Rare earth element-doped porous In2O3 nanosheets for enhanced gas-sensing performance

Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In 2 O 3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In 2 O 3 nanosheets is systematically investigated. The mixed phase composed of c-In 2 O 3 and rh...

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Published inRare metals Vol. 40; no. 6; pp. 1662 - 1668
Main Authors Zhang, Wen-Hui, Ding, Su-Jun, Zhang, Qing-Song, Yi, Hui, Liu, Zi-Xiang, Shi, Meng-Li, Guan, Rong-Feng, Yue, Lu
Format Journal Article
LanguageEnglish
Published Beijing Nonferrous Metals Society of China 01.06.2021
Springer Nature B.V
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Abstract Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In 2 O 3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In 2 O 3 nanosheets is systematically investigated. The mixed phase composed of c-In 2 O 3 and rh-In 2 O 3 can be transformed into rh-In 2 O 3 by doping with rare earth elements. After doping with rare earth elements, the morphology can be changed from compact nanosheets to porous sheets. Compared with pure In 2 O 3 and La, Pr, Sm, Ce-doped porous In 2 O 3 nanosheets, Yb-doped In 2 O 3 nanosheets present the best gas-sensing performance. Among 3%–10% Yb-doped samples, 6% Yb-doped In 2 O 3 porous nanosheets exhibit the optimal gas-sensing performance to 5 × 10 −6 –750 × 10 −6 acetone, giving a high response of 15.3 toward 50 × 10 −6 acetone and fast response/recovery time at the operating temperature of 220 °C. Moreover, 6% Yb-doped porous In 2 O 3 nanosheet sensor also exhibits excellent selectivity and stability, indicating its potential in the next-generation gas sensor. Graphic abstract
AbstractList Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In 2 O 3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In 2 O 3 nanosheets is systematically investigated. The mixed phase composed of c-In 2 O 3 and rh-In 2 O 3 can be transformed into rh-In 2 O 3 by doping with rare earth elements. After doping with rare earth elements, the morphology can be changed from compact nanosheets to porous sheets. Compared with pure In 2 O 3 and La, Pr, Sm, Ce-doped porous In 2 O 3 nanosheets, Yb-doped In 2 O 3 nanosheets present the best gas-sensing performance. Among 3%–10% Yb-doped samples, 6% Yb-doped In 2 O 3 porous nanosheets exhibit the optimal gas-sensing performance to 5 × 10 −6 –750 × 10 −6 acetone, giving a high response of 15.3 toward 50 × 10 −6 acetone and fast response/recovery time at the operating temperature of 220 °C. Moreover, 6% Yb-doped porous In 2 O 3 nanosheet sensor also exhibits excellent selectivity and stability, indicating its potential in the next-generation gas sensor. Graphic abstract
Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In2O3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In2O3 nanosheets is systematically investigated. The mixed phase composed of c-In2O3 and rh-In2O3 can be transformed into rh-In2O3 by doping with rare earth elements. After doping with rare earth elements, the morphology can be changed from compact nanosheets to porous sheets. Compared with pure In2O3 and La, Pr, Sm, Ce-doped porous In2O3 nanosheets, Yb-doped In2O3 nanosheets present the best gas-sensing performance. Among 3%–10% Yb-doped samples, 6% Yb-doped In2O3 porous nanosheets exhibit the optimal gas-sensing performance to 5 × 10−6–750 × 10−6 acetone, giving a high response of 15.3 toward 50 × 10−6 acetone and fast response/recovery time at the operating temperature of 220 °C. Moreover, 6% Yb-doped porous In2O3 nanosheet sensor also exhibits excellent selectivity and stability, indicating its potential in the next-generation gas sensor.Graphic abstract
Author Shi, Meng-Li
Ding, Su-Jun
Yue, Lu
Liu, Zi-Xiang
Zhang, Wen-Hui
Guan, Rong-Feng
Yi, Hui
Zhang, Qing-Song
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Keywords Gas sensor
Rare earth elements
In
Doping
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Acetone
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Snippet Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In 2 O 3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure,...
Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In2O3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure,...
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SubjectTerms Acetone
Biomaterials
Cerium
Chemistry and Materials Science
Doping
Energy
Gas sensors
Indium oxides
Lanthanum
Materials Engineering
Materials Science
Metallic Materials
Morphology
Nanoscale Science and Technology
Nanosheets
Operating temperature
Original Article
Physical Chemistry
Praseodymium
Rare earth elements
Recovery time
Selectivity
Trace elements
Title Rare earth element-doped porous In2O3 nanosheets for enhanced gas-sensing performance
URI https://link.springer.com/article/10.1007/s12598-020-01607-x
https://www.proquest.com/docview/2512392529
Volume 40
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