Regulating Solvation Structure in Nonflammable Amide‐Based Electrolytes for Long‐Cycling and Safe Lithium Metal Batteries

• Published in: Advanced energy materials Vol. 12; no. 24
• Main Authors: Zhang, Qian‐Kui, Zhang, Xue‐Qiang, Hou, Li‐Peng, Sun, Shu‐Yu, Zhan, Ying‐Xin, Liang, Jia‐Lin, Zhang, Fang‐Shu, Feng, Xu‐Ning, Li, Bo‐Quan, Huang, Jia‐Qi
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.06.2022
• Subjects: Compatibility; Cycles; Dimethyl acetamide; Electrolytes; Fire hazards; Hazard mitigation; Lithium; Lithium batteries; lithium metal batteries; nonflammable dimethylacetamide; safety; solid electrolyte interphase; Solid electrolytes; Solvation; solvation structure; Solvents; Stability

The cycling stability of lithium metal batteries is steadily improving. The safety issues, which mainly result from the employment of flammable solvents, should be strongly considered for practical Li metal batteries. Nonflammable solvents can mitigate fire hazards; however, their employment irrever...