Enhanced light utilization in semitransparent organic solar cells based on a nonfullerene acceptor of IEICO-4F

• Published in: Applied physics. A, Materials science & processing Vol. 127; no. 11
• Main Authors: Zang, Yue, Chen, Lingfeng, Zhou, Jintao, Xu, Rui, Liu, Zugang
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.11.2021; Springer Nature B.V
• Subjects: Applied physics; Bragg reflectors; Characterization and Evaluation of Materials; Composition effects; Condensed Matter Physics; Electromagnetic absorption; Energy gap; Machines; Manufacturing; Materials science; Matrix methods; Nanotechnology; Optical and Electronic Materials; Optical properties; Optimization; Photoelectric effect; Photovoltaic cells; Physics; Physics and Astronomy; Polymer blends; Processes; Solar cells; Surfaces and Interfaces; Thin Films; Transfer matrices; Transmittance; Semitransparent organic solar cell; Nonfullerene acceptor; Distributed Bragg reflectors; Active layer composition
• DOI: 10.1007/s00339-021-05025-3
• ISSN: 0947-8396

Although high efficiencies have been demonstrated in organic solar cells (OSCs), the development of semitransparent devices is still lagging behind due to the difficulty in making a balance between the active layer absorption and device transmittance. To address this challenge, a detailed study of semitransparent OSCs (ST-OSCs) based on the blends of the low bandgap polymer PTB7-Th and ultra-narrow bandgap nonfullerene acceptor IEICO-4F is carried out. Comprehensive optical modeling using the transfer matrix method (TMM) has been performed to assist the design of ST-OSCs and understand the effect of active layer composition and distributed Bragg reflectors (DBRs) on the device performance. By varying the PTB7-Th/IEICO-4F blending ratio from 1:1.5 to 1:3 and incorporating of DBRs, the average visible transmittance (AVT) of the ST-OSCs was dramatically increased by over 26% with a slight decrease in photocurrent ( J max ) less than 5%. This significant improved light utilization can be attributed to the enhanced photon harvesting of NIR range and decreased visible light absorption by increasing the IEICO-4F content, as well as the optimal optical properties in the ST-OSCs with the use of DBRs. Our results can provide a feasible way to optimize the light harvesting and transmittance of the device for achieving high-performance ST-OSCs.