Reducing Wrinkle Formation in Wool with 2-Iminothiorane Hydrochloride
To study wrinkle formation in wool, we investigate the relationship between wrinkle recovery and moisture regain in wool fabrics and the influence of incorporating bulky molecules (ninhydrin) on wrinkle recovery. We prepare wool fabrics by introducing additional disulfide (-SS-) groups using 2-imino...
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| Published in | Textile research journal Vol. 72; no. 4; pp. 285 - 289 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Thousand Oaks, CA
SAGE Publications
01.04.2002
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| Subjects | |
| Online Access | Get full text |
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| Abstract | To study wrinkle formation in wool, we investigate the relationship between wrinkle recovery and moisture regain in wool fabrics and the influence of incorporating bulky molecules (ninhydrin) on wrinkle recovery. We prepare wool fabrics by introducing additional disulfide (-SS-) groups using 2-iminothiolane hydrochloride (2-IT), and inves tigate the influence of the disulfide (-SS-) content on wrinkle recovery. FT-Raman spectroscopy reveals that wrinkle recovery improves with increasing -SS- content in wool fabrics. From these experiments, we demonstrate that wrinkle formation in wool occurs with the disconnection and reconnection (rearrangement) of hydrogen bonds, and -SS groups exert a repelling force on hydrogen bonds at the time of wrinkle formation. |
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| AbstractList | To study wrinkle formation in wool, we investigate the relationship between wrinkle recovery and moisture regain in wool fabrics and the influence of incorporating bulky molecules (ninhydrin) on wrinkle recovery. We prepare wool fabrics by introducing additional disulfide (-SS-) groups using 2-iminothiolane hydrochloride (2-IT), and inves tigate the influence of the disulfide (-SS-) content on wrinkle recovery. FT-Raman spectroscopy reveals that wrinkle recovery improves with increasing -SS- content in wool fabrics. From these experiments, we demonstrate that wrinkle formation in wool occurs with the disconnection and reconnection (rearrangement) of hydrogen bonds, and -SS groups exert a repelling force on hydrogen bonds at the time of wrinkle formation. |
| Author | Hori, T. Kuzuhara, A. |
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| Cites_doi | 10.1177/004051756603601004 10.1111/j.1478-4408.1994.tb01640.x 10.2115/fiber.50.10_P559 10.1177/004051759806801007 10.1246/bcsj.46.3407 10.4188/transjtmsj.51.12_T252 10.1016/0584-8539(94)80205-X 10.1177/004051757504501003 10.1016/0026-265X(86)90127-X 10.1002/pol.1976.170141018 10.1002/bip.1976.360150807 |
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| References_xml | – volume: 50 start-page: 559 issue: 10 year: 1994 article-title: Wool Shape Memory of a Woven Product publication-title: Sen'i Gakkaishi contributor: fullname: Hori, M. – volume: 34 start-page: 319 issue: 3 year: 1986 article-title: Identification of Fibers by Infrared and Raman Microspectroscopy publication-title: Microchem. J. contributor: fullname: Schiering. D.W. – start-page: 999 issue: 18 year: 1971 article-title: Influence of Temperature and Moisture Regain Changes on Wrinkling Properties publication-title: Appl. Polym. Symp. contributor: fullname: Kahlson. C. – volume: 14 start-page: 2535 year: 1976 article-title: Investigation of Structural Changes in Wool Fibers Due to Annealing publication-title: J. Polym. Sci. Polym. Chem. Ed. contributor: fullname: Lundell, M. – volume: 45 start-page: 712 year: 1975 article-title: The Wrinkling Behavior of Wool Fabrics—Conditions of Testing publication-title: Textile Res. J. contributor: fullname: Taylor, D.S. – volume: 36 start-page: 874 year: 1966 article-title: Wnnkling Behavior of Wool Fabrics Part I: A Multiple Pleat Test publication-title: Textile Res. J. contributor: fullname: Katz. H.J. – volume: 46 start-page: 3407 year: 1973 article-title: Vibrational Spectra and Molecular Conformations of Dialkyl Disulfides publication-title: Bull Chem. Soc. Jpn. contributor: fullname: Miyazawa, T. – volume: 68 start-page: 739 issue: 10 year: 1998 article-title: Investigating the Photo-Oxidation of Wool Using FT-Raman and FT-IR Spectroscopies publication-title: Textile Res. J. contributor: fullname: Cooke, W.D. – volume: 15 start-page: 1513 year: 1976 article-title: Vibrational Spectrum of the Unordered Polypeptide Chain: A Raman Study of Feather Keratin publication-title: Biopolymers contributor: fullname: Krimm, S. – volume: 50A start-page: 1927 issue: 11 year: 1994 article-title: FT-Raman Studies of Wool, I: Preliminary Studies publication-title: Spectrochem. Acta contributor: fullname: Denning, R.J. – volume: 358 start-page: 137 year: 1977 article-title: The Use of 2-Iminothiolane as a Protein Crosslinking Reagent publication-title: Hoppe-Seyler's Z Physiol. Chem. contributor: fullname: Dülffer, T. – volume: 110 start-page: 196 year: 1994 article-title: FT-Raman Spectroscopic Studies of Wool publication-title: J. Soc. Dyers. Colour. contributor: fullname: Peters, A.T. – volume: 3 start-page: 193 year: 1971 article-title: Wrinkling Behavior of Wool Fabrics: Changes Induced by Chemical Modification publication-title: Textile Chem. Color. contributor: fullname: Leeder. J.D. – volume: 88 start-page: 133 issue: 7 year: 1978 article-title: Wrinkling in Wool Fabrics publication-title: Ind. Textile J. contributor: fullname: Gupta, N.P. – volume: 51 start-page: T252 year: 1998 article-title: A New Testing Method for Wrinkle Recovery of Wool Fabrics publication-title: Sen'i Kikai Gakkaishi contributor: fullname: Kaimori, M. – volume: 16 start-page: 25 issue: 13 year: 1983 article-title: Fundamental Principles of Textile Processing publication-title: Textile Dyer Print. contributor: fullname: Shenay, V.A. – start-page: 999 issue: 18 year: 1971 ident: atypb8 publication-title: Appl. Polym. Symp. contributor: fullname: Kärrholm, E.M. – ident: atypb9 doi: 10.1177/004051756603601004 – volume: 3 start-page: 193 year: 1971 ident: atypb13 publication-title: Textile Chem. Color. contributor: fullname: Leeder. J.D. – volume-title: personal communication ident: atypb10 contributor: fullname: Kugo. K. – ident: atypb4 doi: 10.1111/j.1478-4408.1994.tb01640.x – ident: atypb5 doi: 10.2115/fiber.50.10_P559 – volume: 88 start-page: 133 issue: 7 year: 1978 ident: atypb18 publication-title: Ind. Textile J. contributor: fullname: Vernia, G.K. – ident: atypb7 doi: 10.1177/004051759806801007 – volume: 16 start-page: 25 issue: 13 year: 1983 ident: atypb15 publication-title: Textile Dyer Print. contributor: fullname: Shenay, V.A. – ident: atypb17 doi: 10.1246/bcsj.46.3407 – ident: atypb2 – ident: atypb11 doi: 10.4188/transjtmsj.51.12_T252 – ident: atypb1 doi: 10.1016/0584-8539(94)80205-X – ident: atypb3 doi: 10.1177/004051757504501003 – ident: atypb12 doi: 10.1016/0026-265X(86)90127-X – volume: 358 start-page: 137 year: 1977 ident: atypb14 publication-title: Hoppe-Seyler's Z Physiol. Chem. contributor: fullname: Schramm, H.J. – ident: atypb16 doi: 10.1002/pol.1976.170141018 – ident: atypb6 doi: 10.1002/bip.1976.360150807 |
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| SubjectTerms | Disulfides Fabrics Hydrochlorides Hydrogen bonds Ninhydrin Recovery Textiles Wool |
| Title | Reducing Wrinkle Formation in Wool with 2-Iminothiorane Hydrochloride |
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