Modeling of Carbon Redistribution and Tetragonality Evolution in Supersaturated Ferrite
Martensite and bainite are formed from austenite through the rapid application of Bain’s strain. In several studies, martensite is considered as a body-centered tetragonal phase, but it can also be viewed as bcc ferrite supersaturated with carbon, subject to internal residual stresses from incomplet...
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| Published in | Metallurgical and materials transactions. A, Physical metallurgy and materials science Vol. 55; no. 12; pp. 4940 - 4953 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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New York
Springer US
01.12.2024
Springer Nature B.V |
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| Abstract | Martensite and bainite are formed from austenite through the rapid application of Bain’s strain. In several studies, martensite is considered as a body-centered tetragonal phase, but it can also be viewed as bcc ferrite supersaturated with carbon, subject to internal residual stresses from incomplete relaxation of Bain’s strain. Recent electron backscatter diffraction measurements have revealed a broad spectrum of tetragonality in quenched martensite, which can be attributed to the diversity of internal stress rather than variations in carbon distribution. Therefore, a thermodynamic unit cell model is developed to calculate the kinetics of carbon atom occupancy in particular kinds of octahedral interstitial lattice sites, contributing to tetragonality in loaded ferrite. The model includes a Zener-ordering term that influences carbon atom distribution and consequently affects tetragonality. Simulations suggest that carbon redistribution among octahedral interstitial lattice sites reaches equilibrium with internal stress within an hour at room temperature. The presented model provides a framework for understanding tetragonality in martensite and bainite, incorporating the effects of internal stress and carbon atom distribution in particular kinds of octahedral interstitial lattice sites. |
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| AbstractList | Martensite and bainite are formed from austenite through the rapid application of Bain’s strain. In several studies, martensite is considered as a body-centered tetragonal phase, but it can also be viewed as bcc ferrite supersaturated with carbon, subject to internal residual stresses from incomplete relaxation of Bain’s strain. Recent electron backscatter diffraction measurements have revealed a broad spectrum of tetragonality in quenched martensite, which can be attributed to the diversity of internal stress rather than variations in carbon distribution. Therefore, a thermodynamic unit cell model is developed to calculate the kinetics of carbon atom occupancy in particular kinds of octahedral interstitial lattice sites, contributing to tetragonality in loaded ferrite. The model includes a Zener-ordering term that influences carbon atom distribution and consequently affects tetragonality. Simulations suggest that carbon redistribution among octahedral interstitial lattice sites reaches equilibrium with internal stress within an hour at room temperature. The presented model provides a framework for understanding tetragonality in martensite and bainite, incorporating the effects of internal stress and carbon atom distribution in particular kinds of octahedral interstitial lattice sites. |
| Author | Brandl, D. Ressel, G. Svoboda, J. |
| Author_xml | – sequence: 1 givenname: J. surname: Svoboda fullname: Svoboda, J. organization: Institute of Physics of Materials, Academy of Science of the Czech Republic – sequence: 2 givenname: G. surname: Ressel fullname: Ressel, G. organization: Materials Center, Leoben Forschung GmbH – sequence: 3 givenname: D. surname: Brandl fullname: Brandl, D. email: dominik.brandl@mcl.at organization: Materials Center, Leoben Forschung GmbH |
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| Snippet | Martensite and bainite are formed from austenite through the rapid application of Bain’s strain. In several studies, martensite is considered as a... |
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| SubjectTerms | Bainite Carbon Characterization and Evaluation of Materials Chemistry and Materials Science Electron back scatter Ferrite Lattice sites Martensite Materials Science Metallic Materials Nanotechnology Original Research Article Residual stress Room temperature Strain Stress relaxation Structural Materials Surfaces and Interfaces Tetragonal lattice Thin Films Unit cell |
| Title | Modeling of Carbon Redistribution and Tetragonality Evolution in Supersaturated Ferrite |
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