P2-Na2/3Mn0.66Ni0.21Mg0.05Al0.03X0.0225O2 (X = Zr, Ce) as high performance cathode materials for sodium-ion batteries
As an alternative to lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) have a great potential for large-scale energy storage. Here, new component P2-Na 2/3 Mn 0.66 Ni 0.21 Mg 0.05 Al 0.03 X 0.0225 O 2 (X = Zr, Ce) cathode materials were designed and synthesized by co-precipitation method. Th...
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| Published in | Ionics Vol. 26; no. 2; pp. 727 - 734 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Berlin/Heidelberg
Springer Berlin Heidelberg
01.02.2020
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
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| Abstract | As an alternative to lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) have a great potential for large-scale energy storage. Here, new component P2-Na
2/3
Mn
0.66
Ni
0.21
Mg
0.05
Al
0.03
X
0.0225
O
2
(X = Zr, Ce) cathode materials were designed and synthesized by co-precipitation method. The cathode materials of new component exhibit excellent electrochemical properties due to the new materials concentrate on the advantages of the individual elements. The as-prepared materials display excellent cycling stability (P2-Na
2/3
Mn
0.66
Ni
0.21
Mg
0.05
Al
0.03
Zr
0.0225
O
2
delivers a reversible capacity of 89.3 mAh g
−1
and P2-Na
2/3
Mn
0.66
Ni
0.21
Mg
0.05
Al
0.03
Ce
0.0225
O
2
shows the capacity of 90.2 mAh g
−1
over 300 cycles at a 1 C rate). The new component materials also indicate extremely high rate capability (~ 60 mAh g
−1
after 1000 cycles at a 10 C rate). |
|---|---|
| AbstractList | As an alternative to lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) have a great potential for large-scale energy storage. Here, new component P2-Na2/3Mn0.66Ni0.21Mg0.05Al0.03X0.0225O2 (X = Zr, Ce) cathode materials were designed and synthesized by co-precipitation method. The cathode materials of new component exhibit excellent electrochemical properties due to the new materials concentrate on the advantages of the individual elements. The as-prepared materials display excellent cycling stability (P2-Na2/3Mn0.66Ni0.21Mg0.05Al0.03Zr0.0225O2 delivers a reversible capacity of 89.3 mAh g−1 and P2-Na2/3Mn0.66Ni0.21Mg0.05Al0.03Ce0.0225O2 shows the capacity of 90.2 mAh g−1 over 300 cycles at a 1 C rate). The new component materials also indicate extremely high rate capability (~ 60 mAh g−1 after 1000 cycles at a 10 C rate). As an alternative to lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) have a great potential for large-scale energy storage. Here, new component P2-Na 2/3 Mn 0.66 Ni 0.21 Mg 0.05 Al 0.03 X 0.0225 O 2 (X = Zr, Ce) cathode materials were designed and synthesized by co-precipitation method. The cathode materials of new component exhibit excellent electrochemical properties due to the new materials concentrate on the advantages of the individual elements. The as-prepared materials display excellent cycling stability (P2-Na 2/3 Mn 0.66 Ni 0.21 Mg 0.05 Al 0.03 Zr 0.0225 O 2 delivers a reversible capacity of 89.3 mAh g −1 and P2-Na 2/3 Mn 0.66 Ni 0.21 Mg 0.05 Al 0.03 Ce 0.0225 O 2 shows the capacity of 90.2 mAh g −1 over 300 cycles at a 1 C rate). The new component materials also indicate extremely high rate capability (~ 60 mAh g −1 after 1000 cycles at a 10 C rate). |
| Author | Zheng, Jianan Fu, Fang Ke, Chunyu Yang, Weihua |
| Author_xml | – sequence: 1 givenname: Chunyu surname: Ke fullname: Ke, Chunyu organization: College of Materials Science and Engineering, Huaqiao University – sequence: 2 givenname: Fang surname: Fu fullname: Fu, Fang organization: College of Materials Science and Engineering, Huaqiao University – sequence: 3 givenname: Jianan surname: Zheng fullname: Zheng, Jianan organization: College of Materials Science and Engineering, Huaqiao University – sequence: 4 givenname: Weihua surname: Yang fullname: Yang, Weihua email: hzhyangwh@163.com organization: College of Materials Science and Engineering, Huaqiao University |
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| Keywords | Cathode material Multiple elements P2-type layered oxide Sodium-ion batteries |
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| Snippet | As an alternative to lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) have a great potential for large-scale energy storage. Here, new component P2-Na... As an alternative to lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) have a great potential for large-scale energy storage. Here, new component... |
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| SubjectTerms | Cathodes Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemical analysis Electrochemistry Electrode materials Energy Storage Lithium Lithium-ion batteries Optical and Electronic Materials Original Paper Rechargeable batteries Renewable and Green Energy Sodium-ion batteries Storage batteries Zirconium |
| Title | P2-Na2/3Mn0.66Ni0.21Mg0.05Al0.03X0.0225O2 (X = Zr, Ce) as high performance cathode materials for sodium-ion batteries |
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