AARHV AARTL AASML AATNV AATVU AAUYE AAWCG AAYIU AAYQN AAYTO AAYZH ABAKF ABBBX ABBXA ABDZT ABECU ABFTD ABFTV ABHLI ABHQN ABJCF ABJNI ABJOX ABKCH ABKTR ABMNI ABMQK ABNWP ABQBU ABQSL ABSXP ABTEG ABTHY ABTKH ABTMW ABULA ABWNU ABXPI ACAOD ACBXY ACDTI ACGFS ACHSB ACHXU ACIWK ACKNC ACMDZ ACMLO ACOKC ACOMO ACPIV ACZOJ ADHHG ADHIR ADIMF ADINQ ADKNI ADKPE ADRFC ADTPH ADURQ ADYFF ADZKW AEBTG AEFIE AEFQL AEGAL AEGNC AEJHL AEJRE AEKMD AEMSY AENEX AEOHA AEPYU AESKC AETLH AEVLU AEXYK AFBBN AFEXP AFFNX AFGCZ AFKRA AFLOW AFQWF AFWTZ AFZKB AGAYW AGDGC AGGDS AGJBK AGMZJ AGQEE AGQMX AGRTI AGWIL AGWZB AGYKE AHAVH AHBYD AHKAY AHSBF AHYZX AIAKS AIGIU AIIXL AILAN AITGF AJBLW AJRNO AJZVZ ALMA_UNASSIGNED_HOLDINGS ALWAN AMKLP AMXSW AMYLF AMYQR AOCGG ARMRJ ASPBG AVWKF AXYYD AYJHY AZFZN B-. BA0 BBWZM BDATZ BENPR BGLVJ BGNMA BSONS CAG CCPQU COF CS3 CSCUP DDRTE DL5 DNIVK DPUIP DU5 EBLON EBS EIOEI EJD ESBYG FEDTE FERAY FFXSO FIGPU FINBP FNLPD FRRFC FSGXE FWDCC G-Y G-Z GGCAI GGRSB GJIRD GNWQR GQ6 GQ7 GQ8 GXS H13 HCIFZ HF~ HG5 HG6 HMJXF HQYDN HRMNR HVGLF HZ~ I09 IHE IJ- IKXTQ ITM IWAJR IXC IZIGR IZQ I~X I~Z J-C J0Z JBSCW JCJTX JZLTJ KB. KDC KOV KOW LAS LLZTM M4Y MA- N2Q N9A NB0 NDZJH NPVJJ NQJWS NU0 O9- O93 O9G O9I O9J OAM P19 P2P P9N PDBOC PF- PT4 PT5 QOK QOR QOS R4E R89 R9I RHV RIG RNI RNS ROL RPX RSV RZK S16 S1Z S26 S27 S28 S3B SAP SCG SCLPG SCM SDH SDM SHX SISQX SJYHP SNE SNPRN SNX SOHCF SOJ SPISZ SRMVM SSLCW STPWE SZN T13 T16 TN5 TSG TSK TSV TUC U2A UG4 UOJIU UTJUX UZXMN VC2 VFIZW W23 W48 W4F WH7 WJK WK8 YLTOR Z45 Z5O Z7R Z7S Z7U Z7V Z7W Z7X Z7Y Z7Z Z81 Z83 Z85 Z86 Z87 Z88 Z8M Z8N Z8O Z8P Z8Q Z8R Z8S Z8T Z8U Z8W Z8Z Z91 Z92 ZMTXR ~A9 ~EX AAPKM AAYXX ABBRH ABDBE ABFSG ACSTC ADHKG AEZWR AFDZB AFHIU AFOHR AGQPQ AHPBZ AHWEU AIXLP ATHPR AYFIA CITATION PHGZM PHGZT 8FE 8FG ABRTQ D1I DWQXO PKEHL PQEST PQGLB PQQKQ PQUKI
ID	FETCH-LOGICAL-c319t-95be40886d55b4d927b4d7b70e93b4148190dffc0ce21a41b8df2d64a41cca293
IEDL.DBID	BENPR
ISSN	0170-0839
IngestDate	Sat Aug 23 13:43:39 EDT 2025 Tue Jul 01 01:22:27 EDT 2025 Thu Apr 24 23:04:41 EDT 2025 Fri Feb 21 02:45:54 EST 2025
IsPeerReviewed	true
IsScholarly	true
Issue	10
Keywords	Phosphates Regeneration Poly(phenylenediamine) isomers Adsorption Inner-sphere complexing
Language	English
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c319t-95be40886d55b4d927b4d7b70e93b4148190dffc0ce21a41b8df2d64a41cca293
Notes	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14
PQID	2918057262
PQPubID	2043614
PageCount	21
ParticipantIDs	proquest_journals_2918057262 crossref_citationtrail_10_1007_s00289_021_03922_4 crossref_primary_10_1007_s00289_021_03922_4 springer_journals_10_1007_s00289_021_03922_4
ProviderPackageCode	CITATION AAYXX
PublicationCentury	2000
PublicationDate	2022-10-01
PublicationDateYYYYMMDD	2022-10-01
PublicationDate_xml	– month: 10 year: 2022 text: 2022-10-01 day: 01
PublicationDecade	2020
PublicationPlace	Berlin/Heidelberg
PublicationPlace_xml	– name: Berlin/Heidelberg – name: Heidelberg
PublicationTitle	Polymer bulletin (Berlin, Germany)
PublicationTitleAbbrev	Polym. Bull
PublicationYear	2022
Publisher	Springer Berlin Heidelberg Springer Nature B.V
Publisher_xml	– name: Springer Berlin Heidelberg – name: Springer Nature B.V
References	Unuabonah, Adebowale, Olu-Owolabi (CR26) 2007; 144 Loganathan, Vigneswaran, Kandasamy, Bolan (CR4) 2014; 44 Zhou, Badashah, Luo, Liu, Zhao (CR22) 2011; 22 Wang, Feng, Chen, Wang, Yan (CR5) 2017; 316 Yu, Zhang, Wang, Chai (CR11) 2013; 260 CR19 Tseng, Wu, Wu, Juang (CR14) 2014; 237 Liu, Zhang (CR28) 2015; 277 Jeppu, Clement (CR16) 2012; 129–130 Toor, Jin (CR15) 2012; 187 Wu, Lam, Lee, Lau (CR7) 2007; 69 Acelas, Martin, Lopez, Jefferson (CR25) 2015; 119 Mdlalose, Balogun, Setshedi, Tukulula, Chimuka, Chetty (CR12) 2017; 139 Lov, Sjostedt, Larsbo, Persson, Gustafsson, Cornerlis, Kleja (CR10) 2017; 189 Cheng, Wang, Doudrick, Chan (CR20) 2015; 176–177 Thenmozhi, Arockiasamy, Santhi (CR21) 2014; 2014 Maathuis (CR1) 2009; 12 Warwick, Guerreiro, Soares (CR2) 2013; 41 Su, Yang, Sun, Li, Shang (CR24) 2015; 268 Setshedi, Bhaumik, Songwane, Onyango, Maity (CR17) 2013; 222 Zhao, Sengupta (CR6) 1998; 32 Prasetyo, Ratri, Isnadina (CR13) 2018; 16 Stejskal (CR9) 2015; 41 Qiu, Xu, Sun, Yi, Guo, Zhang, Qu, Guerrero, Wang, Noel, Luo, Gou, Wei (CR8) 2014; 2 Li, Ma, Sun, Huang (CR18) 2009; 25 Shen, Wang, Zhou, Chen, Hu, Dong, Xia (CR29) 2015; 5 Sowmya, Meenakshi (CR3) 2013; 1 Huang, Peng, Li (CR23) 2006; 12 Awual, Shenashen, Jyo, Shiwaku, Yaita (CR27) 2014; 20 RL Tseng (3922_CR14) 2014; 237 M Toor (3922_CR15) 2012; 187 G Thenmozhi (3922_CR21) 2014; 2014 A Sowmya (3922_CR3) 2013; 1 Y Su (3922_CR24) 2015; 268 H Shen (3922_CR29) 2015; 5 XG Li (3922_CR18) 2009; 25 MR Awual (3922_CR27) 2014; 20 C Warwick (3922_CR2) 2013; 41 A Lov (3922_CR10) 2017; 189 GP Jeppu (3922_CR16) 2012; 129–130 NY Acelas (3922_CR25) 2015; 119 B Qiu (3922_CR8) 2014; 2 Q Cheng (3922_CR20) 2015; 176–177 D Zhao (3922_CR6) 1998; 32 L Mdlalose (3922_CR12) 2017; 139 P Loganathan (3922_CR4) 2014; 44 N Wang (3922_CR5) 2017; 316 W Yu (3922_CR11) 2013; 260 RSS Wu (3922_CR7) 2007; 69 H Zhou (3922_CR22) 2011; 22 J Stejskal (3922_CR9) 2015; 41 KZ Setshedi (3922_CR17) 2013; 222 X Liu (3922_CR28) 2015; 277 E Prasetyo (3922_CR13) 2018; 16 3922_CR19 EI Unuabonah (3922_CR26) 2007; 144 FJ Maathuis (3922_CR1) 2009; 12 MR Huang (3922_CR23) 2006; 12
References_xml	– volume: 2014 start-page: 1 year: 2014 end-page: 11 ident: CR21 article-title: Isomers of poly aminophenol: chemical synthesis, characterization, and its corrosion protection aspect on mild steel in 1 M HCl publication-title: Int J Electrochem doi: 10.1155/2014/961617 – volume: 20 start-page: 2840 year: 2014 end-page: 2847 ident: CR27 article-title: Preparing of novel fibrous ligand exchange adsorbent for rapid column-mode trace phosphate removal from water publication-title: J Ind Eng Chem doi: 10.1016/j.jiec.2013.11.016 – volume: 316 start-page: 33 year: 2017 end-page: 40 ident: CR5 article-title: Adsorption mechanism of phosphate by polyaniline/TiO2 composite from wastewater publication-title: Chem Eng J doi: 10.1016/j.cej.2017.01.066 – volume: 41 start-page: 1 year: 2015 end-page: 31 ident: CR9 article-title: Polymers of phenylenediamines publication-title: Prog Polym Sci doi: 10.1016/j.progpolymsci.2014.10.007 – volume: 144 start-page: 386 year: 2007 end-page: 395 ident: CR26 article-title: Kinetic and thermodynamic studies of the adsorption of lead (II) ions onto phosphate-modified kaolinite clay publication-title: J Hazard Mater doi: 10.1016/j.jhazmat.2006.10.046 – volume: 22 start-page: 1459 year: 2011 end-page: 1465 ident: CR22 article-title: Preparation and property comparison of ortho, meta, and para autocatalytic phthalonitrile compounds with amino group publication-title: Polym Adv Technol doi: 10.1002/pat.2018 – volume: 16 start-page: 622 year: 2018 end-page: 629 ident: CR13 article-title: Characterization, kinetic, and isotherm data for adsorption of Pb2+ from aqueous solution by adsorbent from mixture of bagasse-bentonite publication-title: Data Brief doi: 10.1016/j.dib.2017.11.098 – volume: 176–177 start-page: 740 year: 2015 end-page: 748 ident: CR20 article-title: Hexavalent chromium removal using metal oxide photocatalysts publication-title: Appl Catal B: Environ doi: 10.1016/j.apcatb.2015.04.047 – volume: 139 start-page: 72 year: 2017 end-page: 80 ident: CR12 article-title: Synthesis, characterization and optimization of poly(p-phenylenediamine)-based organoclay composite for Cr(VI) remediation publication-title: Appl Clay Sci doi: 10.1016/j.clay.2017.01.015 – volume: 119 start-page: 1353 year: 2015 end-page: 1360 ident: CR25 article-title: Selective removal of phosphate from wastewater using hydrated metal oxides dispersed within anionic exchange media publication-title: Chemosphere doi: 10.1016/j.chemosphere.2014.02.024 – volume: 69 start-page: 289 year: 2007 end-page: 294 ident: CR7 article-title: Removal of phosphate from water by a highly selective La(III)-chelex resin publication-title: Chemosphere doi: 10.1016/j.chemosphere.2007.04.022 – volume: 189 start-page: 709 year: 2017 end-page: 716 ident: CR10 article-title: Solubility and transport of Cr(III) in a historically contaminated soil – evidence of a rapidly reacting dimeric Cr(III) organic matter complex publication-title: Chemosphere doi: 10.1016/j.chemosphere.2017.09.088 – volume: 1 start-page: 906 year: 2013 end-page: 915 ident: CR3 article-title: An efficient and regenerable quaternary amine modified chitosan beads for the removal of nitrate and phosphate anions publication-title: J Environ Chem Eng doi: 10.1016/j.jece.2013.07.031 – ident: CR19 – volume: 260 start-page: 789 year: 2013 end-page: 795 ident: CR11 article-title: Adsorption of Cr ( VI ) using synthetic poly (m-phenylenediamine) publication-title: J hazard Mater doi: 10.1016/j.jhazmat.2013.06.045 – volume: 187 start-page: 79 year: 2012 end-page: 88 ident: CR15 article-title: Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye publication-title: Chem Eng J doi: 10.1016/j.cej.2012.01.089 – volume: 12 start-page: 4341 year: 2006 end-page: 4350 ident: CR23 article-title: Rapid and effective adsorption of lead ions on fine poly(phenylenediamine) microparticles publication-title: Chem - A Eur J doi: 10.1002/chem.200501070 – volume: 44 start-page: 847 year: 2014 end-page: 907 ident: CR4 article-title: Removal and recovery of phosphate from water using sorption publication-title: Crit Rev Environ Sci Technol doi: 10.1080/10643389.2012.741311 – volume: 237 start-page: 153 year: 2014 end-page: 161 ident: CR14 article-title: A convenient method to determine kinetic parameters of adsorption processes by nonlinear regression of pseudo-nth-order equation publication-title: Chem Eng J doi: 10.1016/j.cej.2013.10.013 – volume: 222 start-page: 186 year: 2013 end-page: 197 ident: CR17 article-title: Exfoliated polypyrrole-organically modified montmorillonite clay nanocomposite as a potential adsorbent for Cr(VI) removal publication-title: Chem Eng J doi: 10.1016/j.cej.2013.02.061 – volume: 268 start-page: 270 year: 2015 end-page: 279 ident: CR24 article-title: Synthesis of mesoporous cerium-zirconium binary oxide nanoadsorbents by a solvothermal process and their effective adsorption of phosphate from water publication-title: Chem Eng J doi: 10.1016/j.cej.2015.01.070 – volume: 277 start-page: 112 year: 2015 end-page: 119 ident: CR28 article-title: Removal of phosphate anions using the modified chitosan beads: adsorption kinetic, isotherm and mechanism studies publication-title: Powder Technol doi: 10.1016/j.powtec.2015.02.055 – volume: 129–130 start-page: 46 year: 2012 end-page: 53 ident: CR16 article-title: A modified Langmuir-Freundlich isotherm model for simulating pH-dependent adsorption effects publication-title: J Contaminant Hydrol doi: 10.1016/j.jconhyd.2011.12.001 – volume: 12 start-page: 250 year: 2009 end-page: 258 ident: CR1 article-title: Physiological functions of mineral macronutrients publication-title: Curr Opin Plant Biol doi: 10.1016/j.pbi.2009.04.003 – volume: 41 start-page: 1 year: 2013 end-page: 11 ident: CR2 article-title: Sensing and analysis of soluble phosphates in environmental samples: a review publication-title: Biosens Bioelectron doi: 10.1016/j.bios.2012.07.012 – volume: 32 start-page: 1613 year: 1998 end-page: 1625 ident: CR6 article-title: Ultimate removal of phosphate from wastewater using a new class of polymeric ion exchangers publication-title: Water Res doi: 10.1016/S0043-1354(97)00371-0 – volume: 25 start-page: 1675 year: 2009 end-page: 1684 ident: CR18 article-title: Powerful reactive sorption of silver (I) and mercury (II) onto poly (o-phenylenediamine) microparticles publication-title: Langmuir doi: 10.1021/la802410p – volume: 5 start-page: 22080 year: 2015 end-page: 22090 ident: CR29 article-title: Adsorption of phosphate onto amine functionalized nano-sized magnetic polymer adsorbents: mechanism and magnetic effects publication-title: RSC Adv doi: 10.1039/C4RA14630A – volume: 2 start-page: 2070 year: 2014 end-page: 2080 ident: CR8 article-title: Polyaniline coated ethyl cellulose with improved hexavalent chromium removal publication-title: ACS Sustain Chem Eng doi: 10.1021/sc5003209 – volume: 25 start-page: 1675 year: 2009 ident: 3922_CR18 publication-title: Langmuir doi: 10.1021/la802410p – volume: 187 start-page: 79 year: 2012 ident: 3922_CR15 publication-title: Chem Eng J doi: 10.1016/j.cej.2012.01.089 – volume: 237 start-page: 153 year: 2014 ident: 3922_CR14 publication-title: Chem Eng J doi: 10.1016/j.cej.2013.10.013 – volume: 268 start-page: 270 year: 2015 ident: 3922_CR24 publication-title: Chem Eng J doi: 10.1016/j.cej.2015.01.070 – volume: 189 start-page: 709 year: 2017 ident: 3922_CR10 publication-title: Chemosphere doi: 10.1016/j.chemosphere.2017.09.088 – volume: 12 start-page: 4341 year: 2006 ident: 3922_CR23 publication-title: Chem - A Eur J doi: 10.1002/chem.200501070 – volume: 5 start-page: 22080 year: 2015 ident: 3922_CR29 publication-title: RSC Adv doi: 10.1039/C4RA14630A – volume: 32 start-page: 1613 year: 1998 ident: 3922_CR6 publication-title: Water Res doi: 10.1016/S0043-1354(97)00371-0 – volume: 129–130 start-page: 46 year: 2012 ident: 3922_CR16 publication-title: J Contaminant Hydrol doi: 10.1016/j.jconhyd.2011.12.001 – volume: 69 start-page: 289 year: 2007 ident: 3922_CR7 publication-title: Chemosphere doi: 10.1016/j.chemosphere.2007.04.022 – volume: 2014 start-page: 1 year: 2014 ident: 3922_CR21 publication-title: Int J Electrochem doi: 10.1155/2014/961617 – volume: 277 start-page: 112 year: 2015 ident: 3922_CR28 publication-title: Powder Technol doi: 10.1016/j.powtec.2015.02.055 – volume: 16 start-page: 622 year: 2018 ident: 3922_CR13 publication-title: Data Brief doi: 10.1016/j.dib.2017.11.098 – ident: 3922_CR19 doi: 10.1016/j.eurpolymj.2009.12.007 – volume: 144 start-page: 386 year: 2007 ident: 3922_CR26 publication-title: J Hazard Mater doi: 10.1016/j.jhazmat.2006.10.046 – volume: 260 start-page: 789 year: 2013 ident: 3922_CR11 publication-title: J hazard Mater doi: 10.1016/j.jhazmat.2013.06.045 – volume: 222 start-page: 186 year: 2013 ident: 3922_CR17 publication-title: Chem Eng J doi: 10.1016/j.cej.2013.02.061 – volume: 1 start-page: 906 year: 2013 ident: 3922_CR3 publication-title: J Environ Chem Eng doi: 10.1016/j.jece.2013.07.031 – volume: 41 start-page: 1 year: 2013 ident: 3922_CR2 publication-title: Biosens Bioelectron doi: 10.1016/j.bios.2012.07.012 – volume: 176–177 start-page: 740 year: 2015 ident: 3922_CR20 publication-title: Appl Catal B: Environ doi: 10.1016/j.apcatb.2015.04.047 – volume: 22 start-page: 1459 year: 2011 ident: 3922_CR22 publication-title: Polym Adv Technol doi: 10.1002/pat.2018 – volume: 316 start-page: 33 year: 2017 ident: 3922_CR5 publication-title: Chem Eng J doi: 10.1016/j.cej.2017.01.066 – volume: 119 start-page: 1353 year: 2015 ident: 3922_CR25 publication-title: Chemosphere doi: 10.1016/j.chemosphere.2014.02.024 – volume: 12 start-page: 250 year: 2009 ident: 3922_CR1 publication-title: Curr Opin Plant Biol doi: 10.1016/j.pbi.2009.04.003 – volume: 41 start-page: 1 year: 2015 ident: 3922_CR9 publication-title: Prog Polym Sci doi: 10.1016/j.progpolymsci.2014.10.007 – volume: 2 start-page: 2070 year: 2014 ident: 3922_CR8 publication-title: ACS Sustain Chem Eng doi: 10.1021/sc5003209 – volume: 20 start-page: 2840 year: 2014 ident: 3922_CR27 publication-title: J Ind Eng Chem doi: 10.1016/j.jiec.2013.11.016 – volume: 44 start-page: 847 year: 2014 ident: 3922_CR4 publication-title: Crit Rev Environ Sci Technol doi: 10.1080/10643389.2012.741311 – volume: 139 start-page: 72 year: 2017 ident: 3922_CR12 publication-title: Appl Clay Sci doi: 10.1016/j.clay.2017.01.015
SSID	ssj0017661
Score	2.3049014
Snippet	Phosphorus removal from effluents is vital to avoid eutrophication. The subject study presents the development and performance of poly(phenylenediamine)...
SourceID	proquest crossref springer
SourceType	Aggregation Database Enrichment Source Index Database Publisher
StartPage	8743
SubjectTerms	Adsorbents Adsorption Caustic soda Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Eutrophication Fourier transforms Lewis acid Ligands Mass transfer Organic Chemistry Original Paper Oxidation Oxidizing agents Phenylenediamine Phosphates Phosphorus Phosphorus removal Physical Chemistry Polymer Sciences Polymerization Polymers Potassium Potassium dichromate Sodium Soft and Granular Matter Sorbents Spectrum analysis Synthesis
SummonAdditionalLinks	– databaseName: SpringerLink Journals (ICM) dbid: U2A link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NS8MwFA86D3oRP3E6JQcPigbaNEnb4xiOIerJwcBDaZrUCVtb2onsv_clazsUFbyUQNMc3kvy-72-L4QuQ8G5F0tJfBUowkRCiQSUJRrgLo69gKXK_NB_fBKjMbuf8EmdFFY10e6NS9Le1G2ym3WKERNS4ACoU8I20RY3tjvs4jHtt74DX4hVF0LTUgXwv06V-XmNr3C05pjf3KIWbYZ7aLemibi_0us-2tDZAdoeNN3ZDtHLw9trnCliUEjhIp8tr0y01hJAxOSCzIE8XuNYVXkpTagEBm6KdTa1_n5c6nkOOwznKS6meVVMgXBik2iCP2BUHqHx8O55MCJ1owSSwAlakJBLzeC6EIpzyVRIfXj60nd06EkGBg-gvkrTxEk0dWPmykClVAkGQ1AgAP4x6mR5pk8Q1jT0FUzkYGow4wIUnoEwR8owDWPX7yK3kVeU1FXETTOLWdTWP7YyjkDGkZVxxLropv2mWNXQ-HN2r1FDVJ-nKqKhGwCzpIJ20W2jmvXr31c7_d_0M7RDTX6Djdbroc6ifNfnwDoW8sJusk_A8MxL priority: 102 providerName: Springer Nature
Title	Ligand-based poly(phenylenediamine) adsorbents for enhanced removal of phosphate from water
URI	https://link.springer.com/article/10.1007/s00289-021-03922-4 https://www.proquest.com/docview/2918057262
Volume	79
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
link	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3dS8MwED_UPeiL-InzY-TBB0WDa5am7ZNM2Rx-DBEHEx9K06RO0LZuE_G_99KlGwrupYQ2zcNdcr9fcnc5gMNAuG4jkpJ6yleUi5hRiShLNcJdFDV8nihzoH_XFZ0ev-67fXvgNrJhlaVNLAy1ymJzRn7GAsdHbsEEO88_qKkaZbyrtoTGIlTQBPu4-apctLr3D1M_gifEpCKhKa-CXMCmzRTJc4WTjZoQhTqSBEb5b2ia8c0_LtICedprsGopI2lOdLwOCzrdgOXLslLbJjzfvr5EqaIGkRTJs7fvIxO59Y2AYvJC3pFIHpNIjbKhNGETBHkq0emg8P2ToX7PcLaRLCH5IBvlAySfxCSdkC9sDbeg1249XnaoLZpAY1xNYxq4UnM0HUK5ruQqYB4-PenVddCQHDc_yABUksT1WDMn4o70VcKU4NhEZSL4b8NSmqV6B4hmgaewo4vbDm7cgaJh4KwuZZAEkeNVwSnlFcb2RnFT2OItnN6FXMg4RBmHhYxDXoWT6T_55D6Nub33SzWEdm2NwtlMqMJpqZrZ5_9H250_2h6sMJPbUETq7cPSePipD5BxjGUNFv32VQ0qzaunm1bNTjJ822PNH9LD1C8
linkProvider	ProQuest
linkToHtml	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3PT9swFH5C7MAuiLFNK7DhwyYxDYvGcZz4gBBi6woUTiAhccji2KFIkIS2E-o_xd-499yk1SaNG5fIUhxLeX7299nvF8BnraIozIzhsU0slyoX3CDKcodwl2VhIgtLF_pn56p_KU-uoqsleGpjYcitst0T_UZtq5zuyPeEDhLkFkKJg_qBU9Uosq62JTRmanHqpo94ZBvvH3_H-f0iRO_HxVGfN1UFeI7qNuE6Mk7i2lI2ioy0WsT4jE3cdTo0Ek8HCJG2KPJu7kSQycAkthBWSWzi3wpKvoRb_isZhppWVNL7ObdaxErN6h9SMRdkHk2Qjg_V8yY9Tg4RXaQkgsu_gXDBbv8xyHqc663BakNQ2eFMo97AkivXYeWorQv3Fq4HtzdZaTnhn2V1dTfdIT-xKcIXRaHcI239yjI7rkaGnDQYsmLmyqH3NGAjd1-hbrOqYPWwGtdDpLqMQlzYI7ZG7-DyRYT5HpbLqnQfgDmhY4sdIzzkSDI-qpDAs2uMLnQWxB0IWnmleZO_nMpo3KXzzMtexinKOPUyTmUHvs2_qWfZO57tvdVOQ9qs5HG60LsO7LZTs3j9_9E2nh9tG1b6F2eDdHB8froJrwVFVXgfwS1Ynox-u4_IdSbmk1cwBr9eWqP_AHU4DHs
linkToPdf	http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NS8MwFA86Qb2InzidmoMHRYNtlqbLcUzH1Dk8OBh4KE2TOmFryzaR_fe-9GsqKngpgb4G-l6a3y99XwidCu44dV9K4qqGIowHlEhAWaIB7ny_3mChMj_0H3q802d3A2fwKYs_jXYvXJJZToOp0hTNrhIVXpWJb6mDjJjwAgsAnhK2jFZgO7bNuu7TZulHcDnPOhKa9irABfK0mZ_n-ApNC775zUWaIk97E23klBE3MxtvoSUdbaO1VtGpbQc9d19f_EgRg0gKJ_FofmYit-YAKCYvZAxE8hz7ahpPpAmbwMBTsY6Gqe8fT_Q4htWG4xAnw3iaDIF8YpN0gt9hNNlF_fbNU6tD8qYJJIDXnxHhSM1g6-DKcSRTgrpwdaVraVGXDA4_wABUGAZWoKntM1s2VEgVZzAEYwL476FKFEd6H2FNhatA0IFjBzPuQF43cGZJKULh224V2YW-vCCvKG4aW4y8shZyqmMPdOylOvZYFV2UzyRZPY0_pWuFGbz825p6VNgNYJmU0yq6LEyzuP37bAf_Ez9Bq4_Xba9727s_ROvUpD2kQXw1VJlN3vQRkJGZPE7X2wfR5dN6
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Ligand-based+poly%28phenylenediamine%29+adsorbents+for+enhanced+removal+of+phosphate+from+water&rft.jtitle=Polymer+bulletin+%28Berlin%2C+Germany%29&rft.au=Mdlalose%2C+Lindani&rft.au=Balogun%2C+Mohammed&rft.au=Setshedi%2C+Katlego&rft.au=Klavins%2C+Maris&rft.date=2022-10-01&rft.issn=0170-0839&rft.eissn=1436-2449&rft.volume=79&rft.issue=10&rft.spage=8743&rft.epage=8763&rft_id=info:doi/10.1007%2Fs00289-021-03922-4&rft.externalDBID=n%2Fa&rft.externalDocID=10_1007_s00289_021_03922_4
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0170-0839&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0170-0839&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0170-0839&client=summon