Layered atomic structures of double oxides for low shear strength at high temperatures

Double oxide phases combining a transition metal and a noble metal have recently become a subject of investigation as solid lubricant materials for high-temperature tribological applications. Here, we study the changes in chemistry and crystal structure of silver molybdate (Ag 2Mo 2O 7) and silver t...

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Published inScripta materialia Vol. 62; no. 10; pp. 735 - 738
Main Authors Stone, D., Liu, J., Singh, D.P., Muratore, C., Voevodin, A.A., Mishra, S., Rebholz, C., Ge, Q., Aouadi, S.M.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.05.2010
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Online AccessGet full text
ISSN1359-6462
1872-8456
DOI10.1016/j.scriptamat.2010.02.004

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Abstract Double oxide phases combining a transition metal and a noble metal have recently become a subject of investigation as solid lubricant materials for high-temperature tribological applications. Here, we study the changes in chemistry and crystal structure of silver molybdate (Ag 2Mo 2O 7) and silver tungstate (Ag 2WO 4) thin films and powders from 25 to 600 °C. We show, using ab initio molecular dynamics, high-temperature X-ray diffraction, high-temperature Raman spectroscopy and differential scanning calorimetry in combination with sliding tests, that the layered atomic structure of silver molybdate facilitates sliding, resulting in a low coefficient of friction (<0.2) from 300 to 500 °C.
AbstractList Double oxide phases combining a transition metal and a noble metal have recently become a subject of investigation as solid lubricant materials for high-temperature tribological applications. Here, we study the changes in chemistry and crystal structure of silver molybdate (Ag 2Mo 2O 7) and silver tungstate (Ag 2WO 4) thin films and powders from 25 to 600 °C. We show, using ab initio molecular dynamics, high-temperature X-ray diffraction, high-temperature Raman spectroscopy and differential scanning calorimetry in combination with sliding tests, that the layered atomic structure of silver molybdate facilitates sliding, resulting in a low coefficient of friction (<0.2) from 300 to 500 °C.
Author Singh, D.P.
Rebholz, C.
Mishra, S.
Ge, Q.
Voevodin, A.A.
Stone, D.
Aouadi, S.M.
Liu, J.
Muratore, C.
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  organization: Department of Chemistry, Southern Illinois University, Carbondale, IL 62901, USA
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  organization: Department of Physics, Southern Illinois University, Carbondale, IL 62901, USA
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  organization: Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright-Patterson Air Force Base, OH 45433, USA
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  surname: Aouadi
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  email: saouadi@physics.siu.edu
  organization: Department of Physics, Southern Illinois University, Carbondale, IL 62901, USA
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Ab initio calculations
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Snippet Double oxide phases combining a transition metal and a noble metal have recently become a subject of investigation as solid lubricant materials for...
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SubjectTerms Ab initio calculations
Crystal structure
Friction
Oxides
Raman spectroscopy
Title Layered atomic structures of double oxides for low shear strength at high temperatures
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