Hygro-responsive membranes for effective oil–water separation

There is a critical need for new energy-efficient solutions to separate oil–water mixtures, especially those stabilized by surfactants. Traditional membrane-based separation technologies are energy-intensive and limited, either by fouling or by the inability of a single membrane to separate all type...

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Published inNature communications Vol. 3; no. 1; p. 1025
Main Authors Kota, Arun K., Kwon, Gibum, Choi, Wonjae, Mabry, Joseph M., Tuteja, Anish
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 28.08.2012
Nature Publishing Group
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Abstract There is a critical need for new energy-efficient solutions to separate oil–water mixtures, especially those stabilized by surfactants. Traditional membrane-based separation technologies are energy-intensive and limited, either by fouling or by the inability of a single membrane to separate all types of oil–water mixtures. Here we report membranes with hygro-responsive surfaces, which are both superhydrophilic and superoleophobic, in air and under water. Our membranes can separate, for the first time, a range of different oil–water mixtures in a single-unit operation, with >99.9% separation efficiency, by using the difference in capillary forces acting on the two phases. Our separation methodology is solely gravity-driven and consequently is expected to be highly energy-efficient. We anticipate that our separation methodology will have numerous applications, including the clean-up of oil spills, wastewater treatment, fuel purification and the separation of commercially relevant emulsions. Membrane-based technologies to separate oil–water mixtures are energy-intensive, suffer from fouling or cannot separate a wide range of mixtures. Now, a new membrane is reported that is superhydrophilic and superoleophobic, and can separate a range of oil–water mixtures with high efficiency, without an external energy source.
AbstractList There is a critical need for new energy-efficient solutions to separate oil-water mixtures, especially those stabilized by surfactants. Traditional membrane-based separation technologies are energy-intensive and limited, either by fouling or by the inability of a single membrane to separate all types of oil-water mixtures. Here we report membranes with hygro-responsive surfaces, which are both superhydrophilic and superoleophobic, in air and under water. Our membranes can separate, for the first time, a range of different oil-water mixtures in a single-unit operation, with >99.9% separation efficiency, by using the difference in capillary forces acting on the two phases. Our separation methodology is solely gravity-driven and consequently is expected to be highly energy-efficient. We anticipate that our separation methodology will have numerous applications, including the clean-up of oil spills, wastewater treatment, fuel purification and the separation of commercially relevant emulsions.
There is a critical need for new energy-efficient solutions to separate oil–water mixtures, especially those stabilized by surfactants. Traditional membrane-based separation technologies are energy-intensive and limited, either by fouling or by the inability of a single membrane to separate all types of oil–water mixtures. Here we report membranes with hygro-responsive surfaces, which are both superhydrophilic and superoleophobic, in air and under water. Our membranes can separate, for the first time, a range of different oil–water mixtures in a single-unit operation, with >99.9% separation efficiency, by using the difference in capillary forces acting on the two phases. Our separation methodology is solely gravity-driven and consequently is expected to be highly energy-efficient. We anticipate that our separation methodology will have numerous applications, including the clean-up of oil spills, wastewater treatment, fuel purification and the separation of commercially relevant emulsions. Membrane-based technologies to separate oil–water mixtures are energy-intensive, suffer from fouling or cannot separate a wide range of mixtures. Now, a new membrane is reported that is superhydrophilic and superoleophobic, and can separate a range of oil–water mixtures with high efficiency, without an external energy source.
ArticleNumber 1025
Author Mabry, Joseph M.
Kwon, Gibum
Tuteja, Anish
Choi, Wonjae
Kota, Arun K.
Author_xml – sequence: 1
  givenname: Arun K.
  surname: Kota
  fullname: Kota, Arun K.
  organization: Department of Materials Science and Engineering, University of Michigan
– sequence: 2
  givenname: Gibum
  surname: Kwon
  fullname: Kwon, Gibum
  organization: Department of Materials Science and Engineering, University of Michigan
– sequence: 3
  givenname: Wonjae
  surname: Choi
  fullname: Choi, Wonjae
  organization: Department of Mechanical Engineering, University of Texas, Dallas
– sequence: 4
  givenname: Joseph M.
  surname: Mabry
  fullname: Mabry, Joseph M.
  organization: Rocket Propulsion Division, Air Force Research Laboratory, Edwards Air Force Base
– sequence: 5
  givenname: Anish
  surname: Tuteja
  fullname: Tuteja, Anish
  email: atuteja@umich.edu
  organization: Department of Materials Science and Engineering, University of Michigan, Macromolecular Science and Engineering, University of Michigan
BackLink https://www.ncbi.nlm.nih.gov/pubmed/22929782$$D View this record in MEDLINE/PubMed
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Snippet There is a critical need for new energy-efficient solutions to separate oil–water mixtures, especially those stabilized by surfactants. Traditional...
There is a critical need for new energy-efficient solutions to separate oil-water mixtures, especially those stabilized by surfactants. Traditional...
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Title Hygro-responsive membranes for effective oil–water separation
URI https://link.springer.com/article/10.1038/ncomms2027
https://www.ncbi.nlm.nih.gov/pubmed/22929782
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