Synthesis of a Eu complex based on benzonitrile hydrolysis as the first luminescent probe for clinafloxacin
Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu 2 (pip) 2 (PhCOO) 6 ] via a hydrothermal reaction, where pip denotes 2-phenylimidazo[4,5- f ][1,10]phenanthroline. This complex is very insoluble and stable in water from pH 3 to 10...
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| Published in | CrystEngComm Vol. 23; no. 19; pp. 362 - 368 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
21.05.2021
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| Abstract | Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu
2
(pip)
2
(PhCOO)
6
]
via
a hydrothermal reaction, where pip denotes 2-phenylimidazo[4,5-
f
][1,10]phenanthroline. This complex is very insoluble and stable in water from pH 3 to 10. It exhibits strong characteristic Eu(
iii
) red photoluminescence, which could be significantly quenched by clinafloxacin without remarkable disturbance by other common salts or fluoroquinolone antibiotics. The luminescence quenching might be the result of photoinduced electron transfer from excited pip or benzoate to clinafloxacin. This complex is the first convenient luminescent sensor for clinafloxacin and the limit of detection is determined to be 0.21 μM.
[Eu
2
(pip)
2
(PhCOO)
6
] synthesized
via
hydrolysis of benzonitrile shows specific and quantitative photoluminescence quenching by clinafloxacin. |
|---|---|
| AbstractList | Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu
2
(pip)
2
(PhCOO)
6
]
via
a hydrothermal reaction, where pip denotes 2-phenylimidazo[4,5-
f
][1,10]phenanthroline. This complex is very insoluble and stable in water from pH 3 to 10. It exhibits strong characteristic Eu(
iii
) red photoluminescence, which could be significantly quenched by clinafloxacin without remarkable disturbance by other common salts or fluoroquinolone antibiotics. The luminescence quenching might be the result of photoinduced electron transfer from excited pip or benzoate to clinafloxacin. This complex is the first convenient luminescent sensor for clinafloxacin and the limit of detection is determined to be 0.21 μM. Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu2(pip)2(PhCOO)6] via a hydrothermal reaction, where pip denotes 2-phenylimidazo[4,5-f][1,10]phenanthroline. This complex is very insoluble and stable in water from pH 3 to 10. It exhibits strong characteristic Eu(iii) red photoluminescence, which could be significantly quenched by clinafloxacin without remarkable disturbance by other common salts or fluoroquinolone antibiotics. The luminescence quenching might be the result of photoinduced electron transfer from excited pip or benzoate to clinafloxacin. This complex is the first convenient luminescent sensor for clinafloxacin and the limit of detection is determined to be 0.21 μM. Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu 2 (pip) 2 (PhCOO) 6 ] via a hydrothermal reaction, where pip denotes 2-phenylimidazo[4,5- f ][1,10]phenanthroline. This complex is very insoluble and stable in water from pH 3 to 10. It exhibits strong characteristic Eu( iii ) red photoluminescence, which could be significantly quenched by clinafloxacin without remarkable disturbance by other common salts or fluoroquinolone antibiotics. The luminescence quenching might be the result of photoinduced electron transfer from excited pip or benzoate to clinafloxacin. This complex is the first convenient luminescent sensor for clinafloxacin and the limit of detection is determined to be 0.21 μM. [Eu 2 (pip) 2 (PhCOO) 6 ] synthesized via hydrolysis of benzonitrile shows specific and quantitative photoluminescence quenching by clinafloxacin. |
| Author | Wu, Jian-Zhong Cai, Yue-Peng Lu, Yong-Fang Ruan, Zhong-Yu Lv, Xi Ou, Yong-Cong |
| AuthorAffiliation | Guangdong Provincial Engineering Technology Research Center for Materials for Energy Conversion and Storage South China Normal University School of Chemistry Guangzhou Key Laboratory of Materials for Energy Conversion and Storage |
| AuthorAffiliation_xml | – name: Guangzhou Key Laboratory of Materials for Energy Conversion and Storage – name: South China Normal University – name: Guangdong Provincial Engineering Technology Research Center for Materials for Energy Conversion and Storage – name: School of Chemistry |
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| CitedBy_id | crossref_primary_10_1515_ncrs_2021_0283 crossref_primary_10_1016_j_inoche_2022_109544 crossref_primary_10_1016_j_inoche_2023_111275 |
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| Snippet | Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu
2
(pip)
2
(PhCOO)
6
]
via
a hydrothermal... Hydrolysis of benzonitrile to benzoate was realized for constructing a zero-dimensional dinuclear europium complex [Eu2(pip)2(PhCOO)6] via a hydrothermal... |
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| StartPage | 362 |
| SubjectTerms | Antibiotics Benzoates Benzonitrile Crystallography Electron transfer Europium Hydrolysis Hydrothermal reactions Luminescence quenching Photoluminescence |
| Title | Synthesis of a Eu complex based on benzonitrile hydrolysis as the first luminescent probe for clinafloxacin |
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