Extraction of Zinc and Arsenic from Metallurgical Furnace Dust
Millions of tons of dust produced in the process of gas cleaning are accumulated in dumps located near metallurgical plants. Such dust contains harmful impurities (Zn, As, Pb, and P), thus its recycling by the agglomeration method can lead to either environmental contamination or furnace damage. Hen...
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| Published in | JOM (1989) Vol. 73; no. 11; pp. 3588 - 3596 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.11.2021
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Millions of tons of dust produced in the process of gas cleaning are accumulated in dumps located near metallurgical plants. Such dust contains harmful impurities (Zn, As, Pb, and P), thus its recycling by the agglomeration method can lead to either environmental contamination or furnace damage. Hence, prior separation of iron from the impurities is required to improve the efficiency of the recycling process. Here we propose a new hydrometallurgical scheme for extracting iron in the form Na
3
FeF
6
from the liquid phase produced as the result of dust acidic leaching. The ability of Na
3
FeF
6
to interact with NaOH (KOH) with the formation of Fe(OH)
3
has been utilized for separating Fe
3+
ions from F
–
. The proposed scheme is relatively simple, quick, and inexpensive, thus allowing its use at metallurgical plants to separate Fe from Zn, As, Pb, and P. |
|---|---|
| AbstractList | Millions of tons of dust produced in the process of gas cleaning are accumulated in dumps located near metallurgical plants. Such dust contains harmful impurities (Zn, As, Pb, and P), thus its recycling by the agglomeration method can lead to either environmental contamination or furnace damage. Hence, prior separation of iron from the impurities is required to improve the efficiency of the recycling process. Here we propose a new hydrometallurgical scheme for extracting iron in the form Na3FeF6 from the liquid phase produced as the result of dust acidic leaching. The ability of Na3FeF6 to interact with NaOH (KOH) with the formation of Fe(OH)3 has been utilized for separating Fe3+ ions from F-. The proposed scheme is relatively simple, quick, and inexpensive, thus allowing its use at metallurgical plants to separate Fe from Zn, As, Pb, and P. Millions of tons of dust produced in the process of gas cleaning are accumulated in dumps located near metallurgical plants. Such dust contains harmful impurities (Zn, As, Pb, and P), thus its recycling by the agglomeration method can lead to either environmental contamination or furnace damage. Hence, prior separation of iron from the impurities is required to improve the efficiency of the recycling process. Here we propose a new hydrometallurgical scheme for extracting iron in the form Na 3 FeF 6 from the liquid phase produced as the result of dust acidic leaching. The ability of Na 3 FeF 6 to interact with NaOH (KOH) with the formation of Fe(OH) 3 has been utilized for separating Fe 3+ ions from F – . The proposed scheme is relatively simple, quick, and inexpensive, thus allowing its use at metallurgical plants to separate Fe from Zn, As, Pb, and P. |
| Author | Maiorova, A. V. Shubin, A. B. Kulikova, T. V. |
| Author_xml | – sequence: 1 givenname: A. V. orcidid: 0000-0002-1143-9209 surname: Maiorova fullname: Maiorova, A. V. organization: Institute of Metallurgy of Ural Branch of Russian Academy of Science – sequence: 2 givenname: T. V. orcidid: 0000-0002-0674-1139 surname: Kulikova fullname: Kulikova, T. V. email: kuliko@gmail.com organization: Institute of Metallurgy of Ural Branch of Russian Academy of Science – sequence: 3 givenname: A. B. surname: Shubin fullname: Shubin, A. B. organization: Institute of Metallurgy of Ural Branch of Russian Academy of Science |
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| SubjectTerms | Arsenic Chemistry/Food Science Dust Earth Sciences Efficiency Engineering Environment Extractive metallurgy Ferric hydroxide Fluorides Hydrochloric acid Hydrometallurgy Impurities Iron Leaching Liquid phases Methods Physics Plasma Recycling Technical Article Zinc |
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| Title | Extraction of Zinc and Arsenic from Metallurgical Furnace Dust |
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