Rationale and fallacy of thermoanalytical kinetic patterns How we model subject matter

• Published in: Journal of thermal analysis and calorimetry Vol. 110; no. 1; pp. 5 - 16
• Main Author: SESTAK, J
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Dordrecht Springer Netherlands 01.10.2012; Springer
• Subjects: Analytical Chemistry; Chemistry; Chemistry and Materials Science; Exact sciences and technology; General and physical chemistry; Inorganic Chemistry; Measurement Science and Instrumentation; Physical Chemistry; Polymer Sciences; Theory of reactions, general kinetics; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; DTA; Evaluation; Geometrical modeling; Misinterpretation; Nonisothermal kinetics; Reaction mechanism; Fractals; Heat inertia; Differential thermal analysis; Review; Modeling; Fractal; Solid state reaction; Non isothermal condition; Models; Thermal analysis; Kinetics

Modeling tradition is reviewed within its historical maturity from Plato do Penrose. Metaphors in nonisothermal kinetics achieved a wide application mostly employing models derived by means of undemanding isothermal descriptions. Geometrical basis of such modeling is revised and discussed in terms o...