New N-heterocyclic carbene mercury(II) complexes: Close mercury–arene interaction
Mononuclear mercury complexes ( 1, 2, and 3) bearing bis- N-heterocyclic carbene (NHC) ligands of the form [(NHC) 2-μ-Hg] +2 have been prepared and structurally characterised. The complexes were derived from three bis-imidazolium salts as precursors to NHC; either 1,3-bis( N-methylimidazolium-1-ylme...
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| Published in | Journal of organometallic chemistry Vol. 696; no. 22; pp. 3507 - 3512 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.11.2011
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| Abstract | Mononuclear mercury complexes (
1,
2, and
3) bearing bis-
N-heterocyclic carbene (NHC) ligands of the form [(NHC)
2-μ-Hg]
+2 have been prepared and structurally characterised. The complexes were derived from three bis-imidazolium salts as precursors to NHC; either 1,3-bis(
N-methylimidazolium-1-ylmethyl)benzene bis(hexafluorophosphate) (
I·2PF
6), 1,3-bis(
N-butylimidazolium-1-ylmethyl)benzene bis(hexafluorophosphate) (
II·2PF
6) or 3,5-bis(
N-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) (
III·2PF
6) treated with mercury(II) acetate. Interestingly X-ray crystal structure analysis revealed a close interaction between the Hg metal centre with one carbon atom of the aryl linker in addition to coordination with two NHCs.
A new mercury(II)–N-heterocyclic carbene (NHC) complexes of 1,3-bis(3-methyl-imidazolium-1-ylmethyl)benzenemercury(II) bis(hexafluorophosphate) (
1), 1,3-bis(3-butyl-imidazolium-1-ylmethyl)benzenemercury(II) bis(hexafluorophosphate) (
2) and 3,5-bis(3-butylimidazolium-1-ylmethyl)toluenemercury-(II) bis(hexafluorophosphate) (
3) were synthesized and characterized. The structural studies revealed a close interaction between the Hg metal centre with one carbon atom of the aryl linker in addition to coordination with two NHCs.
[Display omitted]
► Three new mercury(II)-
N-heterocyclic carbene complexes were synthesized. ► The synthesized complexes were characterized by
1H,
13C NMR, CHN analysis and X-ray crystallography. ► X-ray studies revealed a close interaction between the mercury and one carbon atom from the aryl linker. |
|---|---|
| AbstractList | Mononuclear mercury complexes (
1,
2, and
3) bearing bis-
N-heterocyclic carbene (NHC) ligands of the form [(NHC)
2-μ-Hg]
+2 have been prepared and structurally characterised. The complexes were derived from three bis-imidazolium salts as precursors to NHC; either 1,3-bis(
N-methylimidazolium-1-ylmethyl)benzene bis(hexafluorophosphate) (
I·2PF
6), 1,3-bis(
N-butylimidazolium-1-ylmethyl)benzene bis(hexafluorophosphate) (
II·2PF
6) or 3,5-bis(
N-butylimidazolium-1-ylmethyl)toluene bis(hexafluorophosphate) (
III·2PF
6) treated with mercury(II) acetate. Interestingly X-ray crystal structure analysis revealed a close interaction between the Hg metal centre with one carbon atom of the aryl linker in addition to coordination with two NHCs.
A new mercury(II)–N-heterocyclic carbene (NHC) complexes of 1,3-bis(3-methyl-imidazolium-1-ylmethyl)benzenemercury(II) bis(hexafluorophosphate) (
1), 1,3-bis(3-butyl-imidazolium-1-ylmethyl)benzenemercury(II) bis(hexafluorophosphate) (
2) and 3,5-bis(3-butylimidazolium-1-ylmethyl)toluenemercury-(II) bis(hexafluorophosphate) (
3) were synthesized and characterized. The structural studies revealed a close interaction between the Hg metal centre with one carbon atom of the aryl linker in addition to coordination with two NHCs.
[Display omitted]
► Three new mercury(II)-
N-heterocyclic carbene complexes were synthesized. ► The synthesized complexes were characterized by
1H,
13C NMR, CHN analysis and X-ray crystallography. ► X-ray studies revealed a close interaction between the mercury and one carbon atom from the aryl linker. |
| Author | Abdallah, Hassan Hadi Salman, Abbas Washeel Haque, Rosenani A. Guan, Teoh Siang |
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| Keywords | Imidazolium salts X-ray Nitrogen heterocycles Transmetallation Mercury- N-heterocyclic carbenes |
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| Snippet | Mononuclear mercury complexes (
1,
2, and
3) bearing bis-
N-heterocyclic carbene (NHC) ligands of the form [(NHC)
2-μ-Hg]
+2 have been prepared and... |
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| SubjectTerms | Imidazolium salts Mercury- N-heterocyclic carbenes Nitrogen heterocycles Transmetallation X-ray |
| Title | New N-heterocyclic carbene mercury(II) complexes: Close mercury–arene interaction |
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