Ultrafine-grained Ni-rich layered cathode for advanced Li-ion batteries
The development of high energy-density Ni-rich (Ni ≥ 90%) layered cathodes has remained difficult because of the rapid capacity fading that occurs during cycling. This study demonstrates that limiting the primary particle size of the cathode resolves the capacity fading problem as nano-sized primary...
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Published in | Energy & environmental science Vol. 14; no. 12; pp. 6616 - 6626 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
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Cambridge
Royal Society of Chemistry
09.12.2021
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Abstract | The development of high energy-density Ni-rich (Ni ≥ 90%) layered cathodes has remained difficult because of the rapid capacity fading that occurs during cycling. This study demonstrates that limiting the primary particle size of the cathode resolves the capacity fading problem as nano-sized primary particles effectively relieve the high internal strain associated with the phase transition near charge end and fracture-toughen the cathode. A linear relationship is observed between battery cycling stability and cathode primary particle size. The introduction of Mo inhibits the growth/consolidation of primary particles and limits their size to a submicrometer scale thus improving the cycle life of Li[Ni
0.95
Co
0.04
Mo
0.01
]O
2
to a commercially viable level. The Li[Ni
0.95
Co
0.04
Mo
0.01
]O
2
cathode, whose microstructure is engineered to mitigate the mechanical instability of Ni-rich layered cathodes, represents a next-generation high energy-density cathode with fast charging capability for electric vehicles with a material cost advantage over current commercial cathodes as Co, a relatively expensive and increasingly scarce resource, is replaced with Ni without compromising battery capacity and battery life.
The ultrafine-grained Ni-enriched Li[Ni
0.95
Co
0.04
Mo
0.01
]O
2
(NCMo95) cathode achieved by inhibiting particle coarsening imparts the necessary mechanical toughness and significantly extends the battery life. |
---|---|
AbstractList | The development of high energy-density Ni-rich (Ni ≥ 90%) layered cathodes has remained difficult because of the rapid capacity fading that occurs during cycling. This study demonstrates that limiting the primary particle size of the cathode resolves the capacity fading problem as nano-sized primary particles effectively relieve the high internal strain associated with the phase transition near charge end and fracture-toughen the cathode. A linear relationship is observed between battery cycling stability and cathode primary particle size. The introduction of Mo inhibits the growth/consolidation of primary particles and limits their size to a submicrometer scale thus improving the cycle life of Li[Ni
0.95
Co
0.04
Mo
0.01
]O
2
to a commercially viable level. The Li[Ni
0.95
Co
0.04
Mo
0.01
]O
2
cathode, whose microstructure is engineered to mitigate the mechanical instability of Ni-rich layered cathodes, represents a next-generation high energy-density cathode with fast charging capability for electric vehicles with a material cost advantage over current commercial cathodes as Co, a relatively expensive and increasingly scarce resource, is replaced with Ni without compromising battery capacity and battery life.
The ultrafine-grained Ni-enriched Li[Ni
0.95
Co
0.04
Mo
0.01
]O
2
(NCMo95) cathode achieved by inhibiting particle coarsening imparts the necessary mechanical toughness and significantly extends the battery life. The development of high energy-density Ni-rich (Ni ≥ 90%) layered cathodes has remained difficult because of the rapid capacity fading that occurs during cycling. This study demonstrates that limiting the primary particle size of the cathode resolves the capacity fading problem as nano-sized primary particles effectively relieve the high internal strain associated with the phase transition near charge end and fracture-toughen the cathode. A linear relationship is observed between battery cycling stability and cathode primary particle size. The introduction of Mo inhibits the growth/consolidation of primary particles and limits their size to a submicrometer scale thus improving the cycle life of Li[Ni0.95Co0.04Mo0.01]O2 to a commercially viable level. The Li[Ni0.95Co0.04Mo0.01]O2 cathode, whose microstructure is engineered to mitigate the mechanical instability of Ni-rich layered cathodes, represents a next-generation high energy-density cathode with fast charging capability for electric vehicles with a material cost advantage over current commercial cathodes as Co, a relatively expensive and increasingly scarce resource, is replaced with Ni without compromising battery capacity and battery life. The development of high energy-density Ni-rich (Ni ≥ 90%) layered cathodes has remained difficult because of the rapid capacity fading that occurs during cycling. This study demonstrates that limiting the primary particle size of the cathode resolves the capacity fading problem as nano-sized primary particles effectively relieve the high internal strain associated with the phase transition near charge end and fracture-toughen the cathode. A linear relationship is observed between battery cycling stability and cathode primary particle size. The introduction of Mo inhibits the growth/consolidation of primary particles and limits their size to a submicrometer scale thus improving the cycle life of Li[Ni 0.95 Co 0.04 Mo 0.01 ]O 2 to a commercially viable level. The Li[Ni 0.95 Co 0.04 Mo 0.01 ]O 2 cathode, whose microstructure is engineered to mitigate the mechanical instability of Ni-rich layered cathodes, represents a next-generation high energy-density cathode with fast charging capability for electric vehicles with a material cost advantage over current commercial cathodes as Co, a relatively expensive and increasingly scarce resource, is replaced with Ni without compromising battery capacity and battery life. |
Author | Yoon, Chong S Lee, Junghwa Wang, Melody M Namkoong, Been Lee, Andrew C Chueh, William C Yoon, Dae Ro Sun, Yang-Kook Park, Geon-Tae Kim, Un-Hyuck Gu, X. Wendy |
AuthorAffiliation | Hanyang University Stanford University Department of Mechanical Engineering Department of Materials Science and Engineering Department of Energy Engineering |
AuthorAffiliation_xml | – name: Hanyang University – name: Department of Energy Engineering – name: Department of Mechanical Engineering – name: Stanford University – name: Department of Materials Science and Engineering |
Author_xml | – sequence: 1 givenname: Geon-Tae surname: Park fullname: Park, Geon-Tae – sequence: 2 givenname: Dae Ro surname: Yoon fullname: Yoon, Dae Ro – sequence: 3 givenname: Un-Hyuck surname: Kim fullname: Kim, Un-Hyuck – sequence: 4 givenname: Been surname: Namkoong fullname: Namkoong, Been – sequence: 5 givenname: Junghwa surname: Lee fullname: Lee, Junghwa – sequence: 6 givenname: Melody M surname: Wang fullname: Wang, Melody M – sequence: 7 givenname: Andrew C surname: Lee fullname: Lee, Andrew C – sequence: 8 givenname: X. Wendy surname: Gu fullname: Gu, X. Wendy – sequence: 9 givenname: William C surname: Chueh fullname: Chueh, William C – sequence: 10 givenname: Chong S surname: Yoon fullname: Yoon, Chong S – sequence: 11 givenname: Yang-Kook surname: Sun fullname: Sun, Yang-Kook |
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Snippet | The development of high energy-density Ni-rich (Ni ≥ 90%) layered cathodes has remained difficult because of the rapid capacity fading that occurs during... |
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StartPage | 6616 |
SubjectTerms | Batteries Cathodes Cycles Density Electric vehicles Energy consumption Fading Lithium-ion batteries Particle size Phase transitions Rechargeable batteries Ultrafines |
Title | Ultrafine-grained Ni-rich layered cathode for advanced Li-ion batteries |
URI | https://www.proquest.com/docview/2608159100/abstract/ |
Volume | 14 |
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