Rare earth element-doped porous In2O3 nanosheets for enhanced gas-sensing performance
Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In 2 O 3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In 2 O 3 nanosheets is systematically investigated. The mixed phase composed of c-In 2 O 3 and rh...
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Published in | Rare metals Vol. 40; no. 6; pp. 1662 - 1668 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Beijing
Nonferrous Metals Society of China
01.06.2021
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
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Abstract | Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In
2
O
3
nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In
2
O
3
nanosheets is systematically investigated. The mixed phase composed of c-In
2
O
3
and rh-In
2
O
3
can be transformed into rh-In
2
O
3
by doping with rare earth elements. After doping with rare earth elements, the morphology can be changed from compact nanosheets to porous sheets. Compared with pure In
2
O
3
and La, Pr, Sm, Ce-doped porous In
2
O
3
nanosheets, Yb-doped In
2
O
3
nanosheets present the best gas-sensing performance. Among 3%–10% Yb-doped samples, 6% Yb-doped In
2
O
3
porous nanosheets exhibit the optimal gas-sensing performance to 5 × 10
−6
–750 × 10
−6
acetone, giving a high response of 15.3 toward 50 × 10
−6
acetone and fast response/recovery time at the operating temperature of 220 °C. Moreover, 6% Yb-doped porous In
2
O
3
nanosheet sensor also exhibits excellent selectivity and stability, indicating its potential in the next-generation gas sensor.
Graphic abstract |
---|---|
AbstractList | Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In
2
O
3
nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In
2
O
3
nanosheets is systematically investigated. The mixed phase composed of c-In
2
O
3
and rh-In
2
O
3
can be transformed into rh-In
2
O
3
by doping with rare earth elements. After doping with rare earth elements, the morphology can be changed from compact nanosheets to porous sheets. Compared with pure In
2
O
3
and La, Pr, Sm, Ce-doped porous In
2
O
3
nanosheets, Yb-doped In
2
O
3
nanosheets present the best gas-sensing performance. Among 3%–10% Yb-doped samples, 6% Yb-doped In
2
O
3
porous nanosheets exhibit the optimal gas-sensing performance to 5 × 10
−6
–750 × 10
−6
acetone, giving a high response of 15.3 toward 50 × 10
−6
acetone and fast response/recovery time at the operating temperature of 220 °C. Moreover, 6% Yb-doped porous In
2
O
3
nanosheet sensor also exhibits excellent selectivity and stability, indicating its potential in the next-generation gas sensor.
Graphic abstract Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In2O3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure, morphologies and gas-sensing performance of In2O3 nanosheets is systematically investigated. The mixed phase composed of c-In2O3 and rh-In2O3 can be transformed into rh-In2O3 by doping with rare earth elements. After doping with rare earth elements, the morphology can be changed from compact nanosheets to porous sheets. Compared with pure In2O3 and La, Pr, Sm, Ce-doped porous In2O3 nanosheets, Yb-doped In2O3 nanosheets present the best gas-sensing performance. Among 3%–10% Yb-doped samples, 6% Yb-doped In2O3 porous nanosheets exhibit the optimal gas-sensing performance to 5 × 10−6–750 × 10−6 acetone, giving a high response of 15.3 toward 50 × 10−6 acetone and fast response/recovery time at the operating temperature of 220 °C. Moreover, 6% Yb-doped porous In2O3 nanosheet sensor also exhibits excellent selectivity and stability, indicating its potential in the next-generation gas sensor.Graphic abstract |
Author | Shi, Meng-Li Ding, Su-Jun Yue, Lu Liu, Zi-Xiang Zhang, Wen-Hui Guan, Rong-Feng Yi, Hui Zhang, Qing-Song |
Author_xml | – sequence: 1 givenname: Wen-Hui surname: Zhang fullname: Zhang, Wen-Hui organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 2 givenname: Su-Jun surname: Ding fullname: Ding, Su-Jun organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 3 givenname: Qing-Song surname: Zhang fullname: Zhang, Qing-Song organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 4 givenname: Hui surname: Yi fullname: Yi, Hui organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 5 givenname: Zi-Xiang surname: Liu fullname: Liu, Zi-Xiang organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 6 givenname: Meng-Li surname: Shi fullname: Shi, Meng-Li organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 7 givenname: Rong-Feng surname: Guan fullname: Guan, Rong-Feng organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology – sequence: 8 givenname: Lu orcidid: 0000-0003-1197-8023 surname: Yue fullname: Yue, Lu email: yuelu66@126.com organization: Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology |
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Snippet | Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In
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O
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nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure,... Rare earth (La, Pr, Sm, Ce and Yb)-doped porous In2O3 nanosheets are prepared by a solvothermal method. The effect of rare earth elements on the structure,... |
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SubjectTerms | Acetone Biomaterials Cerium Chemistry and Materials Science Doping Energy Gas sensors Indium oxides Lanthanum Materials Engineering Materials Science Metallic Materials Morphology Nanoscale Science and Technology Nanosheets Operating temperature Original Article Physical Chemistry Praseodymium Rare earth elements Recovery time Selectivity Trace elements |
Title | Rare earth element-doped porous In2O3 nanosheets for enhanced gas-sensing performance |
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