Topology, magnetism and dye adsorption properties of metal organic frameworks (MOFs) synthesized from bench chemicals

• Published in: CrystEngComm Vol. 21; no. 35; pp. 5299 - 539
• Main Authors: Iman, Khushboo, Shahid, M, Khan, M. Shahnawaz, Ahmad, Musheer, Sama, Farasha
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 2019
• Subjects: Adsorbents; Adsorption; Antiferromagnetism; Bonding strength; Cations; Crystallography; Dyes; Hydrogen bonding; Ligands; Magnetic properties; Magnetism; Metal-organic frameworks; Methylene blue; Nitrates; Organic chemistry; Pi-electrons; Pollutants; Query languages; Synthesis; Topology; Water chemistry

Herein, two metal organic frameworks (MOFs), namely, [{Cu 2 (μ-OH)(μ-OAc)(H 2 O)(OAc)(bpy) 2 }NO 3 ·4H 2 O] n (CuMOF-1) and [{Co(bpy)(ClO 4 ) 2 (H 2 O) 2 }·bpy] n (CoMOF-2), where bpy = 4,4′-bipyridine, were synthesized, characterized and explored for their material importance in magnetism and dye a...